Hydrothermal synthesis of zeolites-calcium silicate hydrate composite from coal fly ash with co-activation of Ca(OH)2-NaOH for aqueous heavy metals removal

Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization, while the purity and adsorption property of zeolite are limited due to the occurrence of side reactions in the synthesis process. In this study...

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Published inInternational journal of mining science and technology Vol. 32; no. 3; pp. 563 - 573
Main Authors Li, Guanghui, Li, Min, Zhang, Xin, Cao, Pengxu, Jiang, Hao, Luo, Jun, Jiang, Tao
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2022
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Abstract Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization, while the purity and adsorption property of zeolite are limited due to the occurrence of side reactions in the synthesis process. In this study, a designated composite consisted of crystalline zeolites and amorphous calcium silicate hydrate was selected, which was direct synthesized from fly ash under conditions of a Ca/Si molar ratio of 0.8, an initial NaOH concentration of 0.5 mol/L, a hydrothermal temperature of 170 ℃ and a liquid–solid ratio of 15 mL/g. The results indicated that this composite had superior adsorption property for a variety of heavy metals, which was based on the exchange of calcium and sodium ions in zeolites and calcium silicate hydrate. Its adsorption capacities for Pb2+, Ni2+, Cd2+, Zn2+, Cu2+ and Cr3+ attained 409.4, 222.4, 147.5, 93.2, 101.1 and 157.0 mg/g, respectively, in single solution with a pH of 4.5. After regulating the synthesis conditions, the transformation of amorphous calcium silicate hydrate into crystallized tobermorite weakened the adsorption capacity of the composite. Besides, due to the competitive adsorption in a multiple ions solution, the adsorption capacities for these heavy metals had a reduction.
AbstractList Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization, while the purity and adsorption property of zeolite are limited due to the occurrence of side reactions in the synthesis process. In this study, a designated composite consisted of crystalline zeolites and amorphous calcium silicate hydrate was selected, which was direct synthesized from fly ash under conditions of a Ca/Si molar ratio of 0.8, an initial NaOH concentration of 0.5 mol/L, a hydrothermal temperature of 170 ℃ and a liquid–solid ratio of 15 mL/g. The results indicated that this composite had superior adsorption property for a variety of heavy metals, which was based on the exchange of calcium and sodium ions in zeolites and calcium silicate hydrate. Its adsorption capacities for Pb2+, Ni2+, Cd2+, Zn2+, Cu2+ and Cr3+ attained 409.4, 222.4, 147.5, 93.2, 101.1 and 157.0 mg/g, respectively, in single solution with a pH of 4.5. After regulating the synthesis conditions, the transformation of amorphous calcium silicate hydrate into crystallized tobermorite weakened the adsorption capacity of the composite. Besides, due to the competitive adsorption in a multiple ions solution, the adsorption capacities for these heavy metals had a reduction.
Author Zhang, Xin
Luo, Jun
Li, Min
Li, Guanghui
Jiang, Tao
Cao, Pengxu
Jiang, Hao
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Issue 3
Keywords Coal fly ash
Adsorption material
Zeolite
Calcium silicate hydrate
Heavy metals
Language English
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Snippet Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization,...
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elsevier
SourceType Enrichment Source
Index Database
Publisher
StartPage 563
SubjectTerms Adsorption material
Calcium silicate hydrate
Coal fly ash
Heavy metals
Zeolite
Title Hydrothermal synthesis of zeolites-calcium silicate hydrate composite from coal fly ash with co-activation of Ca(OH)2-NaOH for aqueous heavy metals removal
URI https://dx.doi.org/10.1016/j.ijmst.2022.03.001
Volume 32
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