Hydrothermal synthesis of zeolites-calcium silicate hydrate composite from coal fly ash with co-activation of Ca(OH)2-NaOH for aqueous heavy metals removal
Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization, while the purity and adsorption property of zeolite are limited due to the occurrence of side reactions in the synthesis process. In this study...
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Published in | International journal of mining science and technology Vol. 32; no. 3; pp. 563 - 573 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.05.2022
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Abstract | Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization, while the purity and adsorption property of zeolite are limited due to the occurrence of side reactions in the synthesis process. In this study, a designated composite consisted of crystalline zeolites and amorphous calcium silicate hydrate was selected, which was direct synthesized from fly ash under conditions of a Ca/Si molar ratio of 0.8, an initial NaOH concentration of 0.5 mol/L, a hydrothermal temperature of 170 ℃ and a liquid–solid ratio of 15 mL/g. The results indicated that this composite had superior adsorption property for a variety of heavy metals, which was based on the exchange of calcium and sodium ions in zeolites and calcium silicate hydrate. Its adsorption capacities for Pb2+, Ni2+, Cd2+, Zn2+, Cu2+ and Cr3+ attained 409.4, 222.4, 147.5, 93.2, 101.1 and 157.0 mg/g, respectively, in single solution with a pH of 4.5. After regulating the synthesis conditions, the transformation of amorphous calcium silicate hydrate into crystallized tobermorite weakened the adsorption capacity of the composite. Besides, due to the competitive adsorption in a multiple ions solution, the adsorption capacities for these heavy metals had a reduction. |
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AbstractList | Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization, while the purity and adsorption property of zeolite are limited due to the occurrence of side reactions in the synthesis process. In this study, a designated composite consisted of crystalline zeolites and amorphous calcium silicate hydrate was selected, which was direct synthesized from fly ash under conditions of a Ca/Si molar ratio of 0.8, an initial NaOH concentration of 0.5 mol/L, a hydrothermal temperature of 170 ℃ and a liquid–solid ratio of 15 mL/g. The results indicated that this composite had superior adsorption property for a variety of heavy metals, which was based on the exchange of calcium and sodium ions in zeolites and calcium silicate hydrate. Its adsorption capacities for Pb2+, Ni2+, Cd2+, Zn2+, Cu2+ and Cr3+ attained 409.4, 222.4, 147.5, 93.2, 101.1 and 157.0 mg/g, respectively, in single solution with a pH of 4.5. After regulating the synthesis conditions, the transformation of amorphous calcium silicate hydrate into crystallized tobermorite weakened the adsorption capacity of the composite. Besides, due to the competitive adsorption in a multiple ions solution, the adsorption capacities for these heavy metals had a reduction. |
Author | Zhang, Xin Luo, Jun Li, Min Li, Guanghui Jiang, Tao Cao, Pengxu Jiang, Hao |
Author_xml | – sequence: 1 givenname: Guanghui surname: Li fullname: Li, Guanghui – sequence: 2 givenname: Min surname: Li fullname: Li, Min – sequence: 3 givenname: Xin surname: Zhang fullname: Zhang, Xin – sequence: 4 givenname: Pengxu surname: Cao fullname: Cao, Pengxu – sequence: 5 givenname: Hao surname: Jiang fullname: Jiang, Hao – sequence: 6 givenname: Jun orcidid: 0000-0002-2637-7207 surname: Luo fullname: Luo, Jun email: luojun2013@csu.edu.cn – sequence: 7 givenname: Tao surname: Jiang fullname: Jiang, Tao |
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Keywords | Coal fly ash Adsorption material Zeolite Calcium silicate hydrate Heavy metals |
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Snippet | Coal fly ash is a typical secondary aluminum/silicon resource. The preparation of zeolite-type absorbent is a potential way for its value-added utilization,... |
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SubjectTerms | Adsorption material Calcium silicate hydrate Coal fly ash Heavy metals Zeolite |
Title | Hydrothermal synthesis of zeolites-calcium silicate hydrate composite from coal fly ash with co-activation of Ca(OH)2-NaOH for aqueous heavy metals removal |
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