Chemical modifications of activated carbons prepared from different Ganoderma residues, their adsorption, and catalytic application
ABSTRACT This study aimed to prepare Ganoderma-based activated carbons for chemical adsorption and catalyzing N-(phosphonomethyl)iminodiacetic acid to glyphosate. The activated carbons were prepared by applying different activation conditions. These carbon samples were applied to catalyze N-(phospho...
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Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro; em cooperação com a Associação Brasileira do Hidrogênio, ABH2
2024
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| Abstract | ABSTRACT This study aimed to prepare Ganoderma-based activated carbons for chemical adsorption and catalyzing N-(phosphonomethyl)iminodiacetic acid to glyphosate. The activated carbons were prepared by applying different activation conditions. These carbon samples were applied to catalyze N-(phosphonomethyl)iminodiacetic acid to glyphosate. The results showed that the black Ganoderma char activated at 800 °C for 90 min using 40% phosphoric acid had the highest methylene blue adsorption capacity and DPPH scavenging activities, but the methylene blue adsorption capacity of the black Ganoderma sample activated at 800 °C for 90 min using 40% acid-base solution was lower than the red AC sample. These carbon samples had high thermal stability. Chemical modifications of these chars with the carbon modifiers at an optimized activation condition increased the Langmuir-specific surface areas of these carbon samples up to 2055.09 m2/g. The carbon sample of black Ganoderma activated using the 40% acid-base solution at 800 °C for 90 min and coupled with the addition of hydrogen peroxide during ultrasonication and microwave-assisted reactions had the highest glyphosate catalyzing rate. The glyphosate yield obtained from the catalyzing at atmospheric pressure was 58.78 ± 0.28%. These Ganoderma-based activated carbons can replace other carbon materials for catalysis applications and as adsorbents in food and pharmaceutical industries. |
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| AbstractList | ABSTRACT This study aimed to prepare Ganoderma-based activated carbons for chemical adsorption and catalyzing N-(phosphonomethyl)iminodiacetic acid to glyphosate. The activated carbons were prepared by applying different activation conditions. These carbon samples were applied to catalyze N-(phosphonomethyl)iminodiacetic acid to glyphosate. The results showed that the black Ganoderma char activated at 800 °C for 90 min using 40% phosphoric acid had the highest methylene blue adsorption capacity and DPPH scavenging activities, but the methylene blue adsorption capacity of the black Ganoderma sample activated at 800 °C for 90 min using 40% acid-base solution was lower than the red AC sample. These carbon samples had high thermal stability. Chemical modifications of these chars with the carbon modifiers at an optimized activation condition increased the Langmuir-specific surface areas of these carbon samples up to 2055.09 m2/g. The carbon sample of black Ganoderma activated using the 40% acid-base solution at 800 °C for 90 min and coupled with the addition of hydrogen peroxide during ultrasonication and microwave-assisted reactions had the highest glyphosate catalyzing rate. The glyphosate yield obtained from the catalyzing at atmospheric pressure was 58.78 ± 0.28%. These Ganoderma-based activated carbons can replace other carbon materials for catalysis applications and as adsorbents in food and pharmaceutical industries. |
| Author | Huang, Rong Bing Khoo, Hock Eng Liu, Bai Cheng Jiang, Tiemin Lee, Say Wah Chen, Bo Jie Liu, Yang Dong, Xinhong Wu, Pei Ling Li, Xia |
| AuthorAffiliation | UCSI University Guilin University of Technology |
| AuthorAffiliation_xml | – name: UCSI University – name: Guilin University of Technology |
| Author_xml | – sequence: 1 givenname: Bo Jie orcidid: 0009-0006-7538-8742 surname: Chen fullname: Chen, Bo Jie organization: Guilin University of Technology, China – sequence: 2 givenname: Yang surname: Liu fullname: Liu, Yang organization: Guilin University of Technology, China – sequence: 3 givenname: Bai Cheng surname: Liu fullname: Liu, Bai Cheng organization: Guilin University of Technology, China – sequence: 4 givenname: Rong Bing surname: Huang fullname: Huang, Rong Bing organization: Guilin University of Technology, China – sequence: 5 givenname: Pei Ling surname: Wu fullname: Wu, Pei Ling organization: Guilin University of Technology, China – sequence: 6 givenname: Tiemin surname: Jiang fullname: Jiang, Tiemin organization: Guilin University of Technology, China; Guilin University of Technology, China – sequence: 7 givenname: Xinhong surname: Dong fullname: Dong, Xinhong organization: Guilin University of Technology, China; Guilin University of Technology, China – sequence: 8 givenname: Xia surname: Li fullname: Li, Xia organization: Guilin University of Technology, China; Guilin University of Technology, China – sequence: 9 givenname: Hock Eng surname: Khoo fullname: Khoo, Hock Eng organization: Guilin University of Technology, China; Guilin University of Technology, China – sequence: 10 givenname: Say Wah surname: Lee fullname: Lee, Say Wah organization: UCSI University, Malaysia; UCSI University, Malaysia |
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| CitedBy_id | crossref_primary_10_1590_1517_7076_rmat_2024_0811 crossref_primary_10_1007_s41101_024_00260_0 crossref_primary_10_1007_s10853_024_10099_4 |
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| Keywords | herbicide decolorization antioxidant capacity Activated charcoal reishi mushroom |
| Language | English |
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| Title | Chemical modifications of activated carbons prepared from different Ganoderma residues, their adsorption, and catalytic application |
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