Tailoring the d-band center by borophene subunits in chromic diboride toward the hydrogen evolution reaction

• Published in: Inorganic chemistry frontiers Vol. 8; no. 23; pp. 513 - 5138
• Main Authors: Chen, Yanli, Rong, Jiashi, Wang, Zizhun, Tao, Qiang, Gan, Quan, Wang, Fei, Ye, Yanping, Liu, Xiaoyan, Cao, Jian, Fan, Hougang, Wei, Maobin, Zhang, Wei, Zhu, Pinwen, Yang, Lili, Yang, Jinghai
• Format: Journal Article
• Language: English
• Published: London Royal Society of Chemistry 23.11.2021
• Subjects: Basal plane; Borophene; Catalysts; Catalytic activity; Chromium borides; Electrocatalysts; Electronic structure; High temperature; Hydrogen evolution reactions; Inorganic chemistry; Noble metals; Transition metals
• DOI: 10.1039/d1qi00496d
• ISSN: 2052-1553; 2052-1545

Transition metal diborides (TMdBs AlB 2 -type P 6/ mmm ) electrocatalysts have aroused much attention toward the hydrogen evolution reaction (HER), because MoB 2 ( P 6/ mmm ) exhibits superior catalytic activity. However, the understanding of the activity in the different lattice planes of TMdBs is still limited, which impedes the accurate design of new superior catalyst based on TMdBs. In this work, a borophene subunit was utilized to form AlB 2 -type CrB 2 ( P 6/ mmm ) for modulating the d-band center. It was revealed that the d-band center in CrB 2 has almost a linear relation with the Δ G H* value in the different lattice planes of metallic Cr and CrB 2 , and that the modulation of the electronic structure by borophene subunits was more effective at the edge side than in the basal plane of CrB 2 . Single-phase CrB 2 was synthesized via a high pressure and high temperature (HPHT) approach as an electrocatalyst for HER. The performance of CrB 2 revealed a higher catalytic activity with overpotentials of 355 and 522 mV at 10 and 200 mA cm −2 in acidic conditions and a Tafel slope of 77.84 mV dec −1 . These results indicate that CrB 2 is a promising alternative to noble metal-based catalysts, and that modulating the d-band center by borophene subunits is an efficient way to develop novel Cr-based catalysts. Borophene subunits modulate the d-band center in different planes for improving the HER performance.