Synergistic enhancement of thermal conductivity between SiCw and h-BN in MVQ-based composite
Thermally conductive and electrically insulating h-BN/MVQ and h-BN/SiCw/MVQ composites were prepared by internal mixing and two roll mixing, using 1-dimensional (1D) silicon carbide whiskers (SiCw) and 2-dimensional (2D) hexagonal boron nitride flakes (h-BN) as fillers, and methyl vinyl silicone rub...
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Published in | Fullerenes, nanotubes, and carbon nanostructures Vol. 27; no. 5; pp. 434 - 439 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Taylor & Francis
04.05.2019
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Subjects | |
Online Access | Get full text |
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Summary: | Thermally conductive and electrically insulating h-BN/MVQ and h-BN/SiCw/MVQ composites were prepared by internal mixing and two roll mixing, using 1-dimensional (1D) silicon carbide whiskers (SiCw) and 2-dimensional (2D) hexagonal boron nitride flakes (h-BN) as fillers, and methyl vinyl silicone rubber (MVQ) as polymer matrix. Surface modification of 1 D SiCw and 2 D h-BN was characterized by Fourier transform infrared spectroscopy (FT-IR) and contact angle analysis. Morphology, thermal conductivity and dielectric constant of h-BN/MVQ and h-BN/SiCw/MVQ were studied. The results indicated that surface modified h-BN and SiCw could be uniformly distributed in MVQ matrix. At the same volume filler loading, thermal conductivity of h-BN/SiCw/MVQ ternary composite was higher than that of h-BN/MVQ binary composite. When part of 2 D h-BN was instead of 1 D SiCw, there was synergistically enhanced effect between 1 D SiCw and 2 D h-BN for thermal conductivity. When volume ratio of h-BN/SiCw was 8/2, thermal conductivity of h-BN/SiCw/MVQ was higher than that of other ratio. Thermal conductivity of h-BN/SiCw/MVQ composite with different volume ratio was linearly fit with Agari' model. |
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ISSN: | 1536-383X 1536-4046 |
DOI: | 10.1080/1536383X.2019.1580696 |