Thermodynamic investigation of ZrO2-BaO system
Thermodynamic description of ZrO2-BaO system was developed using the available experimental information. Special attention was paid to the modelling of the perovskite phase BaZrO3 by a temperature-dependent polynomial to fit the experimental thermodynamic properties. The liquid phases, Css (cubic Zr...
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Published in | Transactions of Nonferrous Metals Society of China Vol. 17; no. 2; pp. 232 - 237 |
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Main Author | |
Format | Journal Article |
Language | English |
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State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China
01.04.2007
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Online Access | Get full text |
ISSN | 1003-6326 |
DOI | 10.1016/S1003-6326(07)60077-6 |
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Abstract | Thermodynamic description of ZrO2-BaO system was developed using the available experimental information. Special attention was paid to the modelling of the perovskite phase BaZrO3 by a temperature-dependent polynomial to fit the experimental thermodynamic properties. The liquid phases, Css (cubic ZrO2 solid solution) and Tss (tetragonal ZrO2 solid solution) were modelled with Redlich-Kister formula. The compounds Ba2ZrO4 and Ba3Zr207 were treated as stoichiometric phases and the BaOss and Mss (halite BaO and monoclinic ZrO2 solid solutions) were treated as pure compounds. Comparisons between the calculated and the measured phase diagram as well as the thermodynamic quantities indicate that the most reliable experimental information is satisfactorily accounted for by the present thermodynamic calculation. |
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AbstractList | Thermodynamic description of ZrO2-BaO system was developed using the available experimental information. Special attention was paid to the modelling of the perovskite phase BaZrO3 by a temperature-dependent polynomial to fit the experimental thermodynamic properties. The liquid phases, Css (cubic ZrO2 solid solution) and Tss (tetragonal ZrO2 solid solution) were modelled with Redlich-Kister formula. The compounds Ba2ZrO4 and Ba3Zr2O7 were treated as stoichiometric phases and the BaOss and Mss (halite BaO and monoclinic ZrO2 solid solutions) were treated as pure compounds. Comparisons between the calculated and the measured phase diagram as well as the thermodynamic quantities indicate that the most reliable experimental information is satisfactorily accounted for by the present thermodynamic calculation. Thermodynamic description of ZrO2-BaO system was developed using the available experimental information. Special attention was paid to the modelling of the perovskite phase BaZrO3 by a temperature-dependent polynomial to fit the experimental thermodynamic properties. The liquid phases, Css (cubic ZrO2 solid solution) and Tss (tetragonal ZrO2 solid solution) were modelled with Redlich-Kister formula. The compounds Ba2ZrO4 and Ba3Zr207 were treated as stoichiometric phases and the BaOss and Mss (halite BaO and monoclinic ZrO2 solid solutions) were treated as pure compounds. Comparisons between the calculated and the measured phase diagram as well as the thermodynamic quantities indicate that the most reliable experimental information is satisfactorily accounted for by the present thermodynamic calculation. TG1; Thermodynamic description of ZrO2-BaO system was developed using the available experimental information. Special attention was paid to the modelling of the perovskite phase BaZrO3 by a temperature-dependent polynomial to fit the experimental thermodynamic properties. The liquid phases, CSS (cubic ZrO2 solid solution) and TSS (tetragonal ZrO2 solid solution) were modelled with Redlich-Kister formula. The compounds Ba2ZrO4 and Ba3Zr2O7 were treated as stoichiometric phases and the BaOSS and MSS (halite BaO and monoclinic ZrO2 solid solutions) were treated as pure compounds. Comparisons between the calculated and the measured phase diagram as well as the thermodynamic quantities indicate that the most reliable experimental information is satisfactorily accounted for by the present thermodynamic calculation. |
Author | 龚伟平 陈腾飞 金展鹏 |
AuthorAffiliation | State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China |
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Cites_doi | 10.1038/258703a0 10.1016/0022-4596(88)90028-X 10.1016/0040-6031(85)87107-0 10.1016/0022-4596(78)90038-5 10.1007/BF00553200 10.1006/jcht.1994.1088 10.1007/BF00719691 10.1016/S0364-5916(01)00008-6 10.1016/0022-3115(87)90050-X 10.1016/0040-6031(93)80547-N 10.1002/zaac.19291800104 10.1006/jcht.1994.1087 10.1016/0040-6031(89)87169-2 10.1088/0026-1394/27/1/002 10.1016/S0040-6031(97)00212-8 10.1111/j.1151-2916.1977.tb15509.x 10.1016/0022-3115(85)90323-X |
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SubjectTerms | ZrO2-BaO系统 氧化钡 氧化锆 热力学研究 钙钛矿相 |
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