Possible transition from rod-like to disc-like behaviour in ortho-metallated imine complexes of palladium(II): crystal and molecular structure of three palladium complexes

Two series of ortho-metallated palladium imine complexes are reported that contain a coordinated β-diketonate group. In one group the chain length of the imine is varied while the β-diketone is unchanged; in the other the imine chains are both fixed as methoxy and the structure of the β-diketonate i...

Full description

Saved in:
Bibliographic Details
Published inLiquid crystals Vol. 32; no. 11-12; pp. 1437 - 1447
Main Authors Omnès, Laurent, Cîrcu, Viorel, Hutchins, Peter T., Coles, Simon J., Horton, Peter N., Hursthouse, Michael B., Bruce, Duncan W.
Format Journal Article
LanguageEnglish
Published Taylor & Francis 01.11.2005
Online AccessGet full text

Cover

Abstract Two series of ortho-metallated palladium imine complexes are reported that contain a coordinated β-diketonate group. In one group the chain length of the imine is varied while the β-diketone is unchanged; in the other the imine chains are both fixed as methoxy and the structure of the β-diketonate is varied. The mesomorphism of these new complexes is reported and discussed in relation to the search for materials showing a biaxial nematic phase.
AbstractList Two series of ortho-metallated palladium imine complexes are reported that contain a coordinated β-diketonate group. In one group the chain length of the imine is varied while the β-diketone is unchanged; in the other the imine chains are both fixed as methoxy and the structure of the β-diketonate is varied. The mesomorphism of these new complexes is reported and discussed in relation to the search for materials showing a biaxial nematic phase.
Author Bruce, Duncan W.
Hursthouse, Michael B.
Omnès, Laurent
Cîrcu, Viorel
Hutchins, Peter T.
Coles, Simon J.
Horton, Peter N.
Author_xml – sequence: 1
  givenname: Laurent
  surname: Omnès
  fullname: Omnès, Laurent
  organization: Department of Chemistry , University of Exeter
– sequence: 2
  givenname: Viorel
  surname: Cîrcu
  fullname: Cîrcu, Viorel
  organization: Department of Chemistry , University of Exeter
– sequence: 3
  givenname: Peter T.
  surname: Hutchins
  fullname: Hutchins, Peter T.
  organization: Department of Chemistry , University of Exeter
– sequence: 4
  givenname: Simon J.
  surname: Coles
  fullname: Coles, Simon J.
  organization: EPSRC Crystallographic Service , Department of Chemistry , University of Southampton
– sequence: 5
  givenname: Peter N.
  surname: Horton
  fullname: Horton, Peter N.
  organization: EPSRC Crystallographic Service , Department of Chemistry , University of Southampton
– sequence: 6
  givenname: Michael B.
  surname: Hursthouse
  fullname: Hursthouse, Michael B.
  organization: EPSRC Crystallographic Service , Department of Chemistry , University of Southampton
– sequence: 7
  givenname: Duncan W.
  surname: Bruce
  fullname: Bruce, Duncan W.
  email: d.bruce@york.ac.uk
  organization: Department of Chemistry , University of Exeter
BookMark eNqFkMtuFDEQRS2USEwCH8DOS1g0-BG33YgNiniMFIkswrrlR1ljcLdHZTdkvik_SY8GKYtIsCqV7j13cS7I2VxmIOQVZ285M-wdE702YmCKMd4zreQzsuGy7ztllDojm2PerQXxnFzU-oMxpo3RG_JwW2pNLgNtaOeaWiozjVgmiiV0Of1cg0JDqv70ONjZX6ksSNNMC7Zd6SZoNmfbINA0pRmoL9M-wz1UWiLdH7OQlun1dvvmPfV4qGud2jnQqWTwS7ZIa8PFtwXhSLQdAjxyj3MvyHm0ucLLv_eSfP_86e76a3fz7cv2-uNN5-VV3zozcAm9AxH8EGDojXFcKyciiyCc4F6IgSvnmJeBRa210VciShUgcheVlJeEn3Y9rnIQ4rjHNFk8jJyNR9vjE9sr8-HEpDkWnOzvgjmMzR5ywbia9amO8l-4_i_-hBrbfZN_AJluniA
CitedBy_id crossref_primary_10_1002_chem_201103453
crossref_primary_10_1016_j_molliq_2017_08_013
crossref_primary_10_1002_chem_201000717
crossref_primary_10_1039_B605101D
crossref_primary_10_1080_17415993_2018_1551488
crossref_primary_10_1016_j_jorganchem_2017_03_015
crossref_primary_10_1080_02678290701770343
crossref_primary_10_1039_B608823F
crossref_primary_10_1039_B709107A
crossref_primary_10_1016_j_poly_2008_08_023
crossref_primary_10_1016_j_molliq_2017_02_114
Cites_doi 10.1016/S0040-6090(01)01091-4
10.1103/PhysRevA.10.1881
10.1002/9783527619276.ch6a
10.1080/10587259808048444
10.1007/BF00254854
10.1103/PhysRevLett.92.125501
10.1051/jphys:01977003802014900
10.1103/PhysRevLett.45.1000
10.1080/00268949108033415
10.1021/jo01286a109
10.1021/la026618z
10.1080/10587259808048443
10.1107/S0108767390000277
10.1103/PhysRevLett.92.145505
10.1002/(SICI)1521-3773(19980216)37:3<296::AID-ANIE296>3.0.CO;2-U
10.1039/b107775a
10.1007/BF00807029
10.1016/S0076-6879(97)76066-X
10.1021/jo00093a010
10.1107/S0108767394005726
10.1103/PhysRevLett.92.145506
10.1002/tcr.10073
10.1021/jo01029a042
ContentType Journal Article
Copyright Copyright Taylor & Francis Group, LLC 2005
Copyright_xml – notice: Copyright Taylor & Francis Group, LLC 2005
DBID AAYXX
CITATION
DOI 10.1080/02678290500160753
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
Chemistry
EISSN 1366-5855
EndPage 1447
ExternalDocumentID 10_1080_02678290500160753
116058
Genre Original Articles
GroupedDBID -~X
.7F
.QJ
0BK
0R~
29L
30N
4.4
5GY
5VS
AAAJW
AAAVI
AAENE
AAJMT
AALDU
AAMIU
AAPUL
AAQRR
ABBKH
ABCCY
ABFIM
ABHAV
ABJVF
ABKVM
ABLIJ
ABPTK
ABQHQ
ABTAI
ABXUL
ACGEJ
ACGOD
ACIWK
ACTIO
ACYAP
ADCVX
ADGTB
ADXPE
AEGYZ
AEISY
AENEX
AEOZL
AEPSL
AEYOC
AFKVX
AFOLD
AFWJF
AFWLO
AGDLA
AGMYJ
AHDLD
AIJEM
AIRXU
AJWEG
AKBVH
AKOOK
ALMA_UNASSIGNED_HOLDINGS
ALQZU
AQRUH
AVBZW
AWYRJ
BDVFT
BKMSO
BLEHA
CAG
CCCUG
CE4
COF
CS3
CXCUG
DGEBU
DKSSO
DU5
EBS
EJD
E~A
E~B
FUNRP
FVPDL
GTTXZ
HZ~
H~P
IPNFZ
J.P
KYCEM
M4Z
NA5
NW0
O9-
OEUFU
P2P
PQEST
PQQKQ
RIG
RNANH
ROSJB
RTWRZ
S-T
SNACF
TCY
TFL
TFT
TFW
TTHFI
TWF
UT5
UU3
XJE
ZE2
ZGOLN
~S~
AAYXX
ABJNI
ABPAQ
ABXYU
AHDZW
CITATION
H13
TBQAZ
TDBHL
TUROJ
ID FETCH-LOGICAL-c346t-8913e6be2dc9de9688b175b2f0fe2b21c22915bb0c3d0f7778742f35def1bf533
ISSN 0267-8292
IngestDate Fri Aug 23 04:01:46 EDT 2024
Mon May 13 12:09:41 EDT 2019
Tue Jun 13 20:00:12 EDT 2023
IsPeerReviewed true
IsScholarly true
Issue 11-12
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c346t-8913e6be2dc9de9688b175b2f0fe2b21c22915bb0c3d0f7778742f35def1bf533
PageCount 11
ParticipantIDs crossref_primary_10_1080_02678290500160753
informaworld_taylorfrancis_310_1080_02678290500160753
PublicationCentury 2000
PublicationDate 11/1/2005
2005-11-01
PublicationDateYYYYMMDD 2005-11-01
PublicationDate_xml – month: 11
  year: 2005
  text: 11/1/2005
  day: 01
PublicationDecade 2000
PublicationTitle Liquid crystals
PublicationYear 2005
Publisher Taylor & Francis
Publisher_xml – name: Taylor & Francis
References ref12
ref11
ref10
ref2
ref1
Omnès L. (ref14) 2001
McCleverty J. A (ref16) 2003
Barbera J. (ref25) 1998; 37
ref18
Berardi R. (ref15) 2000; 113
Adam W. (ref19) 1994; 59
Moore R. A. (ref17) 1964
ref24
ref23
ref26
Boccara N. (ref13) 1977; 38
ref20
ref22
ref21
ref28
ref27
ref29
ref8
ref7
ref9
ref4
ref3
ref6
ref5
References_xml – ident: ref8
  doi: 10.1016/S0040-6090(01)01091-4
– ident: ref12
  doi: 10.1103/PhysRevA.10.1881
– ident: ref24
  doi: 10.1002/9783527619276.ch6a
– ident: ref29
– ident: ref9
  doi: 10.1080/10587259808048444
– ident: ref3
  doi: 10.1007/BF00254854
– volume-title: Comprehensive Coordination Chemistry II: From Biology to Nanotechnology
  year: 2003
  ident: ref16
  contributor:
    fullname: McCleverty J. A
– ident: ref4
  doi: 10.1103/PhysRevLett.92.125501
– volume: 38
  start-page: 149
  year: 1977
  ident: ref13
  publication-title: J. de Phys.
  doi: 10.1051/jphys:01977003802014900
  contributor:
    fullname: Boccara N.
– ident: ref1
  doi: 10.1103/PhysRevLett.45.1000
– ident: ref10
  doi: 10.1080/00268949108033415
– ident: ref18
  doi: 10.1021/jo01286a109
– volume-title: LiqCryst Database
  ident: ref23
– ident: ref2
  doi: 10.1021/la026618z
– ident: ref11
  doi: 10.1080/10587259808048443
– ident: ref28
  doi: 10.1107/S0108767390000277
– ident: ref5
  doi: 10.1103/PhysRevLett.92.145505
– volume: 37
  start-page: 296
  year: 1998
  ident: ref25
  publication-title: Angew. Chem. int. Edn. Engl.
  doi: 10.1002/(SICI)1521-3773(19980216)37:3<296::AID-ANIE296>3.0.CO;2-U
  contributor:
    fullname: Barbera J.
– start-page: 2248
  year: 2001
  ident: ref14
  publication-title: Chem. Commun.
  doi: 10.1039/b107775a
  contributor:
    fullname: Omnès L.
– ident: ref20
  doi: 10.1007/BF00807029
– volume: 113
  start-page: 5971
  year: 2000
  ident: ref15
  publication-title: Chem. Phys.
  contributor:
    fullname: Berardi R.
– ident: ref21
– ident: ref26
– ident: ref27
  doi: 10.1016/S0076-6879(97)76066-X
– volume: 59
  start-page: 3786
  year: 1994
  ident: ref19
  publication-title: J. org. Chem.
  doi: 10.1021/jo00093a010
  contributor:
    fullname: Adam W.
– ident: ref22
  doi: 10.1107/S0108767394005726
– ident: ref6
  doi: 10.1103/PhysRevLett.92.145506
– ident: ref7
  doi: 10.1002/tcr.10073
– start-page: 1439
  year: 1964
  ident: ref17
  publication-title: J. org. Chem.
  doi: 10.1021/jo01029a042
  contributor:
    fullname: Moore R. A.
SSID ssj0007887
Score 1.836115
Snippet Two series of ortho-metallated palladium imine complexes are reported that contain a coordinated β-diketonate group. In one group the chain length of the imine...
SourceID crossref
informaworld
SourceType Aggregation Database
Enrichment Source
Publisher
StartPage 1437
Title Possible transition from rod-like to disc-like behaviour in ortho-metallated imine complexes of palladium(II): crystal and molecular structure of three palladium complexes
URI https://www.tandfonline.com/doi/abs/10.1080/02678290500160753
Volume 32
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3bjtMwELX2InF5QLCwotzkB5CAKFXrxLnwtiqL2hU3ia5Y8VIlsS1FtMnSptLCE5_At_BJfAkzceIkZRexvEStHU_azul4bJ-ZIeSxYKFIYNqxfXCPbTdi0o4cL7AlV0HsCwnAxgDnN2-98bF7dMJPtravtFhL6yLuJ9_OjSv5H61CG-gVo2QvoVkjFBrgNegXrqBhuP6Tjt_niOi5xEIPmSZf6XgRsIqGxTBPP5flMTD-tttYheivkZFu4flNbpkbFrLALXb0R7Hul9Tcc3mmc9SeYp9IsUZyMJk8YSFuLCTLr6uiSj2wqKvuWjpBLR5TlGyEpZTN6EZo20d-nX5Zp6IWZ3z-d4usPNUPVnU8d4uzMyq7DpfJuiTupvlSzhvEFkgYXRk6sjXtm3F5VfP7A2A2s476nV0QXoUDNsaSgcEPmK6r15famDueZ8NyiLetfbObiqge2hWJW5tvcB79lisAi03_3Gmm4mXCM_EcmpfFun2d9Lib0ntjqjUEyGGdmXVTxDbZZWAywVbvHoxffvpovApkfer9Qv096xN6zBO_KaTjY3Uy8LZ8p-lNcqNa9NADjeBbZEtme-TqqK41uEeut9Ji3iY_a1zTBtcUcU0B17--_0Dw0iKniOj6rcEyTTNaYplCV4NiWqKYGsDRXFGDw6eTybMXtAIcBfxSg19q8IsjSvw24xpxd8jxq8PpaGxXtUXsxHG9wsbTeenFkokkFDL0giAGRzpmaqAki9kQ7Fc45HE8SBwxUL4P85rLlMOFVMNYwRppn-xkeSbvEqoUZzwaCIH3wOojiFzBHVeFKokCqdweeV5rY3aqU8jMLtR_jwza-poV5b6d0kV2_rx9VpwVPcL_MsS58FH3LvO57pNrzd_uAdmB314-BHe8iB9VSP0NFZvd6w
link.rule.ids 315,783,787,27936,27937,60214,61003
linkProvider Library Specific Holdings
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwEB5BORQOFAqIbXn4wAGQ3GadOJtwqyqqXWhXHFqptyiOx9Kqu5tq65VK_xJ_sjNxQrflcegx8iOxPJ75MjP-BuCDVbmtyOzIAcFjmZQKZRmnmUTtMjOwSILNF5yPxunwJPl2qk9bh9tFm1bJ_9AuEEU0upoPNzuju5S4Xa6axAFA3VRJJsD9EB6lTP7FVzii8W9NzJlywcdCmljlqotq_m2KW3bpFmvpir052ICi-9KQZnK2s_Rmp7q6Q-J4_6U8g6ctFBV7QXaewwOcb8L6flcBbhOerJAVvoBfP2o-P1MUnu1bk-ol-HaKIB0sp5MzaqgF3_INDy0BwHIhJnPB0aFaztCz355AruBiYiiahHa8xAtRO3HObXaynH0cjT59EdXiJyHXqaC1iVlXxFcEvtvlAnmEJ0HEm3E3072Ek4Ovx_tD2ZZ6kFWcpF5ysBRTg8pWucU8zTJDuMYoFzlURvVJnPK-NiaqYhu5wYDUTKJcrC26vnEEWV_B2rye42sQzmmly8ha7kNgMCsTq-PE5a4qM3RJDz53G12cB0aPot8Rpd7djR5Eq6JQ-MaN4kLNkz-7F_7S90D_Z0j8z1dt3XPce1gfHh8dFoej8fdteByoZdlF9AbWaEvwLYEmb941J-Ma6ScP0w
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9QwEB5BkXgceBQQ2xbwgQMguWSdOJtwqwqrLo9VD1TqLYrjsbTq7ma165UKf4k_yUyc0G15HHqMnHFkeTzzxTPzDcArq3JbkduRA4LHMikVyjJOM4naZWZgkRSbC5y_jtOjk-TTqT5tc3NWbVol_0O7QBTR2Go-3Avruoy4d9w0ieN_ummSTHj7JtwiFBCxmsfR-Lch5kS5cMVChljlqgtq_m2KS27pEmnphrsZPgg9VVcNSyFnmZztr73Zr35c4XC89koewv0WiIqDoDmP4AbOt-HOYdf_bRvubVAVPoafxzWfnikKz96tSfQSXJsiyALL6eSMBmrBNb7hoS3_Xy_FZC44NlTLGXq-tSeIK7iVGIomnR3PcSVqJxY8Zifr2evR6M17US2_E26dClqamHUtfEVgu10vkSU8qSFeyF1M9wROhh-_HR7JttGDrOIk9ZJDpZgaVLbKLeZplhlCNUa5yKEyqk_KlPe1MVEV28gNBmRkEuVibdH1jSPA-hS25vUcn4FwTitdRtbyOwQFszKxOk5c7qoyQ5f04G23z8Ui8HkU_Y4m9epu9CDa1ITCN5coLnQ8-fP1wp_7Huj_iMT__NTONeVewu3jD8Piy2j8eRfuBl5Zvh_agy3aEXxOiMmbF825-AWnjw6A
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Possible+transition+from+rod%E2%80%90like+to+disc%E2%80%90like+behaviour+in+ortho+%E2%80%90metallated+imine+complexes+of+palladium%28II%29%3A+crystal+and+molecular+structure+of+three+palladium+complexes&rft.jtitle=Liquid+crystals&rft.au=Omn%C3%A8s%2C+Laurent&rft.au=C%C3%AErcu%2C+Viorel&rft.au=Hutchins%2C+Peter+T.&rft.au=Coles%2C+Simon+J.&rft.date=2005-11-01&rft.issn=0267-8292&rft.eissn=1366-5855&rft.volume=32&rft.issue=11-12&rft.spage=1437&rft.epage=1447&rft_id=info:doi/10.1080%2F02678290500160753&rft.externalDBID=n%2Fa&rft.externalDocID=10_1080_02678290500160753
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0267-8292&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0267-8292&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0267-8292&client=summon