Phase behaviors in a binary mixture of diblock copolymers confined between two parallel walls
The phase behaviors in a binary mixture of diblock copolymers confined between two parallel walls are investigated by using a cell dynamics simulation of the time-dependent Ginzburg-Landau theory.The morphological dependence of the wall-block interaction and the distance between walls(confinement de...
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Published in | Chinese physics B Vol. 22; no. 2; pp. 372 - 380 |
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Format | Journal Article |
Language | English |
Published |
01.02.2013
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Online Access | Get full text |
ISSN | 1674-1056 2058-3834 1741-4199 |
DOI | 10.1088/1674-1056/22/2/026401 |
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Abstract | The phase behaviors in a binary mixture of diblock copolymers confined between two parallel walls are investigated by using a cell dynamics simulation of the time-dependent Ginzburg-Landau theory.The morphological dependence of the wall-block interaction and the distance between walls(confinement degree) has been systematically studied,and the effect of repulsive interactions between different monomers is also discussed.It is interesting that multiple novel morphological transitions are observed by changing these factors,and various multilayered sandwich structures are formed in the mixture.Furthermore,the parametric dependence and physical reasons for the microdomain growth and orientational order transitions are discussed.From the simulation,we find that much richer morphologies can form in a binary mixture of diblock copolymers than those in a pure diblock copolymer.Our results provide an insight into the phase behaviors under parallel wall confinement and may provide guidance for experimentalists.This model system can also give a simple way to realize orientational order transition in soft materials through confinement. |
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AbstractList | The phase behaviors in a binary mixture of diblock copolymers confined between two parallel walls are investigated by using a cell dynamics simulation of the time-dependent Ginzburg-Landau theory.The morphological dependence of the wall-block interaction and the distance between walls(confinement degree) has been systematically studied,and the effect of repulsive interactions between different monomers is also discussed.It is interesting that multiple novel morphological transitions are observed by changing these factors,and various multilayered sandwich structures are formed in the mixture.Furthermore,the parametric dependence and physical reasons for the microdomain growth and orientational order transitions are discussed.From the simulation,we find that much richer morphologies can form in a binary mixture of diblock copolymers than those in a pure diblock copolymer.Our results provide an insight into the phase behaviors under parallel wall confinement and may provide guidance for experimentalists.This model system can also give a simple way to realize orientational order transition in soft materials through confinement. The phase behaviors in a binary mixture of diblock copolymers confined between two parallel walls are investigated by using a cell dynamics simulation of the time-dependent Ginzburg-Landau theory. The morphological dependence of the wall-block interaction and the distance between walls (confinement degree) has been systematically studied, and the effect of repulsive interactions between different monomers is also discussed. It is interesting that multiple novel morphological transitions are observed by changing these factors, and various multilayered sandwich structures are formed in the mixture. Furthermore, the parametric dependence and physical reasons for the microdomain growth and orientational order transitions are discussed. From the simulation, we find that much richer morphologies can form in a binary mixture of diblock copolymers than those in a pure diblock copolymer. Our results provide an insight into the phase behaviors under parallel wall confinement and may provide guidance for experimentalists. This model system can also give a simple way to realize orientational order transition in soft materials through confinement. |
Author | 潘俊星 张进军 王宝凤 武海顺 孙敏娜 |
AuthorAffiliation | School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004, China |
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Notes | Pan Jun-Xing , Zhang Jin-Jun , Wang Bao-Feng , Wu Hai-Shun , Sun Min-Na( School of Chemistry and Materials Science, Shanxi Normal University, Linfen 041004, China) 11-5639/O4 parallel walls confinement,phase behavior,binary mixture,diblock copolymer The phase behaviors in a binary mixture of diblock copolymers confined between two parallel walls are investigated by using a cell dynamics simulation of the time-dependent Ginzburg-Landau theory.The morphological dependence of the wall-block interaction and the distance between walls(confinement degree) has been systematically studied,and the effect of repulsive interactions between different monomers is also discussed.It is interesting that multiple novel morphological transitions are observed by changing these factors,and various multilayered sandwich structures are formed in the mixture.Furthermore,the parametric dependence and physical reasons for the microdomain growth and orientational order transitions are discussed.From the simulation,we find that much richer morphologies can form in a binary mixture of diblock copolymers than those in a pure diblock copolymer.Our results provide an insight into the phase behaviors under parallel wall confinement and may provide guidance for experimentalists.This model system can also give a simple way to realize orientational order transition in soft materials through confinement. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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SubjectTerms | Binary mixtures Computer simulation Confinement Copolymers Dynamic tests Ginzburg-Landau理论 Monomers Simulation Walls 二元混合物 取向有序 墙壁 嵌段共聚物 平行 模型系统 相行为 |
Title | Phase behaviors in a binary mixture of diblock copolymers confined between two parallel walls |
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