Wettability alteration of carbonate rocks by surfactants: A mechanistic study

• Published in: Colloids and surfaces. A, Physicochemical and engineering aspects Vol. 410; pp. 1 - 10
• Main Authors: Jarrahian, Kh, Seiedi, O., Sheykhan, M., Sefti, M. Vafaie, Ayatollahi, Sh
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 20.09.2012
• Subjects: Carbonate; Carbonates; FTIR; Reserves; Reservoirs; Rock; Rocks; Stearic acid; Surfactant; Surfactants; TGA; Wettability; Wettability alteration; Zeta potential; Carbonate; Wettability alteration; Surfactant; Zeta potential; FTIR; TGA
• ISSN: 0927-7757; 1873-4359
• DOI: 10.1016/j.colsurfa.2012.06.007

Thermo gravimetric analysis for pure dolomite and treated surfaces with different surfactant solutions at 0.3wt.%. [Display omitted] ► A mechanistic study on wettability alteration during surfactant flooding was presented. ► This study was implemented on carbonate rocks with different analytical instruments. ► The role of surfactants’ structure in wetting change process was reported. ► Cationic surfactant is more effective in changing the wettability of dolomite rock. ► C12TAB irreversibly desorbs stearic acid from dolomite surface via ionic interaction. A considerable quantity of the world's oil reserve is located in naturally fractured carbonate reservoirs, with very low oil recovery efficiency, due to their wettability and tightness of matrixes. Recovery efficiency can be improved considerably, if the reservoir rock wettability is changed from mostly oil-wet to water-wet, thus enhancing water imbibition into the oil saturated rock. In this experimental work, an extensive mechanistic study is performed utilizing different analytical tools to study the effects of surfactants on the sample rock's wettability. The results indicate that the surfactants act in different manners according to their structure. Cationic surfactant C12TAB, tends to irreversibly desorb stearic acid from the dolomite surface via ionic interaction. Nonionic surfactant TritonX-100 is adsorbed on the surface by the polarization of π electrons and ion exchange, releasing more stearic acid from the solid surface. The released stearic acid is then adsorbed as a new layer on the surface, through hydrophobic interaction between the tail of adsorbed surfactants and the non-polar part of the stearic acid. Anionic surfactants, such as SDS, are adsorbed on the surface via hydrophobic interaction between the tail of surfactant and the adsorbed acid, thus changing the wettability of the surface to a neutral wet condition.