Electrochemical behaviour of some 3-methylthio-1,2-dithiolium cations in dimethylformamide solution
Substituted 3-methylthio-1,2-dithiolium cations were prepared by alkylation of the corresponding 1,2-dithiole-3-thiones. These compounds were easily reduced in DMF at a mercury electrode, following two one-electron waves. Electrolysis, carried out at a mercury pool electrode and followed by an alkyl...
Saved in:
| Published in | Electrochimica acta Vol. 50; no. 11; pp. 2219 - 2225 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Oxford
Elsevier Ltd
01.04.2005
Elsevier |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Substituted 3-methylthio-1,2-dithiolium cations were prepared by alkylation of the corresponding 1,2-dithiole-3-thiones. These compounds were easily reduced in DMF at a mercury electrode, following two one-electron waves. Electrolysis, carried out at a mercury pool electrode and followed by an alkylation or an acylation, provided the corresponding alkyl (or acyl) dithioesters and by-products. At a platinum or glassy carbon electrode the reduction was an irreversible process, which was dependent upon the cathode nature. Whatever the electrode, the reduction was a combination of two reactions, a two-electron reduction and a one-electron one involving a dimerization. The electrochemical behaviour of 3-methylthio-1,2-dithiolium cations exhibited many analogies with the cathodic behaviour of the corresponding 1,2-dithiole-3-thiones. Moreover, identical intermediates were implicated in the reduction of 3-methylthio-1,2-dithiolium cations and in the reductive alkylation of 1,2-dithiole-3-thiones. |
|---|---|
| AbstractList | Substituted 3-methylthio-1,2-dithiolium cations were prepared by alkylation of the corresponding 1,2-dithiole-3-thiones. These compounds were easily reduced in DMF at a mercury electrode, following two one-electron waves. Electrolysis, carried out at a mercury pool electrode and followed by an alkylation or an acylation, provided the corresponding alkyl (or acyl) dithioesters and by-products. At a platinum or glassy carbon electrode the reduction was an irreversible process, which was dependent upon the cathode nature. Whatever the electrode, the reduction was a combination of two reactions, a two-electron reduction and a one-electron one involving a dimerization. The electrochemical behaviour of 3-methylthio-1,2-dithiolium cations exhibited many analogies with the cathodic behaviour of the corresponding 1,2-dithiole-3-thiones. Moreover, identical intermediates were implicated in the reduction of 3-methylthio-1,2-dithiolium cations and in the reductive alkylation of 1,2-dithiole-3-thiones. |
| Author | Darchen, André Burgot, Jean-Louis Saidi, Mokhtar Abasq, Marie-Laurence |
| Author_xml | – sequence: 1 givenname: Marie-Laurence surname: Abasq fullname: Abasq, Marie-Laurence email: Marie-Laurence.Abasq@univ-rennes1.fr organization: Laboratoire de Chimie Analytique, U.F.R. des Sciences Pharmaceutiques et Biologiques, Université de Rennes I, 2 Avenue du Professeur Léon Bernard, 35043 Rennes cedex, France – sequence: 2 givenname: Jean-Louis surname: Burgot fullname: Burgot, Jean-Louis organization: Laboratoire de Chimie Analytique, U.F.R. des Sciences Pharmaceutiques et Biologiques, Université de Rennes I, 2 Avenue du Professeur Léon Bernard, 35043 Rennes cedex, France – sequence: 3 givenname: André surname: Darchen fullname: Darchen, André organization: Laboratoire d’Electrochimie, Ecole Nationale Supérieure de Chimie de Rennes, Avenue du Général Leclerc, 35700 Rennes, France – sequence: 4 givenname: Mokhtar surname: Saidi fullname: Saidi, Mokhtar organization: Laboratoire de Valorisation et Promotion des Ressources Sahariennes, Université de Ouargla, 30000 Ouargla, Algérie |
| BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16603425$$DView record in Pascal Francis |
| BookMark | eNqFkM1qwzAQhEVJoUnaZ6gvvdXuSrJl-xhC-gOBXnI3irTCCrYVJKeQt6-MS3ssCEbanW_FzoosBjcgIY8UMgpUvJwy7FCNMp6MAeSxmkW5IUtalTzlVVEvyBKA8jQXlbgjqxBOAFCKEpZE7SbYO9Vib5XskiO28su6i0-cSYLrMeFpj2N77cbWupQ-s1Tb6drZS58oOVo3hMQOibazzTjfy95qjHR3mdr35NbILuDDj67J4XV32L6n-8-3j-1mnyqeF2PKBFOFEMcadCWM4HUVX1qVVHEtuDmaMlecoqCKsYqVUGMOoFGWUKDBmq9JOY9V3oXg0TRnb3vprw2FZoqqOTW_UTVTVFMjSiSfZvIsQ8zAeDkoG_5wIYDnrIi-zezDuMWXRd8EZXFQqK2Pcxvt7L9_fQPYB4ao |
| CODEN | ELCAAV |
| CitedBy_id | crossref_primary_10_1016_j_jorganchem_2008_10_002 crossref_primary_10_1021_om1007105 |
| Cites_doi | 10.1002/zfch.19690090208 10.1149/1.2115429 10.1080/10426509008038053 10.1006/abbi.2000.2022 10.1135/cccc19740861 10.1021/ja00794a038 10.3891/acta.chem.scand.28b-0827 10.1016/S0040-4020(01)93534-3 10.1093/jnci/94.13.1001 10.1016/S0040-4020(01)87440-8 10.1016/S0040-4020(01)80483-X 10.1016/0022-0728(90)80024-Z 10.1016/0076-6879(95)52035-X 10.1016/S0013-4686(02)00481-4 10.1016/0368-1874(84)87066-5 10.1002/jhet.5570230569 10.1016/0076-6879(95)52034-1 10.1016/S0022-0728(02)01262-7 10.1039/c39720000430 10.1021/ja01621a027 10.1016/S0040-4039(01)84434-8 10.1016/S0022-0728(83)80592-0 10.1080/01961779508048738 10.1016/S0040-4020(01)97002-4 10.1016/S0040-4039(01)84433-6 |
| ContentType | Journal Article |
| Copyright | 2004 Elsevier Ltd 2005 INIST-CNRS |
| Copyright_xml | – notice: 2004 Elsevier Ltd – notice: 2005 INIST-CNRS |
| DBID | IQODW AAYXX CITATION |
| DOI | 10.1016/j.electacta.2004.10.004 |
| DatabaseName | Pascal-Francis CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Chemistry |
| EISSN | 1873-3859 |
| EndPage | 2225 |
| ExternalDocumentID | 10_1016_j_electacta_2004_10_004 16603425 S0013468604009636 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 29G 4.4 41~ 457 4G. 53G 5GY 5VS 7-5 71M 8P~ 9JN AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABEFU ABFNM ABFRF ABJNI ABMAC ABNUV ABTAH ABXDB ABYKQ ACBEA ACDAQ ACGFO ACGFS ACIWK ACNCT ACNNM ACRLP ADBBV ADECG ADEWK ADEZE ADIYS ADMUD AEBSH AEFWE AEKER AENEX AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHPOS AI. AIDUJ AIEXJ AIKHN AITUG AJBFU AJOXV AJQLL AJSZI AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD ENUVR EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HMU HVGLF HZ~ H~9 IHE J1W KOM LPU M36 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SC5 SCB SCH SDF SDG SDP SES SEW SPC SPCBC SSG SSK SSZ T5K T9H TWZ UPT VH1 WH7 WUQ XFK XOL XPP YK3 ZMT ZY4 ~02 ~G- 08R ABPIF ABPTK IQODW VOH AAXKI AAYXX AFJKZ AKRWK CITATION |
| ID | FETCH-LOGICAL-c345t-262c566b90d86f6398566dc71c3d63fbf74c31e61c2282709e400dea705efe93 |
| IEDL.DBID | AIKHN |
| ISSN | 0013-4686 |
| IngestDate | Thu Sep 26 16:56:54 EDT 2024 Sun Oct 29 17:07:14 EDT 2023 Fri Feb 23 02:28:14 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 11 |
| Keywords | Anethole dithiolethione Cyclic voltammetry Sulfarlem Dimerization Ring opening Organic solvent Organic cation N,N-Dimethylformamide Reaction mechanism Electrochemical reaction Ring cleavage |
| Language | English |
| License | CC BY 4.0 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c345t-262c566b90d86f6398566dc71c3d63fbf74c31e61c2282709e400dea705efe93 |
| PageCount | 7 |
| ParticipantIDs | crossref_primary_10_1016_j_electacta_2004_10_004 pascalfrancis_primary_16603425 elsevier_sciencedirect_doi_10_1016_j_electacta_2004_10_004 |
| PublicationCentury | 2000 |
| PublicationDate | 2005-04-01 |
| PublicationDateYYYYMMDD | 2005-04-01 |
| PublicationDate_xml | – month: 04 year: 2005 text: 2005-04-01 day: 01 |
| PublicationDecade | 2000 |
| PublicationPlace | Oxford |
| PublicationPlace_xml | – name: Oxford |
| PublicationTitle | Electrochimica acta |
| PublicationYear | 2005 |
| Publisher | Elsevier Ltd Elsevier |
| Publisher_xml | – name: Elsevier Ltd – name: Elsevier |
| References | Kuntz, Hartman, Mayer (bib9) 1969 Burgot, Darchen, Saidi (bib21) 2002; 48 Pedersen, Moller (bib27) 1974; 30 Halpern, Gaudin (bib1) 1950; 83 Häusler, Ritschard (bib2) 1979; 68 Astruc, Astruc, Gonbeau, Pfister-Guillouzo (bib10) 1974; 39 Moiroux, Deycard (bib15) 1984; 131 Largeron, Fleury, Fleury (bib18) 1986; 42 Maignan, Vialle (bib33) 1973 Bryce, Davison, Moore, Hursthouse, Abdul Malik (bib29) 1992; 48 Lam, Macaulay, Leriche, Dyachkova, Coldman, Guillaud, Hawk, Christen, Gadzar (bib3) 2002; 94 Pedersen (bib28) 1974; 13 Abazid, Burgot, Darchen, Saidi (bib19) 1990; 53 Guimon, Gonbeau, Pfister-Guillouso, Bechgaard, Pedersen (bib26) 1973; 29 Amatore, Azzabi, Calas, Jutand, Lefrou, Rollin (bib36) 1990; 288 Largeron, Fleury, Fleury (bib16) 1984; 197 Amatore, Jutand, Thouin, Verpeaux (bib35) 1998; 8–9 Pedersen (bib13) 1982 Darchen, Berthelot, Vaccher, Viana, Debaert, Burgot (bib17) 1986; 23 Pedersen, Bechgaard, Parker (bib23) 1972 Böttcher, Bauer (bib30) 1951; 5–6 Christen, Fackir, Jore (bib6) 1995; 252 M. Saidi, Thesis, Rennes, 1988. Lam, Macaulay, Leriche, Dyachkova, Coldman, Guillaud, Hawk, Christen, Gadzar (bib4) 2003 Christen (bib5) 1995; 252 Bechgaard, Parker, Pedersen (bib25) 1973; 95 Abasq, Burgot, Darchen, Dervout (bib22) 2002; 537 Fields (bib32) 1955; 77 Levron, Burgot, Burgot (bib7) 2000; 382 Starka, Jirousek (bib8) 1959; 14 Pedersen, Parker (bib11) 1972 Moiroux, Deycard, Fleury (bib14) 1983; 146 Pedersen, Parker (bib24) 1972; 9 Pedersen (bib20) 1995; 16 Iversen, Lund (bib12) 1974; 28 Thuillier, Vialle (bib31) 1959 Moiroux (10.1016/j.electacta.2004.10.004_bib14) 1983; 146 Amatore (10.1016/j.electacta.2004.10.004_bib35) 1998; 8–9 Halpern (10.1016/j.electacta.2004.10.004_bib1) 1950; 83 Largeron (10.1016/j.electacta.2004.10.004_bib16) 1984; 197 Levron (10.1016/j.electacta.2004.10.004_bib7) 2000; 382 Largeron (10.1016/j.electacta.2004.10.004_bib18) 1986; 42 Darchen (10.1016/j.electacta.2004.10.004_bib17) 1986; 23 10.1016/j.electacta.2004.10.004_bib34 Häusler (10.1016/j.electacta.2004.10.004_bib2) 1979; 68 Christen (10.1016/j.electacta.2004.10.004_bib6) 1995; 252 Burgot (10.1016/j.electacta.2004.10.004_bib21) 2002; 48 Starka (10.1016/j.electacta.2004.10.004_bib8) 1959; 14 Pedersen (10.1016/j.electacta.2004.10.004_bib27) 1974; 30 Lam (10.1016/j.electacta.2004.10.004_bib4) 2003 Fields (10.1016/j.electacta.2004.10.004_bib32) 1955; 77 Pedersen (10.1016/j.electacta.2004.10.004_bib11) 1972 Iversen (10.1016/j.electacta.2004.10.004_bib12) 1974; 28 Pedersen (10.1016/j.electacta.2004.10.004_bib20) 1995; 16 Pedersen (10.1016/j.electacta.2004.10.004_bib13) 1982 Böttcher (10.1016/j.electacta.2004.10.004_bib30) 1951; 5–6 Abasq (10.1016/j.electacta.2004.10.004_bib22) 2002; 537 Maignan (10.1016/j.electacta.2004.10.004_bib33) 1973 Pedersen (10.1016/j.electacta.2004.10.004_bib28) 1974; 13 Abazid (10.1016/j.electacta.2004.10.004_bib19) 1990; 53 Guimon (10.1016/j.electacta.2004.10.004_bib26) 1973; 29 Amatore (10.1016/j.electacta.2004.10.004_bib36) 1990; 288 Bechgaard (10.1016/j.electacta.2004.10.004_bib25) 1973; 95 Thuillier (10.1016/j.electacta.2004.10.004_bib31) 1959 Astruc (10.1016/j.electacta.2004.10.004_bib10) 1974; 39 Pedersen (10.1016/j.electacta.2004.10.004_bib24) 1972; 9 Lam (10.1016/j.electacta.2004.10.004_bib3) 2002; 94 Christen (10.1016/j.electacta.2004.10.004_bib5) 1995; 252 Pedersen (10.1016/j.electacta.2004.10.004_bib23) 1972 Kuntz (10.1016/j.electacta.2004.10.004_bib9) 1969 Moiroux (10.1016/j.electacta.2004.10.004_bib15) 1984; 131 Bryce (10.1016/j.electacta.2004.10.004_bib29) 1992; 48 |
| References_xml | – volume: 252 start-page: 324 year: 1995 ident: bib6 publication-title: Methods Enzymol. contributor: fullname: Jore – volume: 30 start-page: 553 year: 1974 ident: bib27 publication-title: Tetrahedron Lett. contributor: fullname: Moller – volume: 197 start-page: 183 year: 1984 ident: bib16 publication-title: J. Electroanal. Chem. contributor: fullname: Fleury – volume: 48 start-page: 8143 year: 1992 ident: bib29 publication-title: Tetrahedron contributor: fullname: Abdul Malik – volume: 16 start-page: 173 year: 1995 ident: bib20 publication-title: Sulfur Rep. contributor: fullname: Pedersen – volume: 131 start-page: 2840 year: 1984 ident: bib15 publication-title: J. Electrochem. Soc. contributor: fullname: Deycard – volume: 9 start-page: 767 year: 1972 ident: bib24 publication-title: Tetrahedron Lett. contributor: fullname: Parker – volume: 14 start-page: 173 year: 1959 ident: bib8 publication-title: Pharmazie contributor: fullname: Jirousek – volume: 537 start-page: 145 year: 2002 ident: bib22 publication-title: J. Electroanal. Chem. contributor: fullname: Dervout – start-page: 430 year: 1972 ident: bib23 publication-title: J. Chem. Soc., Chem. Comm. contributor: fullname: Parker – volume: 8–9 start-page: 43 year: 1998 ident: bib35 publication-title: L’actualité chimique contributor: fullname: Verpeaux – volume: 39 start-page: 861 year: 1974 ident: bib10 publication-title: Collect. Czech. Chem. Commun. contributor: fullname: Pfister-Guillouzo – volume: 77 start-page: 4255 year: 1955 ident: bib32 publication-title: J. Am. Chem. Soc. contributor: fullname: Fields – volume: 382 start-page: 189 year: 2000 ident: bib7 publication-title: Arch. Biochem. Biophys. contributor: fullname: Burgot – volume: 83 start-page: 49 year: 1950 ident: bib1 publication-title: Arch. Int. Pharmacol. contributor: fullname: Gaudin – volume: 42 start-page: 409 year: 1986 ident: bib18 publication-title: Tetrahedron contributor: fullname: Fleury – start-page: 771 year: 1972 ident: bib11 publication-title: Tetrahedron Lett. contributor: fullname: Parker – start-page: 60 year: 1969 ident: bib9 publication-title: Z. Chem. contributor: fullname: Mayer – start-page: 1398 year: 1959 ident: bib31 publication-title: Bull. Soc. Chim. Fr. contributor: fullname: Vialle – volume: 13 start-page: 349 year: 1974 ident: bib28 publication-title: Angew. Chem. Int. Ed. contributor: fullname: Pedersen – start-page: 1973 year: 1973 ident: bib33 publication-title: Bull. Soc. Chim. Fr. contributor: fullname: Vialle – volume: 23 start-page: 1603 year: 1986 ident: bib17 publication-title: J. Heterocycl. Chem. contributor: fullname: Burgot – volume: 68 start-page: 1063 year: 1979 ident: bib2 publication-title: Praxis contributor: fullname: Ritschard – volume: 94 start-page: 1001 year: 2002 ident: bib3 publication-title: J. Nat. Cancer Inst. contributor: fullname: Gadzar – volume: 28 start-page: 827 year: 1974 ident: bib12 publication-title: Acta Chem. Scand. Ser. B contributor: fullname: Lund – year: 2003 ident: bib4 publication-title: PCT Int. Appl. contributor: fullname: Gadzar – volume: 53 start-page: 425 year: 1990 ident: bib19 publication-title: Phosphorus Sulfur Silicon Rel. Elem. contributor: fullname: Saidi – volume: 146 start-page: 313 year: 1983 ident: bib14 publication-title: J. Electroanal. Chem. contributor: fullname: Fleury – volume: 288 start-page: 45 year: 1990 ident: bib36 publication-title: J. Electroanal. Chem. contributor: fullname: Rollin – volume: 48 start-page: 107 year: 2002 ident: bib21 publication-title: Electrochem. Acta contributor: fullname: Saidi – volume: 95 start-page: 4373 year: 1973 ident: bib25 publication-title: J. Am. Chem. Soc. contributor: fullname: Pedersen – volume: 5–6 start-page: 458 year: 1951 ident: bib30 publication-title: Ann. Chem. contributor: fullname: Bauer – volume: 252 start-page: 316 year: 1995 ident: bib5 publication-title: Methods Enzymol. contributor: fullname: Christen – volume: 29 start-page: 3695 year: 1973 ident: bib26 publication-title: Tetrahedron contributor: fullname: Pedersen – year: 1982 ident: bib13 article-title: Advances in Heterocylic Chemistry contributor: fullname: Pedersen – start-page: 60 year: 1969 ident: 10.1016/j.electacta.2004.10.004_bib9 publication-title: Z. Chem. doi: 10.1002/zfch.19690090208 contributor: fullname: Kuntz – volume: 131 start-page: 2840 year: 1984 ident: 10.1016/j.electacta.2004.10.004_bib15 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2115429 contributor: fullname: Moiroux – volume: 5–6 start-page: 458 year: 1951 ident: 10.1016/j.electacta.2004.10.004_bib30 publication-title: Ann. Chem. contributor: fullname: Böttcher – volume: 53 start-page: 425 year: 1990 ident: 10.1016/j.electacta.2004.10.004_bib19 publication-title: Phosphorus Sulfur Silicon Rel. Elem. doi: 10.1080/10426509008038053 contributor: fullname: Abazid – volume: 13 start-page: 349 year: 1974 ident: 10.1016/j.electacta.2004.10.004_bib28 publication-title: Angew. Chem. Int. Ed. contributor: fullname: Pedersen – volume: 382 start-page: 189 year: 2000 ident: 10.1016/j.electacta.2004.10.004_bib7 publication-title: Arch. Biochem. Biophys. doi: 10.1006/abbi.2000.2022 contributor: fullname: Levron – volume: 39 start-page: 861 year: 1974 ident: 10.1016/j.electacta.2004.10.004_bib10 publication-title: Collect. Czech. Chem. Commun. doi: 10.1135/cccc19740861 contributor: fullname: Astruc – volume: 95 start-page: 4373 year: 1973 ident: 10.1016/j.electacta.2004.10.004_bib25 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00794a038 contributor: fullname: Bechgaard – volume: 83 start-page: 49 year: 1950 ident: 10.1016/j.electacta.2004.10.004_bib1 publication-title: Arch. Int. Pharmacol. contributor: fullname: Halpern – volume: 68 start-page: 1063 year: 1979 ident: 10.1016/j.electacta.2004.10.004_bib2 publication-title: Praxis contributor: fullname: Häusler – volume: 28 start-page: 827 year: 1974 ident: 10.1016/j.electacta.2004.10.004_bib12 publication-title: Acta Chem. Scand. Ser. B doi: 10.3891/acta.chem.scand.28b-0827 contributor: fullname: Iversen – volume: 29 start-page: 3695 year: 1973 ident: 10.1016/j.electacta.2004.10.004_bib26 publication-title: Tetrahedron doi: 10.1016/S0040-4020(01)93534-3 contributor: fullname: Guimon – volume: 94 start-page: 1001 year: 2002 ident: 10.1016/j.electacta.2004.10.004_bib3 publication-title: J. Nat. Cancer Inst. doi: 10.1093/jnci/94.13.1001 contributor: fullname: Lam – volume: 42 start-page: 409 year: 1986 ident: 10.1016/j.electacta.2004.10.004_bib18 publication-title: Tetrahedron doi: 10.1016/S0040-4020(01)87440-8 contributor: fullname: Largeron – volume: 48 start-page: 8143 year: 1992 ident: 10.1016/j.electacta.2004.10.004_bib29 publication-title: Tetrahedron doi: 10.1016/S0040-4020(01)80483-X contributor: fullname: Bryce – year: 1982 ident: 10.1016/j.electacta.2004.10.004_bib13 contributor: fullname: Pedersen – volume: 288 start-page: 45 year: 1990 ident: 10.1016/j.electacta.2004.10.004_bib36 publication-title: J. Electroanal. Chem. doi: 10.1016/0022-0728(90)80024-Z contributor: fullname: Amatore – volume: 252 start-page: 324 year: 1995 ident: 10.1016/j.electacta.2004.10.004_bib6 publication-title: Methods Enzymol. doi: 10.1016/0076-6879(95)52035-X contributor: fullname: Christen – year: 2003 ident: 10.1016/j.electacta.2004.10.004_bib4 publication-title: PCT Int. Appl. contributor: fullname: Lam – volume: 48 start-page: 107 year: 2002 ident: 10.1016/j.electacta.2004.10.004_bib21 publication-title: Electrochem. Acta doi: 10.1016/S0013-4686(02)00481-4 contributor: fullname: Burgot – volume: 197 start-page: 183 year: 1984 ident: 10.1016/j.electacta.2004.10.004_bib16 publication-title: J. Electroanal. Chem. doi: 10.1016/0368-1874(84)87066-5 contributor: fullname: Largeron – volume: 23 start-page: 1603 year: 1986 ident: 10.1016/j.electacta.2004.10.004_bib17 publication-title: J. Heterocycl. Chem. doi: 10.1002/jhet.5570230569 contributor: fullname: Darchen – ident: 10.1016/j.electacta.2004.10.004_bib34 – volume: 252 start-page: 316 year: 1995 ident: 10.1016/j.electacta.2004.10.004_bib5 publication-title: Methods Enzymol. doi: 10.1016/0076-6879(95)52034-1 contributor: fullname: Christen – volume: 537 start-page: 145 year: 2002 ident: 10.1016/j.electacta.2004.10.004_bib22 publication-title: J. Electroanal. Chem. doi: 10.1016/S0022-0728(02)01262-7 contributor: fullname: Abasq – start-page: 430 year: 1972 ident: 10.1016/j.electacta.2004.10.004_bib23 publication-title: J. Chem. Soc., Chem. Comm. doi: 10.1039/c39720000430 contributor: fullname: Pedersen – volume: 77 start-page: 4255 year: 1955 ident: 10.1016/j.electacta.2004.10.004_bib32 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01621a027 contributor: fullname: Fields – start-page: 771 year: 1972 ident: 10.1016/j.electacta.2004.10.004_bib11 publication-title: Tetrahedron Lett. doi: 10.1016/S0040-4039(01)84434-8 contributor: fullname: Pedersen – volume: 8–9 start-page: 43 year: 1998 ident: 10.1016/j.electacta.2004.10.004_bib35 publication-title: L’actualité chimique contributor: fullname: Amatore – volume: 14 start-page: 173 year: 1959 ident: 10.1016/j.electacta.2004.10.004_bib8 publication-title: Pharmazie contributor: fullname: Starka – start-page: 1398 year: 1959 ident: 10.1016/j.electacta.2004.10.004_bib31 publication-title: Bull. Soc. Chim. Fr. contributor: fullname: Thuillier – volume: 146 start-page: 313 year: 1983 ident: 10.1016/j.electacta.2004.10.004_bib14 publication-title: J. Electroanal. Chem. doi: 10.1016/S0022-0728(83)80592-0 contributor: fullname: Moiroux – volume: 16 start-page: 173 year: 1995 ident: 10.1016/j.electacta.2004.10.004_bib20 publication-title: Sulfur Rep. doi: 10.1080/01961779508048738 contributor: fullname: Pedersen – volume: 30 start-page: 553 year: 1974 ident: 10.1016/j.electacta.2004.10.004_bib27 publication-title: Tetrahedron Lett. doi: 10.1016/S0040-4020(01)97002-4 contributor: fullname: Pedersen – volume: 9 start-page: 767 year: 1972 ident: 10.1016/j.electacta.2004.10.004_bib24 publication-title: Tetrahedron Lett. doi: 10.1016/S0040-4039(01)84433-6 contributor: fullname: Pedersen – start-page: 1973 year: 1973 ident: 10.1016/j.electacta.2004.10.004_bib33 publication-title: Bull. Soc. Chim. Fr. contributor: fullname: Maignan |
| SSID | ssj0007670 |
| Score | 1.8441708 |
| Snippet | Substituted 3-methylthio-1,2-dithiolium cations were prepared by alkylation of the corresponding 1,2-dithiole-3-thiones. These compounds were easily reduced in... |
| SourceID | crossref pascalfrancis elsevier |
| SourceType | Aggregation Database Index Database Publisher |
| StartPage | 2219 |
| SubjectTerms | Anethole dithiolethione Chemistry Cyclic voltammetry Dimerization Electrochemistry Exact sciences and technology General and physical chemistry Kinetics and mechanism of reactions Ring opening Sulfarlem |
| Title | Electrochemical behaviour of some 3-methylthio-1,2-dithiolium cations in dimethylformamide solution |
| URI | https://dx.doi.org/10.1016/j.electacta.2004.10.004 |
| Volume | 50 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LS8NAEB5qe1AR8Yn1Ufbg0a15bHYTb6W0VMWeKngLyT4w0jalj4MXf7u7yaa2B_EgBEIem4TJZObb8M18ALfSU4FiCcWBDBUmXspwmoQcO0aGQHBXyoJN-DKkg1fy9Ba81aBb1cIYWqWN_WVML6K13XNvrXk_yzJT4-v6hIbUuKF2I7oDDZ2OCKlDo_P4PBiuAzKjzKmEDMyALZpXoTaT6KWYK7YLphf5LUkdzJKFNp0qNS82ElH_CA4tgkSd8iGPoSanJ7DbrYTbTmB_o8fgKfBeKXTDbWcAZAvzV3OUK7TIJxL52OhIf46X71mO3TsPm0KNLB9nqwmyf_RQNkUiK08rYO4kExJVfnsGo35v1B1gq6yAuU-CJfaoxzWOSyNHhFRpkBLqLcGZy31BfZUqRrjvSupyT0_JmBNJbWMhE-YEUsnIP4f6NJ_KC0BEpExRroGioiRK9OcvlfDTxFU8CJKINsGpLBnPyv4ZcUUs-4jXxjdqmMQc0KsmPFQWj7dcIdZR_u_Bra139HNTSk23w-DyP1e_gr2idWvB3LmG-nK-kjcalCzTFuy0v9yWdb1v8BTjxQ |
| link.rule.ids | 315,786,790,4521,24144,27955,27956,45618,45712 |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV07T8MwED5BGQpCCAqI8igeGHGbh2MnbKhqVZ5TkbpFiR8iqG0qaAcWfju2k9B2QAxIkaLETmJdLufP0Xf3AVxJTwWKJRQHMlSYeCnDaRJy7BgZAsFdKS2b8OmZDl7I_SgYbUC3yoUxtMoy9hcx3Ubr8kyntGZnlmUmx9f1CQ2pcUPtRnQTtgwaMLyu9teS58EocyoZA9N9jeRltWYSvdmVYtvyvMhvU9TuLPnQhlOF4sXKNNTfh70SP6LbYogHsCGnDah3K9m2BuysVBg8BN4rZG54WRcAlWn5i3eUK_SRTyTysVGR_hzPX7Mcu9ceNmkaWT7OFhNU_s9D2RSJrOhmQe4kExJVXnsEw35v2B3gUlcBc58Ec-xRj2sUl0aOCKnSECXUR4Izl_uC-ipVjHDfldTlnl6QMSeS2sJCJswJpJKRfwy1aT6VJ4CISJmiXMNERUmU6I9fKuGniat4ECQRbYJTWTKeFdUz4opW9hb_GN9oYRLToHdNuKksHq85Qqxj_N8Xt9be0fKhlJpah8Hpf-5-CfXB8Okxfrx7fjiDbVvE1XJ4zqE2f1_ICw1P5mnLut83-Cvkmg |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Electrochemical+behaviour+of+some+3-methylthio-1%2C2-dithiolium+cations+in+dimethylformamide+solution&rft.jtitle=Electrochimica+acta&rft.au=ABASQ%2C+Marie-Laurence&rft.au=BURGOT%2C+Jean-Louis&rft.au=DARCHEN%2C+Andr%C3%A9&rft.au=SAIDI%2C+Mokhtar&rft.date=2005-04-01&rft.pub=Elsevier&rft.issn=0013-4686&rft.eissn=1873-3859&rft.volume=50&rft.issue=11&rft.spage=2219&rft.epage=2225&rft_id=info:doi/10.1016%2Fj.electacta.2004.10.004&rft.externalDBID=n%2Fa&rft.externalDocID=16603425 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0013-4686&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0013-4686&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0013-4686&client=summon |