Oxidative Addition Reactions of Cyclodiphosph(III)Azanes

• Published in: Phosphorus, sulfur, and silicon and the related elements Vol. 169; no. 1; pp. 31 - 34
• Main Authors: Swamy, K. C. Kumara, Kommana, Praveen, Vijjulatha, M., Kumar, K. Praveen
• Format: Journal Article
• Language: English
• Published: Taylor & Francis Group 01.01.2001
• Subjects: cyclodiphosph(III)azanes; oxidative addition; X-ray structure

The ansa compound {[t-BuN)P] 2 [O-6-t-Bu-4-Me-C 6 H 2 ] 2 CH 2 } (2) reacts with two mole equivalents of selenium to afford the bis(seleno) compound {[t-BuN)P(Se)] 2 [O-6-t-Bu-4-Me-C 6 H 2 ] 2 CH 2 } (3); under analogous conditions sulfur gives the P(III)-N-P(V) derivative {[(t-BuN)PN(t-Bu)P(S)][O-6...