Oxidative Addition Reactions of Cyclodiphosph(III)Azanes
The ansa compound {[t-BuN)P] 2 [O-6-t-Bu-4-Me-C 6 H 2 ] 2 CH 2 } (2) reacts with two mole equivalents of selenium to afford the bis(seleno) compound {[t-BuN)P(Se)] 2 [O-6-t-Bu-4-Me-C 6 H 2 ] 2 CH 2 } (3); under analogous conditions sulfur gives the P(III)-N-P(V) derivative {[(t-BuN)PN(t-Bu)P(S)][O-6...
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| Published in | Phosphorus, sulfur, and silicon and the related elements Vol. 169; no. 1; pp. 31 - 34 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Taylor & Francis Group
01.01.2001
|
| Subjects | |
| Online Access | Get full text |
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| Abstract | The ansa compound {[t-BuN)P]
2
[O-6-t-Bu-4-Me-C
6
H
2
]
2
CH
2
} (2) reacts with two mole equivalents of selenium to afford the bis(seleno) compound {[t-BuN)P(Se)]
2
[O-6-t-Bu-4-Me-C
6
H
2
]
2
CH
2
} (3); under analogous conditions sulfur gives the P(III)-N-P(V) derivative {[(t-BuN)PN(t-Bu)P(S)][O-6-t-Bu-4-Me-C
6
H
2
]
2
CH
2
} (4). These reactions are compared with those using [(ArO)PN(t-Bu)]
2
(5) and the macrocycle {[t-BuN-P]
2
(OCH
2
CMe
2
CH
2
O)}
2
(6). |
|---|---|
| AbstractList | The ansa compound {[t-BuN)P]
2
[O-6-t-Bu-4-Me-C
6
H
2
]
2
CH
2
} (2) reacts with two mole equivalents of selenium to afford the bis(seleno) compound {[t-BuN)P(Se)]
2
[O-6-t-Bu-4-Me-C
6
H
2
]
2
CH
2
} (3); under analogous conditions sulfur gives the P(III)-N-P(V) derivative {[(t-BuN)PN(t-Bu)P(S)][O-6-t-Bu-4-Me-C
6
H
2
]
2
CH
2
} (4). These reactions are compared with those using [(ArO)PN(t-Bu)]
2
(5) and the macrocycle {[t-BuN-P]
2
(OCH
2
CMe
2
CH
2
O)}
2
(6). |
| Author | Swamy, K. C. Kumara Kumar, K. Praveen Kommana, Praveen Vijjulatha, M. |
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| CitedBy_id | crossref_primary_10_1021_acs_inorgchem_5b00735 crossref_primary_10_1016_j_ccr_2011_10_021 crossref_primary_10_1039_C4DT00801D crossref_primary_10_1002_zaac_200400275 |
| Cites_doi | 10.1016/S0277-5387(99)00153-9 10.1016/S0277-5387(99)00112-6 |
| ContentType | Journal Article |
| Copyright | Copyright Taylor & Francis Group, LLC 2001 |
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| DOI | 10.1080/10426500108546583 |
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| Snippet | The ansa compound {[t-BuN)P]
2
[O-6-t-Bu-4-Me-C
6
H
2
]
2
CH
2
} (2) reacts with two mole equivalents of selenium to afford the bis(seleno) compound... |
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| StartPage | 31 |
| SubjectTerms | cyclodiphosph(III)azanes oxidative addition X-ray structure |
| Title | Oxidative Addition Reactions of Cyclodiphosph(III)Azanes |
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