Mn3O4 nanoparticles@reduced graphene oxide composite: An efficient electrocatalyst for artificial N2 fixation to NH3 at ambient conditions
Currently, industrial-scale NH 3 production almost relies on energy-intensive Haber-Bosch process from atmospheric N 2 with large amount of CO 2 emission, while low-cost and high-efficient catalysts are demanded for the N 2 reduction reaction (NRR). In this study, Mn 3 O 4 nanoparticles@reduced grap...
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| Published in | Nano research Vol. 12; no. 5; pp. 1093 - 1098 |
|---|---|
| Main Authors | , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Beijing
Tsinghua University Press
01.05.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Currently, industrial-scale NH
3
production almost relies on energy-intensive Haber-Bosch process from atmospheric N
2
with large amount of CO
2
emission, while low-cost and high-efficient catalysts are demanded for the N
2
reduction reaction (NRR). In this study, Mn
3
O
4
nanoparticles@reduced graphene oxide (Mn
3
O
4
@rGO) composite is reported as an efficient NRR electrocatalyst with excellent selectivity for NH
3
formation. In 0.1 M Na
2
SO
4
solution, such catalyst obtains a NH
3
yield of 17.4 μg·h
−1
·mg
−1
cat
. and a Faradaic efficiency of 3.52% at −0.85 V vs. reversible hydrogen electrode. Notably, it also shows high electrochemical stability during electrolysis process. Density functional theory (DFT) calculations also demonstrate that the (112) planes of Mn
3
O
4
possess superior NRR activity. |
|---|---|
| AbstractList | Currently, industrial-scale NH3 production almost relies on energy-intensive Haber-Bosch process from atmospheric N2 with large amount of CO2 emission, while low-cost and high-efficient catalysts are demanded for the N2 reduction reaction (NRR). In this study, Mn3O4 nanoparticles@reduced graphene oxide (Mn3O4@rGO) composite is reported as an efficient NRR electrocatalyst with excellent selectivity for NH3 formation. In 0.1 M Na2SO4 solution, such catalyst obtains a NH3 yield of 17.4 μg·h−1·mg−1cat. and a Faradaic efficiency of 3.52% at −0.85 V vs. reversible hydrogen electrode. Notably, it also shows high electrochemical stability during electrolysis process. Density functional theory (DFT) calculations also demonstrate that the (112) planes of Mn3O4 possess superior NRR activity. Currently, industrial-scale NH 3 production almost relies on energy-intensive Haber-Bosch process from atmospheric N 2 with large amount of CO 2 emission, while low-cost and high-efficient catalysts are demanded for the N 2 reduction reaction (NRR). In this study, Mn 3 O 4 nanoparticles@reduced graphene oxide (Mn 3 O 4 @rGO) composite is reported as an efficient NRR electrocatalyst with excellent selectivity for NH 3 formation. In 0.1 M Na 2 SO 4 solution, such catalyst obtains a NH 3 yield of 17.4 μg·h −1 ·mg −1 cat . and a Faradaic efficiency of 3.52% at −0.85 V vs. reversible hydrogen electrode. Notably, it also shows high electrochemical stability during electrolysis process. Density functional theory (DFT) calculations also demonstrate that the (112) planes of Mn 3 O 4 possess superior NRR activity. |
| Author | Sun, Xuping Wang, Yuan Wu, Xiufeng Gong, Feng Wang, Huanbo Li, Tingshuai Chen, Hongyu Huang, Hong Lu, Wenbo Liu, Qian Shi, Xifeng Zhao, Runbo Asiri, Abdullah M. |
| Author_xml | – sequence: 1 givenname: Hong surname: Huang fullname: Huang, Hong organization: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China – sequence: 2 givenname: Feng surname: Gong fullname: Gong, Feng organization: School of Materials and Energy, University of Electronic Science and Technology of China – sequence: 3 givenname: Yuan surname: Wang fullname: Wang, Yuan organization: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China – sequence: 4 givenname: Huanbo surname: Wang fullname: Wang, Huanbo organization: School of Environment and Resource, Southwest University of Science and Technology – sequence: 5 givenname: Xiufeng surname: Wu fullname: Wu, Xiufeng organization: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), School of Chemistry and Material Science, Shanxi Normal University – sequence: 6 givenname: Wenbo surname: Lu fullname: Lu, Wenbo organization: Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), School of Chemistry and Material Science, Shanxi Normal University – sequence: 7 givenname: Runbo surname: Zhao fullname: Zhao, Runbo organization: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China – sequence: 8 givenname: Hongyu surname: Chen fullname: Chen, Hongyu organization: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China – sequence: 9 givenname: Xifeng surname: Shi fullname: Shi, Xifeng organization: College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University – sequence: 10 givenname: Abdullah M. surname: Asiri fullname: Asiri, Abdullah M. organization: Chemistry Department, Faculty of Science & Center of Excellence for Advanced Materials Research, King Abdulaziz University – sequence: 11 givenname: Tingshuai surname: Li fullname: Li, Tingshuai organization: School of Materials and Energy, University of Electronic Science and Technology of China – sequence: 12 givenname: Qian surname: Liu fullname: Liu, Qian organization: School of Materials and Energy, University of Electronic Science and Technology of China – sequence: 13 givenname: Xuping surname: Sun fullname: Sun, Xuping email: xpsun@uestc.edu.cn organization: Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China |
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| Copyright | Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019 Nano Research is a copyright of Springer, (2019). All Rights Reserved. Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019. |
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| Snippet | Currently, industrial-scale NH
3
production almost relies on energy-intensive Haber-Bosch process from atmospheric N
2
with large amount of CO
2
emission,... Currently, industrial-scale NH3 production almost relies on energy-intensive Haber-Bosch process from atmospheric N2 with large amount of CO2 emission, while... |
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| SubjectTerms | Ammonia Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Carbon dioxide Carbon dioxide emissions Catalysis Catalysts Chemical reduction Chemistry and Materials Science Condensed Matter Physics Density functional theory Electrocatalysts Electrochemistry Electrolysis Graphene Haber Bosch process Manganese oxides Materials Science Nanoparticles Nanotechnology Nitrogen fixation Nitrogenation Research Article Selectivity Sodium sulfate |
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| Title | Mn3O4 nanoparticles@reduced graphene oxide composite: An efficient electrocatalyst for artificial N2 fixation to NH3 at ambient conditions |
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