Progress towards an improved Precambrian seawater 87Sr/86Sr curve

The secular trend of seawater strontium isotope ratio (87Sr/86Sr) reflects changes in the relative contributions of continental versus mantle reservoirs to ocean composition, and informs global tectonic events, weathering rates and biogeochemical cycling through Earth history. However, the Precambri...

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Published inEarth-science reviews Vol. 224; p. 103869
Main Authors Chen, Xi, Zhou, Ying, Shields, Graham A.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.2022
Subjects
Carbonates
Diagenesis
Dissolution methods
Ediacaran period
isotopes
Phanerozoic eon
Precambrian
seawater
strontium
Strontium isotopes
Supercontinent cycles
tectonics
uncertainty
Weathering
Dissolution methods
Diagenesis
Strontium isotopes
Weathering
Supercontinent cycles
Carbonates
Precambrian
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Abstract The secular trend of seawater strontium isotope ratio (87Sr/86Sr) reflects changes in the relative contributions of continental versus mantle reservoirs to ocean composition, and informs global tectonic events, weathering rates and biogeochemical cycling through Earth history. However, the Precambrian seawater 87Sr/86Sr curve is known in far less detail than its Phanerozoic counterpart. For this study, we compiled 2249 strontium isotope ratios of Precambrian marine sedimentary rocks published since 2002, alongside previously compiled older data. Here we evaluate the uncertainty of all published data for constraining coeval seawater 87Sr/86Sr using four criteria (depositional environment, diagenetic alteration, age constraint and dissolution method). The resultant seawater 87Sr/86Sr curve uses mainly ‘high certainty’ data and shows an overall increasing trend from ~0.7005 at c. 3.5 Ga to ≥0.7089 towards the end of the Ediacaran Period. The improved curve shows an earlier deviation of seawater 87Sr/86Sr from the contemporaneous mantle by c. 3.5 Ga, which might reflect the first significant emergence of evolved continental crust related to nascent tectonics. Additionally, the updated curve records two major rises at 2.5-2.2 Ga and 1.9-1.7 Ga in addition to a well-established event at 0.8-0.5 Ga. Despite the relative scarcity of high-certainty data, these two increases are consistent with enhanced continental weathering following the onset of oxidative weathering and assembly of the supercontinent Nuna, respectively. Although confirmation of these two events awaits more high-certainty data, Precambrian seawater 87Sr/86Sr experienced stronger oscillations and better correspondence with supercontinent cycles than previously shown.
AbstractList The secular trend of seawater strontium isotope ratio (⁸⁷Sr/⁸⁶Sr) reflects changes in the relative contributions of continental versus mantle reservoirs to ocean composition, and informs global tectonic events, weathering rates and biogeochemical cycling through Earth history. However, the Precambrian seawater ⁸⁷Sr/⁸⁶Sr curve is known in far less detail than its Phanerozoic counterpart. For this study, we compiled 2249 strontium isotope ratios of Precambrian marine sedimentary rocks published since 2002, alongside previously compiled older data. Here we evaluate the uncertainty of all published data for constraining coeval seawater ⁸⁷Sr/⁸⁶Sr using four criteria (depositional environment, diagenetic alteration, age constraint and dissolution method). The resultant seawater ⁸⁷Sr/⁸⁶Sr curve uses mainly ‘high certainty’ data and shows an overall increasing trend from ~0.7005 at c. 3.5 Ga to ≥0.7089 towards the end of the Ediacaran Period. The improved curve shows an earlier deviation of seawater ⁸⁷Sr/⁸⁶Sr from the contemporaneous mantle by c. 3.5 Ga, which might reflect the first significant emergence of evolved continental crust related to nascent tectonics. Additionally, the updated curve records two major rises at 2.5-2.2 Ga and 1.9-1.7 Ga in addition to a well-established event at 0.8-0.5 Ga. Despite the relative scarcity of high-certainty data, these two increases are consistent with enhanced continental weathering following the onset of oxidative weathering and assembly of the supercontinent Nuna, respectively. Although confirmation of these two events awaits more high-certainty data, Precambrian seawater ⁸⁷Sr/⁸⁶Sr experienced stronger oscillations and better correspondence with supercontinent cycles than previously shown.
The secular trend of seawater strontium isotope ratio (87Sr/86Sr) reflects changes in the relative contributions of continental versus mantle reservoirs to ocean composition, and informs global tectonic events, weathering rates and biogeochemical cycling through Earth history. However, the Precambrian seawater 87Sr/86Sr curve is known in far less detail than its Phanerozoic counterpart. For this study, we compiled 2249 strontium isotope ratios of Precambrian marine sedimentary rocks published since 2002, alongside previously compiled older data. Here we evaluate the uncertainty of all published data for constraining coeval seawater 87Sr/86Sr using four criteria (depositional environment, diagenetic alteration, age constraint and dissolution method). The resultant seawater 87Sr/86Sr curve uses mainly ‘high certainty’ data and shows an overall increasing trend from ~0.7005 at c. 3.5 Ga to ≥0.7089 towards the end of the Ediacaran Period. The improved curve shows an earlier deviation of seawater 87Sr/86Sr from the contemporaneous mantle by c. 3.5 Ga, which might reflect the first significant emergence of evolved continental crust related to nascent tectonics. Additionally, the updated curve records two major rises at 2.5-2.2 Ga and 1.9-1.7 Ga in addition to a well-established event at 0.8-0.5 Ga. Despite the relative scarcity of high-certainty data, these two increases are consistent with enhanced continental weathering following the onset of oxidative weathering and assembly of the supercontinent Nuna, respectively. Although confirmation of these two events awaits more high-certainty data, Precambrian seawater 87Sr/86Sr experienced stronger oscillations and better correspondence with supercontinent cycles than previously shown.
ArticleNumber 103869
Author Chen, Xi
Zhou, Ying
Shields, Graham A.
Author_xml – sequence: 1
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  surname: Chen
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  surname: Zhou
  fullname: Zhou, Ying
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  givenname: Graham A.
  surname: Shields
  fullname: Shields, Graham A.
  email: g.shields@ucl.ac.uk
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Thu Apr 24 23:00:20 EDT 2025
Tue Jul 01 03:11:33 EDT 2025
Fri Feb 23 02:38:35 EST 2024
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Keywords Dissolution methods
Diagenesis
Strontium isotopes
Weathering
Supercontinent cycles
Carbonates
Precambrian
Language English
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Snippet The secular trend of seawater strontium isotope ratio (87Sr/86Sr) reflects changes in the relative contributions of continental versus mantle reservoirs to...
The secular trend of seawater strontium isotope ratio (⁸⁷Sr/⁸⁶Sr) reflects changes in the relative contributions of continental versus mantle reservoirs to...
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SubjectTerms Carbonates
Diagenesis
Dissolution methods
Ediacaran period
isotopes
Phanerozoic eon
Precambrian
seawater
strontium
Strontium isotopes
Supercontinent cycles
tectonics
uncertainty
Weathering
Title Progress towards an improved Precambrian seawater 87Sr/86Sr curve
URI https://dx.doi.org/10.1016/j.earscirev.2021.103869
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