Sulfonamides differing in the alkylamino substituent length – Synthesis, electrochemical characteristic, acid-base profile and complexation properties

• Published in: Polyhedron Vol. 221; pp. 115868 - 115878
• Main Authors: Ciesielska, Aleksandra, Gawrońska, Małgorzata, Makowski, Mariusz, Ramotowska, Sandra
• Format: Journal Article
• Language: English
• Published: OXFORD Elsevier Ltd 15.07.2022; Elsevier
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Crystallography; Electrochemistry; Physical Sciences; pKa; Rhodium(III) complexes; Ruthenium(III) complexes; Science & Technology; Sulfonamides; Electrochemistry; Ruthenium(III) complexes; Rhodium(III) complexes; Sulfonamides; pKa; ANTICANCER; COPPER(II); EQUILIBRIUM; ANTIBACTERIAL; DISSOCIATION-CONSTANTS; DERIVATIVES; PK(A)

This paper describes the synthesis of two sulfonamides (NethylS and NpropylS) differing in the length of the alkylamino substituent. Their physicochemical characteristics are discussed, with particular emphasis on the electrochemical profile, acid-base character, and complexing ability towards triva...