Oxygen removal from blister copper by copper oxide formation
In a recent study by Coursol et al. ,5 the copper-oxide-rich corner of the Na^sub 2^O-CaO-Cu^sub 2^O system was investigated. A ternary phase diagram equilibrated with molten copper was calculated from model parameters5 for the slag system (Figure 4). The equilibrium oxygen concentration in liquid c...
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| Published in | JOM (1989) Vol. 57; no. 7; pp. 64 - 67 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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Springer Nature B.V
01.07.2005
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| Abstract | In a recent study by Coursol et al. ,5 the copper-oxide-rich corner of the Na^sub 2^O-CaO-Cu^sub 2^O system was investigated. A ternary phase diagram equilibrated with molten copper was calculated from model parameters5 for the slag system (Figure 4). The equilibrium oxygen concentration in liquid copper was also measured by Coursol et al.5 for the CaO-Cu^sub 2^O and Na^sub 2^O-Cu^sub 2^O binary systems. |
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| AbstractList | In this study, an alternative approach is proposed to remove oxygen f om blister copper through copper oxide formation. The addition of fluxes promotes both the copper oxide formation and oxygen reduction in molten copper Fundamental aspects of this proposed process are described in this article. Three different fluxes (Na2O-SiO2, CaO-Na 2O, and FeONa2O-Si O2) were tested at the laboratory scale. This work showed encouraging results with oxygen in copper being reduced to industrial specifications without the conventional hydrocarbon reduction step. This approach could be used industrially to remove oxygen from blister copper prior to anode casting and points to a new concept in deoxygenation of copper In a recent study by Coursol et al. ,5 the copper-oxide-rich corner of the Na^sub 2^O-CaO-Cu^sub 2^O system was investigated. A ternary phase diagram equilibrated with molten copper was calculated from model parameters5 for the slag system (Figure 4). The equilibrium oxygen concentration in liquid copper was also measured by Coursol et al.5 for the CaO-Cu^sub 2^O and Na^sub 2^O-Cu^sub 2^O binary systems. |
| Author | Roy, A Coursol, P Lebel, M Davis, B |
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| Cites_doi | 10.1007/s11837-004-0234-z 10.1007/s11663-003-0033-x 10.1021/j150313a018 10.1007/BF03221355 10.1007/s11837-004-0091-9 |
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| References | C.W. Bale (255_CR8) 2005 R. Parra (255_CR7) 2003 P.T. Carter (255_CR9) 1952; 36 P. Coursol (255_CR11) 2001 P. Coursol (255_CR3) 2004; 56 A. Yazawa (255_CR6) 1999 F.C. Kracek (255_CR10) 1930; 34 255_CR2 P. Coursol (255_CR4) 2004; 56 P.E. Queneau (255_CR1) 1996; 48 P. Coursol (255_CR5) 2003; 34B |
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| Snippet | In a recent study by Coursol et al. ,5 the copper-oxide-rich corner of the Na^sub 2^O-CaO-Cu^sub 2^O system was investigated. A ternary phase diagram... In this study, an alternative approach is proposed to remove oxygen f om blister copper through copper oxide formation. The addition of fluxes promotes both... |
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| SubjectTerms | Copper Copper industry Corrosion Equilibrium Extraction processes Furnaces Hydrocarbons Laboratories Metallurgy Neutrons Oxygen Slag Studies Sulfur Temperature |
| Title | Oxygen removal from blister copper by copper oxide formation |
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