Synthesis and preparation of biobased benzoxazine/bismaleimide copolymers: Thermal, mechanical and dielectric properties
A low dielectric constant biobased benzoxazine/bismaleimide copolymer is developed with a green synthesis strategy. [Display omitted] •A unique benzoxazine monomers (E-dea) with active allyl terminations were synthesized using a green synthesis strategy.•Poly(E-dea/BMI) have outstanding thermal, mec...
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| Published in | European polymer journal Vol. 179; p. 111524 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Oxford
Elsevier Ltd
05.10.2022
Elsevier BV |
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| Online Access | Get full text |
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| Abstract | A low dielectric constant biobased benzoxazine/bismaleimide copolymer is developed with a green synthesis strategy.
[Display omitted]
•A unique benzoxazine monomers (E-dea) with active allyl terminations were synthesized using a green synthesis strategy.•Poly(E-dea/BMI) have outstanding thermal, mechanical and low dielectric performances.•The nature behind these attractive performances of poly(E-dea/BMI) was intensively investigated.
Preparation of low dielectric thermosetting resins by green method is a challenging subject. Herein, unique bio-based benzoxazine monomer E-dea was prepared by a solvent-free method using eugenol as phenol source, and then E-dea and bismaleimide (BMI) were copolymerized to prepare poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1). The comprehensive properties including thermal, mechanical and dielectric properties of the copolymers were studied. Notably, poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1) exhibit low dielectric properties with dielectric constants of 2.85 and 2.79 at 1 MHz, respectively. Besides, the glass transition temperature (Tg), the initial thermal decomposition temperature (Tdi) and the flexural strength of poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1) are 167 °C and 169 °C, 333 °C and 321 °C and 115 ± 3.5 MPa and 123 ± 4.9 MPa, respectively. The excellent comprehensive performance is attributed to the interaction between flexible and low dielectric decane segments and rigid oxazine and BMI segments. |
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| AbstractList | Preparation of low dielectric thermosetting resins by green method is a challenging subject. Herein, unique bio-based benzoxazine monomer E-dea was prepared by a solvent-free method using eugenol as phenol source, and then E-dea and bismaleimide (BMI) were copolymerized to prepare poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1). The comprehensive properties including thermal, mechanical and dielectric properties of the copolymers were studied. Notably, poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1) exhibit low dielectric properties with dielectric constants of 2.85 and 2.79 at 1 MHz, respectively. Besides, the glass transition temperature (Tg), the initial thermal decomposition temperature (Tdi) and the flexural strength of poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1) are 167 °C and 169 °C, 333 °C and 321 °C and 115 ± 3.5 MPa and 123 ± 4.9 MPa, respectively. The excellent comprehensive performance is attributed to the interaction between flexible and low dielectric decane segments and rigid oxazine and BMI segments. A low dielectric constant biobased benzoxazine/bismaleimide copolymer is developed with a green synthesis strategy. [Display omitted] •A unique benzoxazine monomers (E-dea) with active allyl terminations were synthesized using a green synthesis strategy.•Poly(E-dea/BMI) have outstanding thermal, mechanical and low dielectric performances.•The nature behind these attractive performances of poly(E-dea/BMI) was intensively investigated. Preparation of low dielectric thermosetting resins by green method is a challenging subject. Herein, unique bio-based benzoxazine monomer E-dea was prepared by a solvent-free method using eugenol as phenol source, and then E-dea and bismaleimide (BMI) were copolymerized to prepare poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1). The comprehensive properties including thermal, mechanical and dielectric properties of the copolymers were studied. Notably, poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1) exhibit low dielectric properties with dielectric constants of 2.85 and 2.79 at 1 MHz, respectively. Besides, the glass transition temperature (Tg), the initial thermal decomposition temperature (Tdi) and the flexural strength of poly(E-dea/BMI-0.86) and poly(E-dea/BMI-1) are 167 °C and 169 °C, 333 °C and 321 °C and 115 ± 3.5 MPa and 123 ± 4.9 MPa, respectively. The excellent comprehensive performance is attributed to the interaction between flexible and low dielectric decane segments and rigid oxazine and BMI segments. |
| ArticleNumber | 111524 |
| Author | Sha, Xin-Long Zhou, Jin Liu, Zongtang Tan, Lu Fei, Zhenghao Wang, Changze Miao, Jia-Tao |
| Author_xml | – sequence: 1 givenname: Xin-Long surname: Sha fullname: Sha, Xin-Long email: shaxl@yctu.edu.cn organization: School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224007, China – sequence: 2 givenname: Changze surname: Wang fullname: Wang, Changze organization: Shangyu NHU BIO-chemical CO. LTD, Shangyu Economic and Technological Development Zone, Shaoxing 312300, China – sequence: 3 givenname: Lu surname: Tan fullname: Tan, Lu organization: School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224007, China – sequence: 4 givenname: Jin surname: Zhou fullname: Zhou, Jin organization: School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224007, China – sequence: 5 givenname: Zongtang surname: Liu fullname: Liu, Zongtang organization: School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224007, China – sequence: 6 givenname: Zhenghao surname: Fei fullname: Fei, Zhenghao organization: School of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng 224007, China – sequence: 7 givenname: Jia-Tao surname: Miao fullname: Miao, Jia-Tao email: jiataomiao@outlook.com organization: Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Lihu Street 1800, Wuxi 214122, China |
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| Snippet | A low dielectric constant biobased benzoxazine/bismaleimide copolymer is developed with a green synthesis strategy.
[Display omitted]
•A unique benzoxazine... Preparation of low dielectric thermosetting resins by green method is a challenging subject. Herein, unique bio-based benzoxazine monomer E-dea was prepared by... |
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| SubjectTerms | Benzoxazine Benzoxazines Biobased Bismaleimide Bismaleimides Copolymerization Copolymers Data envelopment analysis Dielectric properties Flexural strength Glass transition temperature Low dielectric constant Mechanical properties Segments Temperature Thermal decomposition Thermosetting resins |
| Title | Synthesis and preparation of biobased benzoxazine/bismaleimide copolymers: Thermal, mechanical and dielectric properties |
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