Controlled synthesis of silver nanoplates and nanoparticles by reducing silver nitrate with hydroxylamine hydrochloride
An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO3) with hydroxylamine hydrochloride (NH2OH·HCl) at room temperature. Silver nanoplates of various shapes, including triangular, truncated triangular, hexagonal, and truncated hexagonal, e...
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Published in | Rare metals Vol. 36; no. 10; pp. 799 - 805 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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Beijing
Nonferrous Metals Society of China
01.10.2017
Springer Nature B.V |
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Abstract | An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO3) with hydroxylamine hydrochloride (NH2OH·HCl) at room temperature. Silver nanoplates of various shapes, including triangular, truncated triangular, hexagonal, and truncated hexagonal, exhibit an average width and thickness of approximately 1 μm and 50 nm, respectively. Silver nanoparticles were acquired by placing polyvinyl pyrrolidone (PVP) in the reaction solution. The produced silver nanoparticles are quasi-spherical in shape and - 100 nm in size. The catalytic activity in the thermal decomposition of ammonium perchlorate (AID) was distinguished by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC). The outcomes reveal that the addition of silver nanoplates and nanoparticles diminishes the low decomposition temperature of AP by 7 and 14 ℃ and leads to a drop in the high decomposition temperature of AP by 60 and 110 ℃ and a rise in the total DSC heat release by 0.86 and 1.05 kJ.g^-1, respectively. |
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AbstractList | An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO
3
) with hydroxylamine hydrochloride (NH
2
OH·HCl) at room temperature. Silver nanoplates of various shapes, including triangular, truncated triangular, hexagonal, and truncated hexagonal, exhibit an average width and thickness of approximately 1 μm and 50 nm, respectively. Silver nanoparticles were acquired by placing polyvinyl pyrrolidone (PVP) in the reaction solution. The produced silver nanoparticles are quasi-spherical in shape and ∼100 nm in size. The catalytic activity in the thermal decomposition of ammonium perchlorate (AP) was distinguished by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC). The outcomes reveal that the addition of silver nanoplates and nanoparticles diminishes the low decomposition temperature of AP by 7 and 14 °C and leads to a drop in the high decomposition temperature of AP by 60 and 110 °C and a rise in the total DSC heat release by 0.86 and 1.05 kJ·g
−1
, respectively. An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO3) with hydroxylamine hydrochloride (NH2OH·HCl) at room temperature. Silver nanoplates of various shapes, including triangular, truncated triangular, hexagonal, and truncated hexagonal, exhibit an average width and thickness of approximately 1 μm and 50 nm, respectively. Silver nanoparticles were acquired by placing polyvinyl pyrrolidone (PVP) in the reaction solution. The produced silver nanoparticles are quasi-spherical in shape and ∼100 nm in size. The catalytic activity in the thermal decomposition of ammonium perchlorate (AP) was distinguished by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC). The outcomes reveal that the addition of silver nanoplates and nanoparticles diminishes the low decomposition temperature of AP by 7 and 14 °C and leads to a drop in the high decomposition temperature of AP by 60 and 110 °C and a rise in the total DSC heat release by 0.86 and 1.05 kJ·g−1, respectively. An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO3) with hydroxylamine hydrochloride (NH2OH·HCl) at room temperature. Silver nanoplates of various shapes, including triangular, truncated triangular, hexagonal, and truncated hexagonal, exhibit an average width and thickness of approximately 1 μm and 50 nm, respectively. Silver nanoparticles were acquired by placing polyvinyl pyrrolidone (PVP) in the reaction solution. The produced silver nanoparticles are quasi-spherical in shape and - 100 nm in size. The catalytic activity in the thermal decomposition of ammonium perchlorate (AID) was distinguished by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC). The outcomes reveal that the addition of silver nanoplates and nanoparticles diminishes the low decomposition temperature of AP by 7 and 14 ℃ and leads to a drop in the high decomposition temperature of AP by 60 and 110 ℃ and a rise in the total DSC heat release by 0.86 and 1.05 kJ.g^-1, respectively. |
Author | Zhi-Peng Cheng;Xiao-Zhong Chu;Xiao-Qing Wu;Ji-Ming Xu;Hui Zhong;Jing-Zhou Yin |
AuthorAffiliation | Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huaian 223300, China |
Author_xml | – sequence: 1 givenname: Zhi-Peng orcidid: 0000-0002-4507-9037 surname: Cheng fullname: Cheng, Zhi-Peng email: nanohytc@126.com organization: Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University – sequence: 2 givenname: Xiao-Zhong surname: Chu fullname: Chu, Xiao-Zhong organization: Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University – sequence: 3 givenname: Xiao-Qing surname: Wu fullname: Wu, Xiao-Qing organization: Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University – sequence: 4 givenname: Ji-Ming surname: Xu fullname: Xu, Ji-Ming organization: Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University – sequence: 5 givenname: Hui surname: Zhong fullname: Zhong, Hui organization: Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University – sequence: 6 givenname: Jing-Zhou surname: Yin fullname: Yin, Jing-Zhou organization: Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Huaiyin Normal University |
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Notes | An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO3) with hydroxylamine hydrochloride (NH2OH·HCl) at room temperature. Silver nanoplates of various shapes, including triangular, truncated triangular, hexagonal, and truncated hexagonal, exhibit an average width and thickness of approximately 1 μm and 50 nm, respectively. Silver nanoparticles were acquired by placing polyvinyl pyrrolidone (PVP) in the reaction solution. The produced silver nanoparticles are quasi-spherical in shape and - 100 nm in size. The catalytic activity in the thermal decomposition of ammonium perchlorate (AID) was distinguished by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC). The outcomes reveal that the addition of silver nanoplates and nanoparticles diminishes the low decomposition temperature of AP by 7 and 14 ℃ and leads to a drop in the high decomposition temperature of AP by 60 and 110 ℃ and a rise in the total DSC heat release by 0.86 and 1.05 kJ.g^-1, respectively. Silver nanoparticle; Silver nanoplates;Formation mechanism; Ammonium perchlorate 11-2112/TF ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
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Snippet | An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO3) with hydroxylamine hydrochloride... An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO 3 ) with hydroxylamine hydrochloride (NH 2... An easy and effective method of silver nanoplate synthesis technique was created by reducing silver nitrate (AgNO3) with hydroxylamine hydrochloride... |
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SubjectTerms | Biomaterials Catalysis Catalytic activity Chemical synthesis Chemistry and Materials Science Differential scanning calorimetry Energy Heat measurement Materials Engineering Materials Science Metallic Materials Nanoparticles Nanoscale Science and Technology Physical Chemistry Silver Thermal analysis Thermal decomposition Thermogravimetric analysis |
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Title | Controlled synthesis of silver nanoplates and nanoparticles by reducing silver nitrate with hydroxylamine hydrochloride |
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