Effect of monomer structure on properties of polyimide as LIB separator and its mechanism study
Polyimide (PI) has remarkable thermal stability and mechanical properties, and is considered as an important candidate material for the manufacture of high-security new separators of lithium ion batteries (LIBs). However, different types of PI may exhibit performance differences in battery applicati...
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Published in | Electrochimica acta Vol. 337; p. 135838 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Oxford
Elsevier Ltd
20.03.2020
Elsevier BV |
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Abstract | Polyimide (PI) has remarkable thermal stability and mechanical properties, and is considered as an important candidate material for the manufacture of high-security new separators of lithium ion batteries (LIBs). However, different types of PI may exhibit performance differences in battery applications due to their various monomer structures. We synthesize four PIs with different monomers, including 1,2,4,5-pyromellitic dianhydride-4,4′-oxydianiline (PMDA-ODA), 3,3′,4,4′-biphenyltetracarboxylic dianhydride-4,4′-oxydianiline (BPDA-ODA), 3,3′,4,4′-oxydiphthalic dianhydride-4,4′-oxydianiline (ODPA-ODA) and 3,3′,4,4′-benzophenonetetracarboxylic dianhydride-4,4′-oxydianiline (BTDA-ODA), and electrospin them into nanofiber films. Those PI films are then thoroughly evaluated as the separator of LIB. Results show that the electrochemical window of those four PI films is up to 5.1 V (vs. Li+/Li), their wettability and electrolyte uptake are all related to the surface polarity and porosity. Among the four PI separators, BPDA-ODA shows the best cycle performance (95.8% @0.2C, 25 °C) and rate performance in the NCM811|Li battery system, while the BTDA-ODA is the worst in battery applications due to its surface polarity, low electrolyte uptake and the lithiation reaction occurred on the carbonyl groups between two benzene rings, and therefore is not suitable for usage in manufacturing separators. |
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AbstractList | Polyimide (PI) has remarkable thermal stability and mechanical properties, and is considered as an important candidate material for the manufacture of high-security new separators of lithium ion batteries (LIBs). However, different types of PI may exhibit performance differences in battery applications due to their various monomer structures. We synthesize four PIs with different monomers, including 1,2,4,5-pyromellitic dianhydride-4,4′-oxydianiline (PMDA-ODA), 3,3′,4,4′-biphenyltetracarboxylic dianhydride-4,4′-oxydianiline (BPDA-ODA), 3,3′,4,4′-oxydiphthalic dianhydride-4,4′-oxydianiline (ODPA-ODA) and 3,3′,4,4′-benzophenonetetracarboxylic dianhydride-4,4′-oxydianiline (BTDA-ODA), and electrospin them into nanofiber films. Those PI films are then thoroughly evaluated as the separator of LIB. Results show that the electrochemical window of those four PI films is up to 5.1 V (vs. Li+/Li), their wettability and electrolyte uptake are all related to the surface polarity and porosity. Among the four PI separators, BPDA-ODA shows the best cycle performance (95.8% @0.2C, 25 °C) and rate performance in the NCM811|Li battery system, while the BTDA-ODA is the worst in battery applications due to its surface polarity, low electrolyte uptake and the lithiation reaction occurred on the carbonyl groups between two benzene rings, and therefore is not suitable for usage in manufacturing separators. Polyimide (PI) has remarkable thermal stability and mechanical properties, and is considered as an important candidate material for the manufacture of high-security new separators of lithium ion batteries (LIBs). However, different types of PI may exhibit performance differences in battery applications due to their various monomer structures. We synthesize four PIs with different monomers, including 1,2,4,5-pyromellitic dianhydride-4,4′-oxydianiline (PMDA-ODA), 3,3′,4,4′-biphenyltetracarboxylic dianhydride-4,4′-oxydianiline (BPDA-ODA), 3,3′,4,4′-oxydiphthalic dianhydride-4,4′-oxydianiline (ODPA-ODA) and 3,3′,4,4′-benzophenonetetracarboxylic dianhydride-4,4′-oxydianiline (BTDA-ODA), and electrospin them into nanofiber films. Those PI films are then thoroughly evaluated as the separator of LIB. Results show that the electrochemical window of those four PI films is up to 5.1 V (vs. Li+/Li), their wettability and electrolyte uptake are all related to the surface polarity and porosity. Among the four PI separators, BPDA-ODA shows the best cycle performance (95.8% @0.2C, 25 °C) and rate performance in the NCM811|Li battery system, while the BTDA-ODA is the worst in battery applications due to its surface polarity, low electrolyte uptake and the lithiation reaction occurred on the carbonyl groups between two benzene rings, and therefore is not suitable for usage in manufacturing separators. |
ArticleNumber | 135838 |
Author | Cao, Jian-Hua Wu, Da-Yong He, Lei Liang, Tian |
Author_xml | – sequence: 1 givenname: Lei orcidid: 0000-0002-6023-7515 surname: He fullname: He, Lei organization: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhong-guan-cun East Road, Haidian District, Beijing, 100190, PR China – sequence: 2 givenname: Jian-Hua surname: Cao fullname: Cao, Jian-Hua organization: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhong-guan-cun East Road, Haidian District, Beijing, 100190, PR China – sequence: 3 givenname: Tian surname: Liang fullname: Liang, Tian organization: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhong-guan-cun East Road, Haidian District, Beijing, 100190, PR China – sequence: 4 givenname: Da-Yong orcidid: 0000-0002-5745-253X surname: Wu fullname: Wu, Da-Yong email: dayongwu@mail.ipc.ac.cn organization: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 29 Zhong-guan-cun East Road, Haidian District, Beijing, 100190, PR China |
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CitedBy_id | crossref_primary_10_1007_s42765_022_00190_3 crossref_primary_10_1021_acsami_2c00390 crossref_primary_10_3390_polym15081954 crossref_primary_10_1007_s10853_023_08889_3 crossref_primary_10_1021_acsami_3c01788 crossref_primary_10_1016_j_jallcom_2022_168543 crossref_primary_10_1021_acs_energyfuels_1c02553 crossref_primary_10_1016_j_compositesa_2022_107132 crossref_primary_10_1016_j_memsci_2023_121533 crossref_primary_10_1002_app_52604 crossref_primary_10_1021_acsaem_2c00745 crossref_primary_10_1039_D0RA00884B crossref_primary_10_1007_s40820_023_01104_7 crossref_primary_10_1002_sstr_202200383 crossref_primary_10_1016_j_ijoes_2024_100557 crossref_primary_10_3390_membranes12100961 crossref_primary_10_1021_acsapm_2c00467 crossref_primary_10_1021_acsaem_1c00804 |
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SubjectTerms | Benzene Carbonyl groups Carbonyls Dianhydrides Electrolytes Electrospinning Lithium Lithium ion battery Lithium-ion batteries Materials selection Mechanical properties Monomer structure Monomers Nanofibers Polarity Polyimide Porosity Rechargeable batteries Separators Thermal stability Wettability |
Title | Effect of monomer structure on properties of polyimide as LIB separator and its mechanism study |
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