The Synthesis, Full Characterisation and Utilisation of Template‐Free Silica Sodalite, a Novel Polymorph of Silica

Empty glass: Subjecting ethylene glycol silica sodalite to heat (680 °C) under a nitrogen atmosphere (i) successfully removes the templating agent to give cubic silica sodalite, which, upon consequent heating under an oxygen atmosphere (ii), transforms into a rhombohedral form of the empty sodalite,...

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Published inChemistry : a European journal Vol. 15; no. 22; pp. 5441 - 5443
Main Authors King, R. S. P., Dann, S. E., Elsegood, M. R. J., Kelly, P. F., Mortimer, R. J.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY‐VCH Verlag 25.05.2009
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Summary:Empty glass: Subjecting ethylene glycol silica sodalite to heat (680 °C) under a nitrogen atmosphere (i) successfully removes the templating agent to give cubic silica sodalite, which, upon consequent heating under an oxygen atmosphere (ii), transforms into a rhombohedral form of the empty sodalite, in effect a novel polymorph of silica. Empty glass: Subjecting ethylene glycol silica sodalite to heat (680 °C) under a nitrogen atmosphere (i) successfully removes the templating agent to give cubic silica sodalite, which, upon consequent heating under an oxygen atmosphere (ii), transforms into a rhombohedral form of the empty sodalite, in effect a novel polymorph of silica.
Bibliography:ObjectType-Article-1
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ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200802551