Lignin precipitation on the pulp fibers in the ethanol-based organosolv pulping
Ethanol pulping of eucalyptus wood chips and wheat straw was conducted to investigate the precipitation of dissolved lignin back onto the fibers in pulping and washing. Results show that a large amount of lignin particles are present on the fibers after pulping and each stage of washing in a four-st...
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| Published in | Colloids and surfaces. A, Physicochemical and engineering aspects Vol. 301; no. 1; pp. 255 - 263 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
05.07.2007
Elsevier |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Ethanol pulping of eucalyptus wood chips and wheat straw was conducted to investigate the precipitation of dissolved lignin back onto the fibers in pulping and washing. Results show that a large amount of lignin particles are present on the fibers after pulping and each stage of washing in a four-stage washing sequence, which was identified by both light microscopy and SEM, and by XPS. When the ethanol concentration of a lignin ethanol solution is reduced or the temperature drops as in the pulp washing process, lignin precipitation occurs. It has been concluded that high kappa number of ethanol pulp is mainly due to the precipitation of the dissolved lignin from the pulping liquor, which accounts for the easy bleachability of the ethanol pulp. |
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| AbstractList | Ethanol pulping of eucalyptus wood chips and wheat straw was conducted to investigate the precipitation of dissolved lignin back onto the fibers in pulping and washing. Results show that a large amount of lignin particles are present on the fibers after pulping and each stage of washing in a four-stage washing sequence, which was identified by both light microscopy and SEM, and by XPS. When the ethanol concentration of a lignin ethanol solution is reduced or the temperature drops as in the pulp washing process, lignin precipitation occurs. It has been concluded that high kappa number of ethanol pulp is mainly due to the precipitation of the dissolved lignin from the pulping liquor, which accounts for the easy bleachability of the ethanol pulp. |
| Author | Zhang, Meiyun Xu, Yongjian Li, Kecheng |
| Author_xml | – sequence: 1 givenname: Yongjian surname: Xu fullname: Xu, Yongjian organization: Department of Chemical Engineering and Limerick Pulp and Paper Centre, University of New Brunswick, Fredericton, NB, Canada E3B 6C2 – sequence: 2 givenname: Kecheng surname: Li fullname: Li, Kecheng email: kecheng@unb.ca organization: Department of Chemical Engineering and Limerick Pulp and Paper Centre, University of New Brunswick, Fredericton, NB, Canada E3B 6C2 – sequence: 3 givenname: Meiyun surname: Zhang fullname: Zhang, Meiyun organization: College of Pulp and Paper Engineering, Shaanxi University of Science and Technology, Shaanxi 712081, China |
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| Cites_doi | 10.1515/hfsg.1988.42.3.177 10.1081/WCT-200038066 10.1080/02773810601023438 10.1016/S0009-2614(01)01022-3 10.1016/S0927-7757(03)00320-0 10.1515/hfsg.1989.43.3.159 10.1002/sia.2454 10.1002/app.1979.070240406 10.1080/02773819608545815 |
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| Keywords | Eucalyptus Wheat straw Lignin precipitation Ethanol pulping Organosolv pulping SEM XPS Lignin Scanning electron microscopy Ethanol Fiber Alcohol X ray Precipitation Dicotyledones Angiospermae Alkanol Myrtaceae Photoelectron spectrometry Spermatophyta |
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| Snippet | Ethanol pulping of eucalyptus wood chips and wheat straw was conducted to investigate the precipitation of dissolved lignin back onto the fibers in pulping and... |
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| SubjectTerms | Chemistry Ethanol pulping Eucalyptus Exact sciences and technology General and physical chemistry Lignin precipitation Organosolv pulping SEM Wheat straw XPS |
| Title | Lignin precipitation on the pulp fibers in the ethanol-based organosolv pulping |
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