Correlation between Structural and Transport Properties of Ca-Doped La Nickelates and Their Electrochemical Performance

This work presents the results from a study of the structure and transport properties of Ca-doped La2NiO4+δ. La2−xCaxNiO4+δ (x = 0–0.4) materials that were synthesized via combustion of organic-nitrate precursors and characterized by X-ray diffraction (XRD), in situ XRD using synchrotron radiation,...

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Published inCrystals (Basel) Vol. 11; no. 3; p. 297
Main Authors Pikalova, Elena, Sadykov, Vladislav, Sadovskaya, Ekaterina, Yeremeev, Nikita, Kolchugin, Alexander, Shmakov, Alexander, Vinokurov, Zakhar, Mishchenko, Denis, Filonova, Elena, Belyaev, Vladimir
Format Journal Article
LanguageEnglish
Published MDPI AG 01.03.2021
Subjects
Ca doping
isotope exchange
La2NiO4+δ
oxygen mobility
polarization resistance
synchrotron radiation studies
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Abstract This work presents the results from a study of the structure and transport properties of Ca-doped La2NiO4+δ. La2−xCaxNiO4+δ (x = 0–0.4) materials that were synthesized via combustion of organic-nitrate precursors and characterized by X-ray diffraction (XRD), in situ XRD using synchrotron radiation, thermogravimetric analysis (TGA) and isotope exchange of oxygen with C18O2. The structure was defined as orthorhombic (Fmmm) for x = 0 and tetragonal (I4/mmm) for x = 0.1–0.4. Changes that occurred in the unit cell parameters and volume as the temperature changed during heating were shown to be caused by the excess oxygen loss. Typical for Ruddlesden–Popper phases, oxygen mobility and surface reactivity decreased as the Ca content was increased due to a reduction in the over-stoichiometric oxygen content with the exception of x = 0.1. This composition demonstrated its superior oxygen transport properties compared to La2NiO4+δ due to the enhanced oxygen mobility caused by structural features. Electrochemical data obtained showed relatively low polarization resistance for the electrodes with a low Ca content, which correlates well with oxygen transport properties.
AbstractList This work presents the results from a study of the structure and transport properties of Ca-doped La2NiO4+δ. La2−xCaxNiO4+δ (x = 0–0.4) materials that were synthesized via combustion of organic-nitrate precursors and characterized by X-ray diffraction (XRD), in situ XRD using synchrotron radiation, thermogravimetric analysis (TGA) and isotope exchange of oxygen with C18O2. The structure was defined as orthorhombic (Fmmm) for x = 0 and tetragonal (I4/mmm) for x = 0.1–0.4. Changes that occurred in the unit cell parameters and volume as the temperature changed during heating were shown to be caused by the excess oxygen loss. Typical for Ruddlesden–Popper phases, oxygen mobility and surface reactivity decreased as the Ca content was increased due to a reduction in the over-stoichiometric oxygen content with the exception of x = 0.1. This composition demonstrated its superior oxygen transport properties compared to La2NiO4+δ due to the enhanced oxygen mobility caused by structural features. Electrochemical data obtained showed relatively low polarization resistance for the electrodes with a low Ca content, which correlates well with oxygen transport properties.
Author Filonova, Elena
Belyaev, Vladimir
Sadovskaya, Ekaterina
Pikalova, Elena
Shmakov, Alexander
Vinokurov, Zakhar
Yeremeev, Nikita
Sadykov, Vladislav
Kolchugin, Alexander
Mishchenko, Denis
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Snippet This work presents the results from a study of the structure and transport properties of Ca-doped La2NiO4+δ. La2−xCaxNiO4+δ (x = 0–0.4) materials that were...
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StartPage 297
SubjectTerms Ca doping
isotope exchange
La2NiO4+δ
oxygen mobility
polarization resistance
synchrotron radiation studies
Title Correlation between Structural and Transport Properties of Ca-Doped La Nickelates and Their Electrochemical Performance
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