Chitosan-based materials: Preparation, modification and application

Chitosan is a natural biopolymer with a modifiable structure and abundant function groups, moreover, it can be processed into various shapes and sizes, making it suitable for various applications. This review analyzed and summarized the recent advances in chitosan-based materials, particularly focus...

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Published inJournal of cleaner production Vol. 355; p. 131825
Main Authors Wang, Jianlong, Zhuang, Shuting
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 25.06.2022
Subjects
acylation
alkylation
biopolymers
Chitosan
copolymerization
Crosslinking
Environmental application
esterification
Grafting
hydrolysis
medicine
microparticles
Modifying strategy
molecular weight
nanofibers
three-dimensional printing
water treatment
Crosslinking
Modifying strategy
Chitosan
Grafting
Environmental application
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Abstract Chitosan is a natural biopolymer with a modifiable structure and abundant function groups, moreover, it can be processed into various shapes and sizes, making it suitable for various applications. This review analyzed and summarized the recent advances in chitosan-based materials, particularly focusing on the modification of chitosan by physical, chemical and biological methods, which provided plentiful information on the preparation, characterization and application of chitosan-based materials. In this review, various preparation and modification methods for improving chitosan performances, as well as the application of chitosan and its derivatives, were critically analyzed and summarized in detail. Chitosan-based materials can be fabricated into different shapes and sizes, such as nanofiber, nanoparticles, microspheres, membranes, and 3D printed scaffolds. In addition, chitosan can be modified through physical, chemical, and biological modifications, to obtain versatile chitosan-based materials. For physical modification, crosslinking and blending are commonly used., while chemical modification is based on chemical reactions (e.g. acylation, esterification, etherification, N-alkylation, graft copolymerization, and degradation), to prepare the corresponding derivatives (e.g. chemically cross-linked chitosan, grafted chitosan, low molecular weight chitosan, and oligo-chitosan) through crosslinking, grafting, and degradation. The biological modification is associated with various enzymes to realize the hydrolysis or grafting. With improved performances through modification, as well as various shapes and sizes, chitosan-based materials show promising applications in versatile fields, such as water treatment, food processing, pharmaceutical/biomedicine, textiles and agriculture. This review will deepen the understanding the state of the art of chitosan-based materials, including their preparation, characterization and application. [Display omitted] •Various modification methods for improving chitosan performances were reviewed.•Physical, chemical and biological methods are applied for chitosan modification.•Chitosan-based materials have promising applications in versatile fields.•This review systematically summarized the advances in chitosan-based materials.
AbstractList Chitosan is a natural biopolymer with a modifiable structure and abundant function groups, moreover, it can be processed into various shapes and sizes, making it suitable for various applications. This review analyzed and summarized the recent advances in chitosan-based materials, particularly focusing on the modification of chitosan by physical, chemical and biological methods, which provided plentiful information on the preparation, characterization and application of chitosan-based materials. In this review, various preparation and modification methods for improving chitosan performances, as well as the application of chitosan and its derivatives, were critically analyzed and summarized in detail. Chitosan-based materials can be fabricated into different shapes and sizes, such as nanofiber, nanoparticles, microspheres, membranes, and 3D printed scaffolds. In addition, chitosan can be modified through physical, chemical, and biological modifications, to obtain versatile chitosan-based materials. For physical modification, crosslinking and blending are commonly used., while chemical modification is based on chemical reactions (e.g. acylation, esterification, etherification, N-alkylation, graft copolymerization, and degradation), to prepare the corresponding derivatives (e.g. chemically cross-linked chitosan, grafted chitosan, low molecular weight chitosan, and oligo-chitosan) through crosslinking, grafting, and degradation. The biological modification is associated with various enzymes to realize the hydrolysis or grafting. With improved performances through modification, as well as various shapes and sizes, chitosan-based materials show promising applications in versatile fields, such as water treatment, food processing, pharmaceutical/biomedicine, textiles and agriculture. This review will deepen the understanding the state of the art of chitosan-based materials, including their preparation, characterization and application.
Chitosan is a natural biopolymer with a modifiable structure and abundant function groups, moreover, it can be processed into various shapes and sizes, making it suitable for various applications. This review analyzed and summarized the recent advances in chitosan-based materials, particularly focusing on the modification of chitosan by physical, chemical and biological methods, which provided plentiful information on the preparation, characterization and application of chitosan-based materials. In this review, various preparation and modification methods for improving chitosan performances, as well as the application of chitosan and its derivatives, were critically analyzed and summarized in detail. Chitosan-based materials can be fabricated into different shapes and sizes, such as nanofiber, nanoparticles, microspheres, membranes, and 3D printed scaffolds. In addition, chitosan can be modified through physical, chemical, and biological modifications, to obtain versatile chitosan-based materials. For physical modification, crosslinking and blending are commonly used., while chemical modification is based on chemical reactions (e.g. acylation, esterification, etherification, N-alkylation, graft copolymerization, and degradation), to prepare the corresponding derivatives (e.g. chemically cross-linked chitosan, grafted chitosan, low molecular weight chitosan, and oligo-chitosan) through crosslinking, grafting, and degradation. The biological modification is associated with various enzymes to realize the hydrolysis or grafting. With improved performances through modification, as well as various shapes and sizes, chitosan-based materials show promising applications in versatile fields, such as water treatment, food processing, pharmaceutical/biomedicine, textiles and agriculture. This review will deepen the understanding the state of the art of chitosan-based materials, including their preparation, characterization and application. [Display omitted] •Various modification methods for improving chitosan performances were reviewed.•Physical, chemical and biological methods are applied for chitosan modification.•Chitosan-based materials have promising applications in versatile fields.•This review systematically summarized the advances in chitosan-based materials.
ArticleNumber 131825
Author Wang, Jianlong
Zhuang, Shuting
Author_xml – sequence: 1
  givenname: Jianlong
  orcidid: 0000-0001-9572-851X
  surname: Wang
  fullname: Wang, Jianlong
  email: wangjl@tsinghua.edu.cn
  organization: Laboratory of Environmental Technology, INET, Tsinghua University, Beijing, 100084, PR China
– sequence: 2
  givenname: Shuting
  surname: Zhuang
  fullname: Zhuang, Shuting
  organization: Laboratory of Environmental Technology, INET, Tsinghua University, Beijing, 100084, PR China
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Snippet Chitosan is a natural biopolymer with a modifiable structure and abundant function groups, moreover, it can be processed into various shapes and sizes, making...
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SubjectTerms acylation
alkylation
biopolymers
Chitosan
copolymerization
Crosslinking
Environmental application
esterification
Grafting
hydrolysis
medicine
microparticles
Modifying strategy
molecular weight
nanofibers
three-dimensional printing
water treatment
Title Chitosan-based materials: Preparation, modification and application
URI https://dx.doi.org/10.1016/j.jclepro.2022.131825
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Volume 355
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