Solubilisation and chemical fixation of copper(ii) in micronized copper treated wood

Wood preservatives using micronized particulate copper as the main active ingredient recently introduced in the USA have generated controversies due to their limited intrinsic solubility compared to the conventional soluble copper treatments. Because the availability of soluble copper ions is essent...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 45; no. 9; pp. 3679 - 3686
Main Authors Xue, Wei, Ruddick, John N. R, Kennepohl, Pierre
Format Journal Article
LanguageEnglish
Published England 01.01.2016
Subjects
Availability
Copper
COPPER IONS
Fixation
MICA
PRESERVATIVES
Solubility
Spectroscopy
Wood
X-ray fluorescence
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Abstract Wood preservatives using micronized particulate copper as the main active ingredient recently introduced in the USA have generated controversies due to their limited intrinsic solubility compared to the conventional soluble copper treatments. Because the availability of soluble copper ions is essential for these preservatives to provide an effective treatment, concerns centered on whether they are able to produce soluble copper when introduced into wood, and the copper fixation mechanism of the treatment is little understood. A combination of Electron Paramagnetic Resonance (EPR) spectroscopy and X-ray Fluorescence (XRF) spectroscopy has been successfully utilized to characterize and quantify solubilized and fixed copper species in micronized copper treated wood, which also contains unreacted particulate copper. On the basis of the experimental results, the fixation mechanism is thought to be triggered by the reaction between the carboxylic acid protons in hemicellulose of wood with the particulate copper, and the quantities of the solubilized and fixed copper species are determined by the availability of these acidic protons. Wood preservatives using micronized particulate copper as the main active ingredient recently introduced in the USA have generated controversies due to their limited intrinsic solubility compared to the conventional soluble copper treatments.
AbstractList Wood preservatives using micronized particulate copper as the main active ingredient recently introduced in the USA have generated controversies due to their limited intrinsic solubility compared to the conventional soluble copper treatments. Because the availability of soluble copper ions is essential for these preservatives to provide an effective treatment, concerns centered on whether they are able to produce soluble copper when introduced into wood, and the copper fixation mechanism of the treatment is little understood. A combination of Electron Paramagnetic Resonance (EPR) spectroscopy and X-ray Fluorescence (XRF) spectroscopy has been successfully utilized to characterize and quantify solubilized and fixed copper species in micronized copper treated wood, which also contains unreacted particulate copper. On the basis of the experimental results, the fixation mechanism is thought to be triggered by the reaction between the carboxylic acid protons in hemicellulose of wood with the particulate copper, and the quantities of the solubilized and fixed copper species are determined by the availability of these acidic protons.
Wood preservatives using micronized particulate copper as the main active ingredient recently introduced in the USA have generated controversies due to their limited intrinsic solubility compared to the conventional soluble copper treatments. Because the availability of soluble copper ions is essential for these preservatives to provide an effective treatment, concerns centered on whether they are able to produce soluble copper when introduced into wood, and the copper fixation mechanism of the treatment is little understood. A combination of Electron Paramagnetic Resonance (EPR) spectroscopy and X-ray Fluorescence (XRF) spectroscopy has been successfully utilized to characterize and quantify solubilized and fixed copper species in micronized copper treated wood, which also contains unreacted particulate copper. On the basis of the experimental results, the fixation mechanism is thought to be triggered by the reaction between the carboxylic acid protons in hemicellulose of wood with the particulate copper, and the quantities of the solubilized and fixed copper species are determined by the availability of these acidic protons. Wood preservatives using micronized particulate copper as the main active ingredient recently introduced in the USA have generated controversies due to their limited intrinsic solubility compared to the conventional soluble copper treatments.
Author Kennepohl, Pierre
Ruddick, John N. R
Xue, Wei
AuthorAffiliation Department of Chemistry
The University of British Columbia
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Cites_doi 10.1128/AEM.13.5.732-737.1965
10.1002/(SICI)1521-4079(1998)33:1<51::AID-CRAT51>3.0.CO;2-H
10.1007/s00107-004-0555-1
10.1515/hf-2012-0136
10.1016/S0146-6380(01)00158-9
10.1111/j.1439-0434.2006.01132.x
10.1038/299618a0
10.1016/j.jhazmat.2010.01.128
10.1111/j.1365-2389.1989.tb01288.x
10.1111/j.1469-8137.1993.tb03796.x
10.1515/HF.2005.094
10.1007/s00226-012-0475-x
10.1007/BF02861716
10.1515/HF.2000.023
10.1515/hfsg.1978.32.6.209
10.1515/HF.2008.031
10.1515/hfsg.1995.49.6.483
10.1515/hfsg.1994.48.2.91
10.1515/hf-2014-0128
10.1515/HF.2000.060
10.1515/HF.2002.038
10.1016/S0038-1098(00)00365-3
10.1016/0016-7037(77)90156-9
10.1016/j.ibiod.2007.06.017
10.1515/HF.2001.095
10.1128/AEM.61.5.1968-1975.1995
10.1515/hf-2011-0152
10.1515/HF.2008.032
10.1016/0016-7037(80)90163-5
10.1163/22941932-90000351
10.1016/0003-9861(74)90298-7
10.1515/hf.2011.188
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References Tascioglu (C5DT03159A-(cit40)/*[position()=1]) 2005; 59
Hastrup (C5DT03159A-(cit53)/*[position()=1]) 2013; 67
Matsunaga (C5DT03159A-(cit23)/*[position()=1]) 2004; 25
Staccioli (C5DT03159A-(cit11)/*[position()=1]) 2000; 54
McCallan (C5DT03159A-(cit6)/*[position()=1]) 1949; 15
Peisach (C5DT03159A-(cit33)/*[position()=1]) 1974; 165
Astilleros (C5DT03159A-(cit18)/*[position()=1]) 1998; 33
Ratajczak (C5DT03159A-(cit30)/*[position()=1]) 2008; 62
Zahora (C5DT03159A-(cit24)/*[position()=1]) 2011
Goodman (C5DT03159A-(cit49)/*[position()=1]) 1982; 299
Templeton III (C5DT03159A-(cit50)/*[position()=1]) 1980; 44
Levy (C5DT03159A-(cit27)/*[position()=1]) 1978; 32
Kofoed (C5DT03159A-(cit19)/*[position()=1]) 2010
Hughes (C5DT03159A-(cit28)/*[position()=1]) 1994; 48
Zhang (C5DT03159A-(cit20)/*[position()=1]) 2009
Lucas (C5DT03159A-(cit13)/*[position()=1]) 2002
Humar (C5DT03159A-(cit4)/*[position()=1]) 2008; 62
Xue (C5DT03159A-(cit42)/*[position()=1]) 2015; 69
Ruddick (C5DT03159A-(cit36)/*[position()=1]) 2001; 55
Jin (C5DT03159A-(cit45)/*[position()=1]) 2010
Kartal (C5DT03159A-(cit44)/*[position()=1]) 2013
Stirling (C5DT03159A-(cit21)/*[position()=1]) 2010
Freeman (C5DT03159A-(cit5)/*[position()=1]) 2008; 58
Ruddick (C5DT03159A-(cit35)/*[position()=1]) 1992; 13
Choi (C5DT03159A-(cit15)/*[position()=1]) 2007
Ahn (C5DT03159A-(cit22)/*[position()=1]) 2010; 178
Hoffmann (C5DT03159A-(cit9)/*[position()=1]) 2008; 62
Yamamoto (C5DT03159A-(cit32)/*[position()=1]) 1992
Dhyani (C5DT03159A-(cit8)/*[position()=1]) 2012; 46
FAO (C5DT03159A-(cit1)/*[position()=1]) 2010
Jiang (C5DT03159A-(cit12)/*[position()=1]) 2004; 54
Jerzykiewicz (C5DT03159A-(cit48)/*[position()=1]) 2002; 33
Xue (C5DT03159A-(cit38)/*[position()=1]) 2012; 66
Janod (C5DT03159A-(cit37)/*[position()=1]) 2000; 116
Xue (C5DT03159A-(cit39)/*[position()=1]) 2013; 67
Fengel (C5DT03159A-(cit41)/*[position()=1]) 2011
Gadd (C5DT03159A-(cit3)/*[position()=1]) 1993; 124
Senesi (C5DT03159A-(cit46)/*[position()=1]) 1977; 41
Montag (C5DT03159A-(cit7)/*[position()=1]) 2006; 154
Takao (C5DT03159A-(cit51)/*[position()=1]) 1965; 13
Xie (C5DT03159A-(cit34)/*[position()=1]) 1995; 49
Lee (C5DT03159A-(cit10)/*[position()=1]) 2010; 64
Eaton (C5DT03159A-(cit2)/*[position()=1]) 1993
Pankras (C5DT03159A-(cit26)/*[position()=1]) 2012; 66
Ung (C5DT03159A-(cit14)/*[position()=1]) 2005; 63
Humar (C5DT03159A-(cit29)/*[position()=1]) 2002; 56
Zahora (C5DT03159A-(cit25)/*[position()=1]) 2010
Senesi (C5DT03159A-(cit47)/*[position()=1]) 1989; 40
Caesar-Tonthat (C5DT03159A-(cit52)/*[position()=1]) 1995; 61
Zhang (C5DT03159A-(cit31)/*[position()=1]) 2000; 54
Sjöström (C5DT03159A-(cit43)/*[position()=1]) 1993
References_xml – issn: 1993
  end-page: 23-35
  publication-title: Wood: Decay, Pests and Protection
  doi: Eaton Hale
– issn: 2011
  publication-title: Wood: Chemistry, Ultrastructure, Reactions
  doi: Fengel Wegener
– issn: 2009
  end-page: US7632567B1
  publication-title: U.S. Pat. Appl. Publ
  doi: Osmose, Inc., USA.
– issn: 1993
  publication-title: Wood Chemistry: Fundamentals and Applications
  doi: Sjöström
– issn: 2006
  end-page: US20060288904A1
  publication-title: U.S. Pat. Appl. Publ
  doi: Osmose, Inc., USA.
– issn: 2010
  publication-title: Global forest resources assessment 2010 main report
  doi: FAO
– volume-title: Wood: Decay, Pests and Protection
  year: 1993
  ident: C5DT03159A-(cit2)/*[position()=1]
  contributor:
    fullname: Eaton
– year: 2007
  ident: C5DT03159A-(cit15)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Choi
– year: 1992
  ident: C5DT03159A-(cit32)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Yamamoto
– volume: 58
  start-page: 6
  year: 2008
  ident: C5DT03159A-(cit5)/*[position()=1]
  publication-title: For. Prod. J.
  contributor:
    fullname: Freeman
– volume: 64
  start-page: 653
  year: 2010
  ident: C5DT03159A-(cit10)/*[position()=1]
  publication-title: Holzforschung
  contributor:
    fullname: Lee
– volume: 13
  start-page: 732
  year: 1965
  ident: C5DT03159A-(cit51)/*[position()=1]
  publication-title: Appl. Microbiol.
  doi: 10.1128/AEM.13.5.732-737.1965
  contributor:
    fullname: Takao
– volume: 33
  start-page: 51
  year: 1998
  ident: C5DT03159A-(cit18)/*[position()=1]
  publication-title: Cryst. Res. Technol.
  doi: 10.1002/(SICI)1521-4079(1998)33:1<51::AID-CRAT51>3.0.CO;2-H
  contributor:
    fullname: Astilleros
– volume: 13
  start-page: 116
  year: 1992
  ident: C5DT03159A-(cit35)/*[position()=1]
  publication-title: Proc. Can. Wood Preserv. Assoc.
  contributor:
    fullname: Ruddick
– volume: 63
  start-page: 186
  year: 2005
  ident: C5DT03159A-(cit14)/*[position()=1]
  publication-title: Holz als Roh- und Werkst.
  doi: 10.1007/s00107-004-0555-1
  contributor:
    fullname: Ung
– volume: 67
  start-page: 815
  year: 2013
  ident: C5DT03159A-(cit39)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/hf-2012-0136
  contributor:
    fullname: Xue
– volume: 33
  start-page: 265
  year: 2002
  ident: C5DT03159A-(cit48)/*[position()=1]
  publication-title: Org. Geochem.
  doi: 10.1016/S0146-6380(01)00158-9
  contributor:
    fullname: Jerzykiewicz
– volume: 154
  start-page: 474
  year: 2006
  ident: C5DT03159A-(cit7)/*[position()=1]
  publication-title: J. Phytopathol.
  doi: 10.1111/j.1439-0434.2006.01132.x
  contributor:
    fullname: Montag
– volume: 299
  start-page: 618
  year: 1982
  ident: C5DT03159A-(cit49)/*[position()=1]
  publication-title: Nature
  doi: 10.1038/299618a0
  contributor:
    fullname: Goodman
– volume-title: Global forest resources assessment 2010 main report
  year: 2010
  ident: C5DT03159A-(cit1)/*[position()=1]
  contributor:
    fullname: FAO
– year: 2010
  ident: C5DT03159A-(cit19)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Kofoed
– volume: 178
  start-page: 604
  year: 2010
  ident: C5DT03159A-(cit22)/*[position()=1]
  publication-title: J. Hazard. Mater.
  doi: 10.1016/j.jhazmat.2010.01.128
  contributor:
    fullname: Ahn
– year: 2009
  ident: C5DT03159A-(cit20)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Zhang
– volume: 66
  start-page: 505
  year: 2012
  ident: C5DT03159A-(cit26)/*[position()=1]
  publication-title: Holzforschung
  contributor:
    fullname: Pankras
– volume: 40
  start-page: 461
  year: 1989
  ident: C5DT03159A-(cit47)/*[position()=1]
  publication-title: J. Soil Sci.
  doi: 10.1111/j.1365-2389.1989.tb01288.x
  contributor:
    fullname: Senesi
– volume: 124
  start-page: 25
  year: 1993
  ident: C5DT03159A-(cit3)/*[position()=1]
  publication-title: New Phytol.
  doi: 10.1111/j.1469-8137.1993.tb03796.x
  contributor:
    fullname: Gadd
– volume: 59
  start-page: 574
  year: 2005
  ident: C5DT03159A-(cit40)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/HF.2005.094
  contributor:
    fullname: Tascioglu
– volume: 46
  start-page: 1203
  year: 2012
  ident: C5DT03159A-(cit8)/*[position()=1]
  publication-title: Wood Sci. Technol.
  doi: 10.1007/s00226-012-0475-x
  contributor:
    fullname: Dhyani
– volume: 15
  start-page: 629
  year: 1949
  ident: C5DT03159A-(cit6)/*[position()=1]
  publication-title: Bot. Rev.
  doi: 10.1007/BF02861716
  contributor:
    fullname: McCallan
– year: 2010
  ident: C5DT03159A-(cit45)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Jin
– volume: 54
  start-page: 133
  year: 2000
  ident: C5DT03159A-(cit11)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/HF.2000.023
  contributor:
    fullname: Staccioli
– volume: 32
  start-page: 209
  year: 1978
  ident: C5DT03159A-(cit27)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/hfsg.1978.32.6.209
  contributor:
    fullname: Levy
– volume: 62
  start-page: 294
  year: 2008
  ident: C5DT03159A-(cit30)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/HF.2008.031
  contributor:
    fullname: Ratajczak
– volume: 49
  start-page: 483
  year: 1995
  ident: C5DT03159A-(cit34)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/hfsg.1995.49.6.483
  contributor:
    fullname: Xie
– volume: 48
  start-page: 91
  year: 1994
  ident: C5DT03159A-(cit28)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/hfsg.1994.48.2.91
  contributor:
    fullname: Hughes
– volume: 69
  start-page: 509
  year: 2015
  ident: C5DT03159A-(cit42)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/hf-2014-0128
  contributor:
    fullname: Xue
– volume: 54
  start-page: 343
  year: 2000
  ident: C5DT03159A-(cit31)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/HF.2000.060
  contributor:
    fullname: Zhang
– volume: 56
  start-page: 229
  year: 2002
  ident: C5DT03159A-(cit29)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/HF.2002.038
  contributor:
    fullname: Humar
– volume: 116
  start-page: 513
  year: 2000
  ident: C5DT03159A-(cit37)/*[position()=1]
  publication-title: Solid State Commun.
  doi: 10.1016/S0038-1098(00)00365-3
  contributor:
    fullname: Janod
– year: 2010
  ident: C5DT03159A-(cit25)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Zahora
– volume: 41
  start-page: 969
  year: 1977
  ident: C5DT03159A-(cit46)/*[position()=1]
  publication-title: Geochim. Cosmochim. Acta
  doi: 10.1016/0016-7037(77)90156-9
  contributor:
    fullname: Senesi
– volume: 62
  start-page: 46
  year: 2008
  ident: C5DT03159A-(cit4)/*[position()=1]
  publication-title: Int. Biodeterior. Biodegrad.
  doi: 10.1016/j.ibiod.2007.06.017
  contributor:
    fullname: Humar
– volume: 55
  start-page: 585
  year: 2001
  ident: C5DT03159A-(cit36)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/HF.2001.095
  contributor:
    fullname: Ruddick
– volume: 61
  start-page: 1968
  year: 1995
  ident: C5DT03159A-(cit52)/*[position()=1]
  publication-title: Appl. Environ. Microbiol.
  doi: 10.1128/AEM.61.5.1968-1975.1995
  contributor:
    fullname: Caesar-Tonthat
– volume: 67
  start-page: 99
  year: 2013
  ident: C5DT03159A-(cit53)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/hf-2011-0152
  contributor:
    fullname: Hastrup
– volume: 54
  start-page: 213
  year: 2004
  ident: C5DT03159A-(cit12)/*[position()=1]
  publication-title: For. Prod. J.
  contributor:
    fullname: Jiang
– year: 2013
  ident: C5DT03159A-(cit44)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Kartal
– volume-title: Wood: Chemistry, Ultrastructure, Reactions
  year: 2011
  ident: C5DT03159A-(cit41)/*[position()=1]
  contributor:
    fullname: Fengel
– volume: 62
  start-page: 300
  year: 2008
  ident: C5DT03159A-(cit9)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/HF.2008.032
  contributor:
    fullname: Hoffmann
– volume-title: Wood Chemistry: Fundamentals and Applications
  year: 1993
  ident: C5DT03159A-(cit43)/*[position()=1]
  contributor:
    fullname: Sjöström
– year: 2002
  ident: C5DT03159A-(cit13)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Lucas
– volume: 44
  start-page: 741
  year: 1980
  ident: C5DT03159A-(cit50)/*[position()=1]
  publication-title: Geochim. Cosmochim. Acta
  doi: 10.1016/0016-7037(80)90163-5
  contributor:
    fullname: Templeton III
– volume: 25
  start-page: 79
  year: 2004
  ident: C5DT03159A-(cit23)/*[position()=1]
  publication-title: IAWA J.
  doi: 10.1163/22941932-90000351
  contributor:
    fullname: Matsunaga
– volume: 165
  start-page: 691
  year: 1974
  ident: C5DT03159A-(cit33)/*[position()=1]
  publication-title: Arch. Biochem. Biophys.
  doi: 10.1016/0003-9861(74)90298-7
  contributor:
    fullname: Peisach
– volume: 66
  start-page: 889
  year: 2012
  ident: C5DT03159A-(cit38)/*[position()=1]
  publication-title: Holzforschung
  doi: 10.1515/hf.2011.188
  contributor:
    fullname: Xue
– year: 2010
  ident: C5DT03159A-(cit21)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Stirling
– year: 2011
  ident: C5DT03159A-(cit24)/*[position()=1]
  publication-title: Int. Res. Gr. Wood Preserv.
  contributor:
    fullname: Zahora
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Snippet Wood preservatives using micronized particulate copper as the main active ingredient recently introduced in the USA have generated controversies due to their...
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StartPage 3679
SubjectTerms Availability
Copper
COPPER IONS
Fixation
MICA
PRESERVATIVES
Solubility
Spectroscopy
Wood
X-ray fluorescence
Title Solubilisation and chemical fixation of copper(ii) in micronized copper treated wood
URI https://www.ncbi.nlm.nih.gov/pubmed/26819092
https://search.proquest.com/docview/1768168111
https://search.proquest.com/docview/1816005324
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