Metal-organic frameworks as potential catalysts for biodiesel production and biomass conversion: Mechanism and characteristics

This comprehensive assessment examines the key challenges confronting the transportation sector, a major source of greenhouse gas emissions. These issues include rising fuel costs and declining reserves. Although electric mobility is becoming more popular in light-duty transportation, heavy-duty tru...

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Published inIndustrial crops and products Vol. 211; p. 118232
Main Authors Le, Thanh Tuan, Sharma, Prabhakar, Le, Huu Son, Le, Huu Cuong, Le, Duc Trong Nguyen, Cao, Dao Nam, Truong, Thanh Hai, Tran, Viet Dung
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2024
Subjects
animals
biodiesel
Biodiesel synthesis
biomass
Biomass conversion
Catalytic characteristic
Green chemistry
greenhouse gases
Metal-organic frameworks
nanopores
pollutants
Reaction mechanism
toxicity
transportation
transportation industry
vegetables
Reaction mechanism
Biodiesel synthesis
Green chemistry
Catalytic characteristic
Biomass conversion
Metal-organic frameworks
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Abstract This comprehensive assessment examines the key challenges confronting the transportation sector, a major source of greenhouse gas emissions. These issues include rising fuel costs and declining reserves. Although electric mobility is becoming more popular in light-duty transportation, heavy-duty trucks continue to rely heavily on diesel engines. Biofuels are the subject of extensive research as both a financially viable and environmentally conscious alternative. Biodiesel derived from animal fats and vegetable oils is widely recognized for its natural decomposition, low toxicity, low pollutant emissions, and renewable properties. Catalysts aid in the chemical transformation of biomass, an important renewable energy source around the world. Solid acid catalysts are becoming increasingly important in improving the quality of biomass. This study analyzes the ability of metal-organic frameworks (MOFs), which are hybrid nanoporous materials, to act as catalysts in biomass conversion and biodiesel production. MOFs offer exceptional performance attributes, including large surface areas and customizable pore architectures, making them highly versatile for various applications. The review analyzes the role of MOF-based catalysts in accelerating biomass conversions and biodiesel synthesis, focusing on their structural properties, benefits, and challenges. This work provides useful insights into the significance of MOFs. It emphasizes MOFs as critical catalysts for promoting green chemistry practices and advancing the paradigm of sustainable energy production. •MOF is found as efficient catalyst for biodiesel production and biomass conversion.•Synthesis process and main properties of MOF catalysts are completely presented.•Catalytic reaction mechanisms of MOF for biofuel synthesis are scrutinized.•Challenges and perspectives of MOF catalysts are discussed in detail.
AbstractList This comprehensive assessment examines the key challenges confronting the transportation sector, a major source of greenhouse gas emissions. These issues include rising fuel costs and declining reserves. Although electric mobility is becoming more popular in light-duty transportation, heavy-duty trucks continue to rely heavily on diesel engines. Biofuels are the subject of extensive research as both a financially viable and environmentally conscious alternative. Biodiesel derived from animal fats and vegetable oils is widely recognized for its natural decomposition, low toxicity, low pollutant emissions, and renewable properties. Catalysts aid in the chemical transformation of biomass, an important renewable energy source around the world. Solid acid catalysts are becoming increasingly important in improving the quality of biomass. This study analyzes the ability of metal-organic frameworks (MOFs), which are hybrid nanoporous materials, to act as catalysts in biomass conversion and biodiesel production. MOFs offer exceptional performance attributes, including large surface areas and customizable pore architectures, making them highly versatile for various applications. The review analyzes the role of MOF-based catalysts in accelerating biomass conversions and biodiesel synthesis, focusing on their structural properties, benefits, and challenges. This work provides useful insights into the significance of MOFs. It emphasizes MOFs as critical catalysts for promoting green chemistry practices and advancing the paradigm of sustainable energy production. •MOF is found as efficient catalyst for biodiesel production and biomass conversion.•Synthesis process and main properties of MOF catalysts are completely presented.•Catalytic reaction mechanisms of MOF for biofuel synthesis are scrutinized.•Challenges and perspectives of MOF catalysts are discussed in detail.
This comprehensive assessment examines the key challenges confronting the transportation sector, a major source of greenhouse gas emissions. These issues include rising fuel costs and declining reserves. Although electric mobility is becoming more popular in light-duty transportation, heavy-duty trucks continue to rely heavily on diesel engines. Biofuels are the subject of extensive research as both a financially viable and environmentally conscious alternative. Biodiesel derived from animal fats and vegetable oils is widely recognized for its natural decomposition, low toxicity, low pollutant emissions, and renewable properties. Catalysts aid in the chemical transformation of biomass, an important renewable energy source around the world. Solid acid catalysts are becoming increasingly important in improving the quality of biomass. This study analyzes the ability of metal-organic frameworks (MOFs), which are hybrid nanoporous materials, to act as catalysts in biomass conversion and biodiesel production. MOFs offer exceptional performance attributes, including large surface areas and customizable pore architectures, making them highly versatile for various applications. The review analyzes the role of MOF-based catalysts in accelerating biomass conversions and biodiesel synthesis, focusing on their structural properties, benefits, and challenges. This work provides useful insights into the significance of MOFs. It emphasizes MOFs as critical catalysts for promoting green chemistry practices and advancing the paradigm of sustainable energy production.
ArticleNumber 118232
Author Le, Huu Son
Truong, Thanh Hai
Le, Thanh Tuan
Tran, Viet Dung
Cao, Dao Nam
Le, Duc Trong Nguyen
Sharma, Prabhakar
Le, Huu Cuong
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  givenname: Prabhakar
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  givenname: Huu Son
  surname: Le
  fullname: Le, Huu Son
  email: son.lh@vlu.edu.vn
  organization: Faculty of Automotive Engineering, School of Technology, Van Lang University, Ho Chi Minh City, Vietnam
– sequence: 4
  givenname: Huu Cuong
  surname: Le
  fullname: Le, Huu Cuong
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  organization: Faculty of Automotive Engineering, Dong A University, Danang, Vietnam
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  givenname: Dao Nam
  surname: Cao
  fullname: Cao, Dao Nam
  organization: PATET Research Group, Ho Chi Minh City University of Transport, Ho Chi Minh City, Vietnam
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  fullname: Truong, Thanh Hai
  organization: PATET Research Group, Ho Chi Minh City University of Transport, Ho Chi Minh City, Vietnam
– sequence: 8
  givenname: Viet Dung
  surname: Tran
  fullname: Tran, Viet Dung
  organization: PATET Research Group, Ho Chi Minh City University of Transport, Ho Chi Minh City, Vietnam
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Snippet This comprehensive assessment examines the key challenges confronting the transportation sector, a major source of greenhouse gas emissions. These issues...
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SubjectTerms animals
biodiesel
Biodiesel synthesis
biomass
Biomass conversion
Catalytic characteristic
Green chemistry
greenhouse gases
Metal-organic frameworks
nanopores
pollutants
Reaction mechanism
toxicity
transportation
transportation industry
vegetables
Title Metal-organic frameworks as potential catalysts for biodiesel production and biomass conversion: Mechanism and characteristics
URI https://dx.doi.org/10.1016/j.indcrop.2024.118232
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