Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS

The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the dis...

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Published inJournal of polymer science. Part B, Polymer physics Vol. 43; no. 21; pp. 2981 - 2992
Main Authors Prado, Luís A. S. de A., Goerigk, G., Ponce, M. L., Garamus, V. M., Wittich, H., Willumeit, R., Schulte, K., Nunes, S. P.
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LanguageEnglish
Published Hoboken Wiley Subscription Services, Inc., A Wiley Company 01.11.2005
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Abstract The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2981–2992, 2005
AbstractList The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2981–2992, 2005
Abstract The distribution of ZrO 2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO 2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2981–2992, 2005
Author Ponce, M. L.
Nunes, S. P.
Goerigk, G.
Wittich, H.
Prado, Luís A. S. de A.
Willumeit, R.
Schulte, K.
Garamus, V. M.
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Issue 21
Keywords Tungsten compound
Dispersion degree
Hybrid material
Zirconium IV Oxides
Polymer solid electrolyte
Ether copolymer
Small angle X ray scattering
Experimental study
Functional polymer
Ketone copolymer
Sulfonate copolymer
Heteropolyacid
Cation exchange membrane
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Snippet The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering...
Abstract The distribution of ZrO 2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray...
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SubjectTerms anomalous small-angle X-ray scattering
Applied sciences
Exact sciences and technology
Exchange resins and membranes
Forms of application and semi-finished materials
organic-inorganic hybrid materials
Polymer industry, paints, wood
proton-conducting membranes
Technology of polymers
Title Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS
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