Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS
The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the dis...
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Published in | Journal of polymer science. Part B, Polymer physics Vol. 43; no. 21; pp. 2981 - 2992 |
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Abstract | The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2981–2992, 2005 |
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AbstractList | The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2981–2992, 2005 Abstract The distribution of ZrO 2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering (ASAXS). Scattering curves were obtained using X‐ray energies near the Zr and W absorption edges, allowing the independent analysis of the distribution of ZrO 2 and PTA in the sample. The interaction between both inorganic components improved their dispersion considerably when compared with films containing just one of the additives. The synergism was correlated to previous investigations concerning proton conductivity and permeability of the membranes developed for direct methanol fuel cell. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 2981–2992, 2005 |
Author | Ponce, M. L. Nunes, S. P. Goerigk, G. Wittich, H. Prado, Luís A. S. de A. Willumeit, R. Schulte, K. Garamus, V. M. |
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Keywords | Tungsten compound Dispersion degree Hybrid material Zirconium IV Oxides Polymer solid electrolyte Ether copolymer Small angle X ray scattering Experimental study Functional polymer Ketone copolymer Sulfonate copolymer Heteropolyacid Cation exchange membrane |
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Snippet | The distribution of ZrO2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray scattering... Abstract The distribution of ZrO 2 and phosphotungstic acid (PTA) in a matrix of sulfonated polyether ketone was investigated by anomalous small‐angle X‐ray... |
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SubjectTerms | anomalous small-angle X-ray scattering Applied sciences Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials organic-inorganic hybrid materials Polymer industry, paints, wood proton-conducting membranes Technology of polymers |
Title | Characterization of proton-conducting organic-inorganic polymeric materials by ASAXS |
URI | https://api.istex.fr/ark:/67375/WNG-WV6BJ60N-W/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fpolb.20576 |
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