First synthesis of P-aryl-phosphinosugars, organophosphorus analogues of C-arylglycosides
The synthesis of the first example of P-arylphosphinosugar is reported. The protected polyhydroxylated 1,2-oxaphosphinane is prepared by a two steps sequence (phenylphosphinate addition on protected mannofuranose followed by intramolecular transesterification) on gram scale. Deprotection of the di-i...
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Published in | Tetrahedron letters Vol. 46; no. 21; pp. 3741 - 3744 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
OXFORD
Elsevier Ltd
23.05.2005
Elsevier |
Subjects | |
Online Access | Get full text |
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