Superconducting properties of zinc substitution in Tl-2223 phase
The effect of partial replacement of copper by zinc in Tl 2Ba 2Ca 2Cu 3O 10− δ superconductor phase is studied. Superconducting samples of the nominal composition Tl 2Ba 2Ca 2Cu 3− x Zn x O 10− δ with x ranging from 0 to 0.6 are prepared under normal pressure by a one step of solid-state reaction te...
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| Published in | Journal of alloys and compounds Vol. 460; no. 1; pp. 500 - 506 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
28.07.2008
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| Subjects | |
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| Abstract | The effect of partial replacement of copper by zinc in Tl
2Ba
2Ca
2Cu
3O
10−
δ
superconductor phase is studied. Superconducting samples of the nominal composition Tl
2Ba
2Ca
2Cu
3−
x
Zn
x
O
10−
δ
with
x ranging from 0 to 0.6 are prepared under normal pressure by a one step of solid-state reaction technique. The samples are characterized by using X-ray powder diffraction, scanning electron microscope (SEM) and EDX. The X-ray data indicate that the partial replacement of Cu
2+ions by Zn
2+ions does not influence the tetragonal structure of the samples, and the lattice parameters
a and
c vary according to the difference in the ionic radii of Cu and Zn. The superconducting parameters, such as superconducting transition temperature
T
c, critical current density
J
c and irreversibility field
B
ir are calculated from electrical resistivity and AC-magnetic susceptibility measurements. |
|---|---|
| AbstractList | The effect of partial replacement of copper by zinc in Tl2Ba2Ca2Cu3O10-delta superconductor phase is studied. Superconducting samples of the nominal composition Tl2Ba2Ca2Cu3-xZnxO10-delta with x ranging from 0 to 0.6 are prepared under normal pressure by a one step of solid-state reaction technique. The samples are characterized by using X-ray powder diffraction, scanning electron microscope (SEM) and EDX. The X-ray data indicate that the partial replacement of Cu2+ions by Zn2+ions does not influence the tetragonal structure of the samples, and the lattice parameters a and c vary according to the difference in the ionic radii of Cu and Zn. The superconducting parameters, such as superconducting transition temperature Tc, critical current density Jc and irreversibility field Bir are calculated from electrical resistivity and AC-magnetic susceptibility measurements. The effect of partial replacement of copper by zinc in Tl 2Ba 2Ca 2Cu 3O 10− δ superconductor phase is studied. Superconducting samples of the nominal composition Tl 2Ba 2Ca 2Cu 3− x Zn x O 10− δ with x ranging from 0 to 0.6 are prepared under normal pressure by a one step of solid-state reaction technique. The samples are characterized by using X-ray powder diffraction, scanning electron microscope (SEM) and EDX. The X-ray data indicate that the partial replacement of Cu 2+ions by Zn 2+ions does not influence the tetragonal structure of the samples, and the lattice parameters a and c vary according to the difference in the ionic radii of Cu and Zn. The superconducting parameters, such as superconducting transition temperature T c, critical current density J c and irreversibility field B ir are calculated from electrical resistivity and AC-magnetic susceptibility measurements. |
| Author | Ibrahim, I.H. Abou-Aly, A.I. Awad, R. Isber, S. El-Korek, M. Faraj, A. |
| Author_xml | – sequence: 1 givenname: R. surname: Awad fullname: Awad, R. email: rawad64@yahoo.com organization: Physics Department, Faculty of Science, Alexandria University, Alexandria, Egypt – sequence: 2 givenname: A.I. surname: Abou-Aly fullname: Abou-Aly, A.I. organization: Physics Department, Faculty of Science, Alexandria University, Alexandria, Egypt – sequence: 3 givenname: I.H. surname: Ibrahim fullname: Ibrahim, I.H. organization: Physics Department, Faculty of Science, Alexandria University, Alexandria, Egypt – sequence: 4 givenname: M. surname: El-Korek fullname: El-Korek, M. organization: Physics Department, Faculty of Science, Beirut Arab University, Beirut, Lebanon – sequence: 5 givenname: S. surname: Isber fullname: Isber, S. organization: Physics Department, American University of Beirut, Bliss Street, P.O. Box 11-0236, Beirut, Lebanon – sequence: 6 givenname: A. surname: Faraj fullname: Faraj, A. organization: Physics Department, Faculty of Science, Beirut Arab University, Beirut, Lebanon |
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| Snippet | The effect of partial replacement of copper by zinc in Tl
2Ba
2Ca
2Cu
3O
10−
δ
superconductor phase is studied. Superconducting samples of the nominal... The effect of partial replacement of copper by zinc in Tl2Ba2Ca2Cu3O10-delta superconductor phase is studied. Superconducting samples of the nominal... |
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| SubjectTerms | AC-magnetic susceptibility Critical current density Irreversibility field Resistivity |
| Title | Superconducting properties of zinc substitution in Tl-2223 phase |
| URI | https://dx.doi.org/10.1016/j.jallcom.2007.05.100 https://search.proquest.com/docview/33594761 |
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