Towards Functional Fluorous Surfactants. Synthesis and Spectroscopic Features of Systematically Modified Sugar-Substituted Fluorous 1,2,3-Triazoles

• Published in: Journal of fluorine chemistry Vol. 234; pp. 109519 - 109531
• Main Authors: Ahmed, Ahmed M.A., Mohammed, Adnan I., Read, Roger W.
• Format: Journal Article
• Language: English
• Published: LAUSANNE Elsevier B.V 01.06.2020; Elsevier; Elsevier BV
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; Cycloaddition; Derivatives; dipolar cycloaddition; Esterification; fluorous 1,2,3-triazoles; fluorous surfactants; Galactose; Homology; Hydrophobicity; Libraries; NMR; NMR spectroscopic analysis; Nuclear magnetic resonance; Perfluoro compounds; Physical Sciences; Pollutants; Science & Technology; Solvation; Substitutes; Sugar; sugar triazoles; Surfactants; Triazoles; fluorous 1,2,3-triazoles; fluorous surfactants; NMR spectroscopic analysis; dipolar cycloaddition; sugar triazoles; SOLID-PHASE; CARBOHYDRATE; CONFORMATION; AMPHIPHILES; IODIDES; TEMPO CATALYST; LIQUID-CRYSTALS; REGIOSELECTIVE SYNTHESIS; ORGANOFLUORINE COMPOUNDS; FLUORINATED SURFACTANTS

1-Polyfluoroalkyl-triazol-4-yl-methyl and -ethyl ether glycosides and 1-glycosidyl-triazol-4-ylmethoxy-polyfluoroalkanes with systematically varied degrees of fluorination and substituent chain lengths, ring position, and free and protected sugar moieties have been synthesized by Cu(I)-induced Huisg...