Investigations into the slip behavior of zirconium diboride
The slip systems in ZrB2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a dislocation density of approximately 1013 m−2. The structure of the dislocations as well as the low density is in agreement with a ceramic that is hard...
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Published in | Journal of materials research Vol. 31; no. 18; pp. 2749 - 2756 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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New York, USA
Cambridge University Press
28.09.2016
Springer International Publishing Springer Nature B.V |
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Abstract | The slip systems in ZrB2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a dislocation density of approximately 1013 m−2. The structure of the dislocations as well as the low density is in agreement with a ceramic that is hard and brittle and dislocation nucleation and motion is restricted. The low temperature slip systems were found to include c-prismatic slip—
${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {0001} \right]\left( {\bar 1010} \right)$
—and a-pyramidal slip—
${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {11\bar 20} \right]\left( {\bar 1101} \right)$
whereas the elevated temperature sample revealed a-basal slip—
${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {11\bar 20} \right]\left( {0001} \right)$
. Density functional theory Generalized Stacking Fault Energy curves for perfect slip were calculated and agreed well with geometric considerations for slip, including interplanar spacing and planar packing. Though basal slip has the lowest fault energy, the presence of the other dislocation types is suggestive that the activation barrier is not a hindrance for the temperatures studied and is likely activated to increase the number of plastic degrees of freedom. |
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AbstractList | Abstract
The slip systems in ZrB
2
flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a dislocation density of approximately 10
13
m
−2
. The structure of the dislocations as well as the low density is in agreement with a ceramic that is hard and brittle and dislocation nucleation and motion is restricted. The low temperature slip systems were found to include c-prismatic slip—
${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {0001} \right]\left( {\bar 1010} \right)$
—and a-pyramidal slip—
${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {11\bar 20} \right]\left( {\bar 1101} \right)$
whereas the elevated temperature sample revealed a-basal slip—
${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {11\bar 20} \right]\left( {0001} \right)$
. Density functional theory Generalized Stacking Fault Energy curves for perfect slip were calculated and agreed well with geometric considerations for slip, including interplanar spacing and planar packing. Though basal slip has the lowest fault energy, the presence of the other dislocation types is suggestive that the activation barrier is not a hindrance for the temperatures studied and is likely activated to increase the number of plastic degrees of freedom. The slip systems in ZrB 2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a dislocation density of approximately 10 13 m −2 . The structure of the dislocations as well as the low density is in agreement with a ceramic that is hard and brittle and dislocation nucleation and motion is restricted. The low temperature slip systems were found to include c-prismatic slip— 1 / 3 [ 0001 ] ( 1 ¯ 010 ) —and a-pyramidal slip— 1 / 3 [ 11 2 ¯ 0 ] ( 1 ¯ 101 ) whereas the elevated temperature sample revealed a-basal slip— 1 / 3 [ 11 2 ¯ 0 ] ( 0001 ) . Density functional theory Generalized Stacking Fault Energy curves for perfect slip were calculated and agreed well with geometric considerations for slip, including interplanar spacing and planar packing. Though basal slip has the lowest fault energy, the presence of the other dislocation types is suggestive that the activation barrier is not a hindrance for the temperatures studied and is likely activated to increase the number of plastic degrees of freedom. The slip systems in ZrB2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a dislocation density of approximately 1013 m−2. The structure of the dislocations as well as the low density is in agreement with a ceramic that is hard and brittle and dislocation nucleation and motion is restricted. The low temperature slip systems were found to include c-prismatic slip— ${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {0001} \right]\left( {\bar 1010} \right)$ —and a-pyramidal slip— ${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {11\bar 20} \right]\left( {\bar 1101} \right)$ whereas the elevated temperature sample revealed a-basal slip— ${1 \mathord{\left/ {\vphantom {1 3}} \right. \kern-\nulldelimiterspace} 3}\left[ {11\bar 20} \right]\left( {0001} \right)$ . Density functional theory Generalized Stacking Fault Energy curves for perfect slip were calculated and agreed well with geometric considerations for slip, including interplanar spacing and planar packing. Though basal slip has the lowest fault energy, the presence of the other dislocation types is suggestive that the activation barrier is not a hindrance for the temperatures studied and is likely activated to increase the number of plastic degrees of freedom. The slip systems in ZrB2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a dislocation density of approximately 1013 m-2. The structure of the dislocations as well as the low density is in agreement with a ceramic that is hard and brittle and dislocation nucleation and motion is restricted. The low temperature slip systems were found to include c-prismatic slip-- [formula omitted: see PDF] --and a-pyramidal slip-- [formula omitted: see PDF] whereas the elevated temperature sample revealed a-basal slip-- [formula omitted: see PDF] . Density functional theory Generalized Stacking Fault Energy curves for perfect slip were calculated and agreed well with geometric considerations for slip, including interplanar spacing and planar packing. Though basal slip has the lowest fault energy, the presence of the other dislocation types is suggestive that the activation barrier is not a hindrance for the temperatures studied and is likely activated to increase the number of plastic degrees of freedom. |
Author | Hunter, Brett Fahrenholtz, William De Leon, Nicholas Thompson, Gregory B. Yu, Xiao-Xiang Hilmas, Greg Weinberger, Christopher Weaver, Mark L. |
Author_xml | – sequence: 1 givenname: Brett surname: Hunter fullname: Hunter, Brett organization: Department of Metallurgical & Materials Engineering, University of Alabama, Tuscaloosa, AL 35405 – sequence: 2 givenname: Xiao-Xiang surname: Yu fullname: Yu, Xiao-Xiang organization: Department of Metallurgical & Materials Engineering, University of Alabama, Tuscaloosa, AL 35405 – sequence: 3 givenname: Nicholas surname: De Leon fullname: De Leon, Nicholas organization: Department of Metallurgical & Materials Engineering, University of Alabama, Tuscaloosa, AL 35405 – sequence: 4 givenname: Christopher surname: Weinberger fullname: Weinberger, Christopher organization: † Department of Mechanical Engineering and Mechanics, Drexel University, Philadelphia, PA 19104 – sequence: 5 givenname: William surname: Fahrenholtz fullname: Fahrenholtz, William organization: ‡ Department of Materials Science & Engineering, Missouri S&T, Rolla, MO 65401 – sequence: 6 givenname: Greg surname: Hilmas fullname: Hilmas, Greg organization: ‡ Department of Materials Science & Engineering, Missouri S&T, Rolla, MO 65401 – sequence: 7 givenname: Mark L. surname: Weaver fullname: Weaver, Mark L. organization: Department of Metallurgical & Materials Engineering, University of Alabama, Tuscaloosa, AL 35405 – sequence: 8 givenname: Gregory B. surname: Thompson fullname: Thompson, Gregory B. email: gthompson@eng.ua.edu organization: Department of Metallurgical & Materials Engineering, University of Alabama, Tuscaloosa, AL 35405 |
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Snippet | The slip systems in ZrB2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a... The slip systems in ZrB 2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a... Abstract The slip systems in ZrB 2 flexural tested at 1000 °C and 1500 °C have been quantified. The dislocations in both samples were long and straight with a... |
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SubjectTerms | Analysis Applied and Technical Physics Biomaterials Ceramics Chemistry Deformation Focus Section Article Focus Section Articles Focus Section: Reinventing Boron Chemistry and Materials for the 21st Century Graphite Hot pressing Inorganic Chemistry Materials Engineering Materials research Materials Science Nanotechnology Oxidation Scanning electron microscopy Studies Temperature |
Title | Investigations into the slip behavior of zirconium diboride |
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