Symmetry and Phase-Selected NMR Spectra of Liquid Crystalline Samples
It is demonstrated that the NMR spectra of liquid crystalline samples can be simplified by using multiple quantum filtering. In a system of N spin-12nuclei, the N or (N-1)-multiple quantum filtered spectra (NQF or (N-1)QF) contain lines which originate only from transitions among the eigenstates bel...
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Published in | Journal of magnetic resonance (1997) Vol. 135; no. 2; pp. 298 - 309 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
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United States
Elsevier Inc
01.12.1998
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Abstract | It is demonstrated that the NMR spectra of liquid crystalline samples can be simplified by using multiple quantum filtering. In a system of N spin-12nuclei, the N or (N-1)-multiple quantum filtered spectra (NQF or (N-1)QF) contain lines which originate only from transitions among the eigenstates belonging to the highest symmetry class of the spin permutation group. In addition the NQF spectra are divided further into two sets of lines which differ in phase by 180°. A method for simulating and analysing multiple quantum filtered spectra is described, with examples from molecules with up to eight interacting spins. |
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AbstractList | It is demonstrated that the NMR spectra of liquid crystalline samples can be simplified by using multiple quantum filtering. In a system of N spin-12 nuclei, the N or (N-1)-multiple quantum filtered spectra (NQF or (N-1)QF) contain lines which originate only from transitions among the eigenstates belonging to the highest symmetry class of the spin permutation group. In addition the NQF spectra are divided further into two sets of lines which differ in phase by 180 degrees. A method for simulating and analysing multiple quantum filtered spectra is described, with examples from molecules with up to eight interacting spins. It is demonstrated that the NMR spectra of liquid crystalline samples can be simplified by using multiple quantum filtering. In a system of N spin-12nuclei, the N or (N-1)-multiple quantum filtered spectra (NQF or (N-1)QF) contain lines which originate only from transitions among the eigenstates belonging to the highest symmetry class of the spin permutation group. In addition the NQF spectra are divided further into two sets of lines which differ in phase by 180°. A method for simulating and analysing multiple quantum filtered spectra is described, with examples from molecules with up to eight interacting spins. |
Author | Longeri, M Palke, W.E De Luca, G Emsley, J.W Turner, D.L Carravetta, M Foord, E.K Castiglione, F Edgar, M Farrant, R.D Lindon, J.C |
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Cites_doi | 10.1063/1.1725826 10.1021/ar50039a001 10.1016/0009-2614(87)80064-7 10.1080/00268978300100381 10.1021/ci00019a011 |
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Snippet | It is demonstrated that the NMR spectra of liquid crystalline samples can be simplified by using multiple quantum filtering. In a system of N spin-12nuclei,... It is demonstrated that the NMR spectra of liquid crystalline samples can be simplified by using multiple quantum filtering. In a system of N spin-12 nuclei,... |
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SubjectTerms | Magnetic Resonance Spectroscopy |
Title | Symmetry and Phase-Selected NMR Spectra of Liquid Crystalline Samples |
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