On the mechanism of the catalytic destruction of 1,2-dichloroethane over Ce/Zr mixed oxide catalysts
The oxidation mechanism of the oxidation of 1,2-dichloroethane on Ce/Zr mixed oxides was investigated by means of a combined flow and infrared spectroscopy study. The decomposition occurs through by dehydrochlorination into vinyl chloride in the presence of acid sites. This intermediate can be attac...
Saved in:
Published in | Journal of molecular catalysis. A, Chemical Vol. 278; no. 1; pp. 181 - 188 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
14.12.2007
Elsevier |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | The oxidation mechanism of the oxidation of 1,2-dichloroethane on Ce/Zr mixed oxides was investigated by means of a combined flow and infrared spectroscopy study. The decomposition occurs through by dehydrochlorination into vinyl chloride in the presence of acid sites. This intermediate can be attacked by nucleophilic oxygen species from the catalyst to form chlorinated alkoxide species, which readily decompose to gradually generate acetaldehyde, acetates and CO
x
.
▪
This study has been undertaken to investigate the efficiency of ceria, zirconia, and Ce
x
Zr
1−
x
O
2 mixed oxides as catalysts for the 1,2-dichloroethane destruction in dry air. Mixed oxides exhibit promoted redox and acidic properties, which result catalytically relevant for the oxidation of this chlorinated compound. Considering all compositions it was observed that catalytic activity varies as a function of zirconia content, being Ce
0.5Zr
0.5O
2 the sample which showed a better performance. The notable improvement in catalyst activity of CeO
2 can be achieved through structural doping with Zr ions.
Likewise, the present study has been focused on the elucidation of the pathway involved in the progressive oxidation of the chlorinated hydrocarbon as a function of the temperature by means of FTIR. It is postulated that the destruction of 1,2-dichloroethane at low temperatures proceeds through dehydrochlorination into vinyl chloride in the presence of acid sites. This compound can be protonated in the presence of OH surface species forming carbonium ions that can be attacked by nucleophilic oxygen species from the catalyst to form chlorinated alkoxide species. These intermediates readily decompose to generate acetaldehyde, which can be further oxidised into acetates and finally degraded to CO
x
. |
---|---|
AbstractList | The oxidation mechanism of the oxidation of 1,2-dichloroethane on Ce/Zr mixed oxides was investigated by means of a combined flow and infrared spectroscopy study. The decomposition occurs through by dehydrochlorination into vinyl chloride in the presence of acid sites. This intermediate can be attacked by nucleophilic oxygen species from the catalyst to form chlorinated alkoxide species, which readily decompose to gradually generate acetaldehyde, acetates and CO
x
.
▪
This study has been undertaken to investigate the efficiency of ceria, zirconia, and Ce
x
Zr
1−
x
O
2 mixed oxides as catalysts for the 1,2-dichloroethane destruction in dry air. Mixed oxides exhibit promoted redox and acidic properties, which result catalytically relevant for the oxidation of this chlorinated compound. Considering all compositions it was observed that catalytic activity varies as a function of zirconia content, being Ce
0.5Zr
0.5O
2 the sample which showed a better performance. The notable improvement in catalyst activity of CeO
2 can be achieved through structural doping with Zr ions.
Likewise, the present study has been focused on the elucidation of the pathway involved in the progressive oxidation of the chlorinated hydrocarbon as a function of the temperature by means of FTIR. It is postulated that the destruction of 1,2-dichloroethane at low temperatures proceeds through dehydrochlorination into vinyl chloride in the presence of acid sites. This compound can be protonated in the presence of OH surface species forming carbonium ions that can be attacked by nucleophilic oxygen species from the catalyst to form chlorinated alkoxide species. These intermediates readily decompose to generate acetaldehyde, which can be further oxidised into acetates and finally degraded to CO
x
. |
Author | de Rivas, Beatriz López-Fonseca, Rubén González-Velasco, Juan R. Gutiérrez-Ortiz, José I. |
Author_xml | – sequence: 1 givenname: Beatriz surname: de Rivas fullname: de Rivas, Beatriz – sequence: 2 givenname: Rubén surname: López-Fonseca fullname: López-Fonseca, Rubén – sequence: 3 givenname: Juan R. surname: González-Velasco fullname: González-Velasco, Juan R. – sequence: 4 givenname: José I. surname: Gutiérrez-Ortiz fullname: Gutiérrez-Ortiz, José I. email: joseignacio.gutierrez@ehu.es |
BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19438504$$DView record in Pascal Francis |
BookMark | eNqFkE1LAzEQhoNUsK3-BCEXb-6abPYjOYkUv6DQi4J4CWkyoSm7m5LE0v57t7bi0dMM8877DvNM0Kj3PSB0TUlOCa3v1nnnW62SygtCmpyInJD6DI0pb1jGaPkxGnrGaUZpLS7QJMY1IaRkJR0js-hxWgHuQK9U72KHvf0ZHPLafXIaG4gpfOnkfH8Q6W2RGadXrQ8e0mAC7LcQ8AzuPgPu3A4M9jtnfiNiipfo3Ko2wtWpTtH70-Pb7CWbL55fZw_zTDMmUlYxIxrLrCZLUEvNOK9LVmlleAl1w4QlFBpSEGOqpRUVLxpeCKjZoBVG0YZNUXXM1cHHGMDKTXCdCntJiTygkmt5QiUPqCQRckA1-G6Ovo2KWrU2qF67-GcWJePVAGyK7o97MDyxdRBk1A56DcYF0Eka7_659A1r-YQo |
CitedBy_id | crossref_primary_10_1021_acs_est_1c08009 crossref_primary_10_1039_D0CY01060J crossref_primary_10_1002_ange_201510903 crossref_primary_10_1021_cs300644s crossref_primary_10_1016_j_apcatb_2009_04_017 crossref_primary_10_1016_j_cej_2015_10_025 crossref_primary_10_1016_j_apcata_2013_02_026 crossref_primary_10_1016_j_cej_2019_02_155 crossref_primary_10_1016_j_molcata_2014_05_035 crossref_primary_10_1016_j_chemosphere_2017_10_104 crossref_primary_10_3390_catal10121446 crossref_primary_10_1016_j_apcatb_2012_09_056 crossref_primary_10_3724_SP_J_1088_2012_11003 crossref_primary_10_1016_j_apcatb_2016_05_076 crossref_primary_10_1016_j_apcatb_2011_12_028 crossref_primary_10_1016_j_apcatb_2015_10_016 crossref_primary_10_1016_j_jiec_2018_03_016 crossref_primary_10_1016_j_apcatb_2012_07_008 crossref_primary_10_1016_j_apcata_2011_12_028 crossref_primary_10_1016_j_apcatb_2013_05_048 crossref_primary_10_1016_j_cej_2015_12_107 crossref_primary_10_1016_j_jre_2023_12_012 crossref_primary_10_3390_catal11080946 crossref_primary_10_1016_j_cej_2020_126534 crossref_primary_10_1021_acs_est_1c05586 crossref_primary_10_1039_C7CP08322J crossref_primary_10_1080_10643389_2020_1818490 crossref_primary_10_1007_s10562_013_1073_8 crossref_primary_10_1016_j_apcatb_2020_119577 crossref_primary_10_1016_j_cej_2017_04_002 crossref_primary_10_1039_C5RA07405C crossref_primary_10_1039_D1NR01538A crossref_primary_10_1016_j_cej_2013_08_107 crossref_primary_10_1016_j_jhazmat_2010_07_081 crossref_primary_10_3390_nano9050675 crossref_primary_10_1016_j_apcatb_2007_12_013 crossref_primary_10_1016_j_apcata_2017_10_006 crossref_primary_10_1016_j_apcatb_2019_01_023 crossref_primary_10_1016_j_chemosphere_2024_141948 crossref_primary_10_1016_j_apcatb_2015_03_015 crossref_primary_10_1016_j_cej_2016_03_032 crossref_primary_10_1021_acs_chemrev_8b00408 crossref_primary_10_1016_j_ces_2020_116405 crossref_primary_10_3390_catal8090358 crossref_primary_10_1016_j_apcatb_2011_03_003 crossref_primary_10_1016_j_jes_2016_07_014 crossref_primary_10_1021_acs_est_0c07326 crossref_primary_10_1016_j_apcatb_2013_11_041 crossref_primary_10_1016_j_apsusc_2021_151240 crossref_primary_10_1016_j_jre_2023_09_007 crossref_primary_10_1039_D2EN00951J crossref_primary_10_1016_j_jhazmat_2020_122218 crossref_primary_10_1016_j_apcatb_2010_09_034 crossref_primary_10_1016_j_jiec_2017_08_010 crossref_primary_10_1134_S0023158411020169 crossref_primary_10_1016_j_jcis_2015_10_061 crossref_primary_10_1007_s10562_016_1785_7 crossref_primary_10_1016_j_scitotenv_2022_161063 crossref_primary_10_1016_j_apcatb_2016_03_005 crossref_primary_10_1016_j_jhazmat_2017_08_036 crossref_primary_10_1002_anie_201510903 crossref_primary_10_1016_j_jre_2019_11_015 crossref_primary_10_1016_j_ces_2014_12_051 crossref_primary_10_1016_j_cattod_2019_05_016 crossref_primary_10_1039_D1DT02852A crossref_primary_10_1016_j_apcatb_2014_06_048 crossref_primary_10_1016_j_chemosphere_2009_02_019 crossref_primary_10_1016_S1872_2067_20_63653_1 crossref_primary_10_1016_j_apcatb_2012_09_026 crossref_primary_10_1021_acs_est_6b06585 crossref_primary_10_1016_j_ces_2019_05_051 crossref_primary_10_1016_j_molcata_2011_04_021 crossref_primary_10_1007_s10971_010_2186_9 crossref_primary_10_1016_j_jes_2014_09_032 crossref_primary_10_1016_j_apcatb_2019_03_077 crossref_primary_10_1016_j_apsusc_2021_150836 crossref_primary_10_1007_s10562_008_9672_5 |
Cites_doi | 10.1016/S0920-5861(02)00383-8 10.1039/a605341f 10.1016/j.jhazmat.2004.03.019 10.1016/j.jcat.2004.10.003 10.1021/jp0358376 10.1006/jcat.1999.2765 10.1016/S0920-5861(99)00163-7 10.1007/BF00767212 10.1002/(SICI)1096-9918(199908)28:1<123::AID-SIA632>3.0.CO;2-6 10.1023/A:1015376409863 10.1039/9781847553294-00105 10.1016/j.apcatb.2004.01.024 10.1016/S0926-3373(96)00078-1 10.1021/jp002509m 10.1016/S0926-860X(02)00460-X 10.1006/jcat.1998.2274 10.1016/S0926-860X(99)00283-5 10.1006/jcat.1999.2563 10.1006/jcat.1997.1443 10.1016/S0926-3373(02)00127-3 10.1016/S0920-5861(99)00169-8 10.1016/S1381-1169(02)00474-0 10.1016/S0167-2991(08)64199-3 10.1016/S0926-3373(99)00054-5 10.1021/ja00067a031 10.1006/jcat.1995.1132 10.1016/j.apcata.2004.04.014 10.1021/jp962530g 10.1016/j.apcatb.2004.01.005 10.1006/jcat.1995.1022 10.1016/S0920-5861(00)00438-7 10.1016/0920-5861(95)00095-W 10.1023/A:1016643232442 10.1007/BF02708797 10.1016/S1381-1169(97)00262-8 10.1016/S0920-5861(99)00045-0 10.1002/1096-9918(200008)30:1<273::AID-SIA715>3.0.CO;2-G 10.1016/S0920-5861(02)00037-8 10.1016/0021-9517(91)90124-M |
ContentType | Journal Article |
Copyright | 2007 Elsevier B.V. 2008 INIST-CNRS |
Copyright_xml | – notice: 2007 Elsevier B.V. – notice: 2008 INIST-CNRS |
DBID | IQODW AAYXX CITATION |
DOI | 10.1016/j.molcata.2007.09.006 |
DatabaseName | Pascal-Francis CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering Chemistry |
EISSN | 1873-314X |
EndPage | 188 |
ExternalDocumentID | 10_1016_j_molcata_2007_09_006 19438504 S1381116907005304 |
GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 29L 4.4 457 4G. 53G 5GY 5VS 7-5 71M 8P~ AABNK AACTN AAEDT AAEDW AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABFNM ABMAC ABNUV ABXDB ABYKQ ACDAQ ACGFS ACNCT ACNNM ACRLP ADBBV ADECG ADEWK ADEZE ADMUD AEBSH AEKER AFFNX AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AHPOS AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BKOJK BLXMC CS3 EBS EFJIC EJD ENUVR EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HVGLF HZ~ IHE J1W KOM M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SCB SDF SDG SDP SES SEW SPC SSG SSK SSZ T5K TN5 ZMT ABPIF IQODW AAXKI AAYXX AKRWK CITATION |
ID | FETCH-LOGICAL-c339t-53d97f3fc0beabc3886435cad84e6739f01e7020dd5bf95827829e636732da173 |
IEDL.DBID | AIKHN |
ISSN | 1381-1169 |
IngestDate | Thu Sep 12 17:15:11 EDT 2024 Sun Oct 22 16:05:31 EDT 2023 Fri Feb 23 02:28:44 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 1 |
Keywords | Ceria–zirconia mixed oxides 1,2-Dichloroethane Catalytic combustion IR-spectroscopy Oxidation mechanism Mixed catalyst Ternary compound Catalytic reaction Destruction Transition element compounds Cerium oxide Mechanism Lanthanide compound Infrared spectrometry Zirconia Zirconium oxide Chlorocarbon Oxidation Ceria-zirconia mixed oxides |
Language | English |
License | CC BY 4.0 |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c339t-53d97f3fc0beabc3886435cad84e6739f01e7020dd5bf95827829e636732da173 |
PageCount | 8 |
ParticipantIDs | crossref_primary_10_1016_j_molcata_2007_09_006 pascalfrancis_primary_19438504 elsevier_sciencedirect_doi_10_1016_j_molcata_2007_09_006 |
PublicationCentury | 2000 |
PublicationDate | 2007-12-14 |
PublicationDateYYYYMMDD | 2007-12-14 |
PublicationDate_xml | – month: 12 year: 2007 text: 2007-12-14 day: 14 |
PublicationDecade | 2000 |
PublicationPlace | Amsterdam |
PublicationPlace_xml | – name: Amsterdam |
PublicationTitle | Journal of molecular catalysis. A, Chemical |
PublicationYear | 2007 |
Publisher | Elsevier B.V Elsevier |
Publisher_xml | – name: Elsevier B.V – name: Elsevier |
References | Centi, Ciambelli, Perathoner, Russo (bib1) 2002; 75 Ouyang, Yao (bib39) 2000; 104 Álvarez-Galván, Pawelec, de la Peña O'Shea, Fierro, Arias (bib6) 2004; 51 Feijen-Jeurissen, Jorna, Nieuwenhuys, Sinquin, Petit, Hindermann (bib15) 1999; 54 Liu, Flytzani-Stephanopoulos (bib11) 1995; 153 Daturi, Binet, Lavalley, Blanchard (bib35) 2000; 30 Reddy, Khan, Yamada, Kobayashi, Loridant, Volta (bib20) 2003; 107 Hannus (bib24) 1999; 189 Setiabudi, Chen, Mul, Makkee, Moulijn (bib14) 2004; 51 Li, Xin, Guo (bib40) 1992; 12 Boaro, Vicario, de Leitenburg, Dolcetti, Trovarelli (bib21) 2003; 77 González-Velasco, Gutiérrez-Ortiz, Marc, Botas, González-Marcos, Blanchard (bib9) 1999; 22 Everaert, Baeyens (bib4) 2004; 109 Feaver, Rossin (bib28) 1999; 54 Sohn, Ryu (bib33) 2001; 74 Yee, Morrison, Idriss (bib38) 2000; 191 Finocchio, Willey, Busca, Lorenzelli (bib23) 1997; 93 Balducci, Kaspar, Fornasiero, Graziani (bib22) 1997; 101 Tajima, Niwa, Fuji, Koinuma, Aizawa, Kushiyama, Kobayashi, Mizuno, Ohuchi (bib29) 1997; 12 Kang, Lee, Lee, Chung, Yoon, Ogino, Miyata, Choung (bib36) 2003; 193 Liotta, Macaluso, Longo, Pantaleo, Martorana, Deganello (bib10) 2003; 240 López-Fonseca, Aranzabal, Steltenpohl, Gutiérrez-Ortiz, González-Velasco (bib18) 2000; 62 Heneghan, Hutchings, Taylor (bib2) 2004; 17 López-Fonseca, Gutiérrez-Ortiz, Gutiérrez-Ortiz, González-Velasco (bib25) 2003; 2 Windawi, Wyatt (bib3) 1993; 37 Miao, Yang, Cai (bib30) 1999; 28 Trovarelli (bib7) 2002 Gluhoi, Bogdanchikova, Nieuwenhuys (bib8) 2005; 229 Krishnamoorthy, Amiridis (bib17) 1999; 51 van den Brink, Mulder, Louw, Sinquin, Petit, Hindermann (bib26) 1998; 180 Scire, Minico, Cristafulli, Satriano, Pistone (bib13) 2003; 40 Driessen, Miller, Grassian (bib34) 1998; 131 Finocchio, Busca, Lorenzelli, Willey (bib41) 1995; 151 Cutrufello, Ferino, Monaci, Rombi, Solinas (bib32) 2002; 19 Liu, Cheng (bib27) 1995; 26 Yee, Morrison, Idriss (bib37) 1999; 186 Li, Xin, Guo, Onishi (bib12) 1993; 75 Gutiérrez-Ortiz, de Rivas, López-Fonseca, González-Velasco (bib19) 2004; 269 Ranga Rao, Ranjan Sahu (bib31) 2001; 113 Chintawar, Greene (bib16) 1997; 165 Petrosius, Drago, Young, Grunewald (bib5) 1993; 115 Ranga Rao (10.1016/j.molcata.2007.09.006_bib31) 2001; 113 Álvarez-Galván (10.1016/j.molcata.2007.09.006_bib6) 2004; 51 Feaver (10.1016/j.molcata.2007.09.006_bib28) 1999; 54 Sohn (10.1016/j.molcata.2007.09.006_bib33) 2001; 74 Driessen (10.1016/j.molcata.2007.09.006_bib34) 1998; 131 Tajima (10.1016/j.molcata.2007.09.006_bib29) 1997; 12 Gutiérrez-Ortiz (10.1016/j.molcata.2007.09.006_bib19) 2004; 269 Everaert (10.1016/j.molcata.2007.09.006_bib4) 2004; 109 Hannus (10.1016/j.molcata.2007.09.006_bib24) 1999; 189 Petrosius (10.1016/j.molcata.2007.09.006_bib5) 1993; 115 Li (10.1016/j.molcata.2007.09.006_bib12) 1993; 75 Setiabudi (10.1016/j.molcata.2007.09.006_bib14) 2004; 51 Krishnamoorthy (10.1016/j.molcata.2007.09.006_bib17) 1999; 51 Daturi (10.1016/j.molcata.2007.09.006_bib35) 2000; 30 Gluhoi (10.1016/j.molcata.2007.09.006_bib8) 2005; 229 Boaro (10.1016/j.molcata.2007.09.006_bib21) 2003; 77 Liu (10.1016/j.molcata.2007.09.006_bib27) 1995; 26 Liu (10.1016/j.molcata.2007.09.006_bib11) 1995; 153 Choudhary (10.1016/j.molcata.2007.09.006_bib42) 1991; 130 González-Velasco (10.1016/j.molcata.2007.09.006_bib9) 1999; 22 Ouyang (10.1016/j.molcata.2007.09.006_bib39) 2000; 104 López-Fonseca (10.1016/j.molcata.2007.09.006_bib18) 2000; 62 Liotta (10.1016/j.molcata.2007.09.006_bib10) 2003; 240 Kang (10.1016/j.molcata.2007.09.006_bib36) 2003; 193 Chintawar (10.1016/j.molcata.2007.09.006_bib16) 1997; 165 Heneghan (10.1016/j.molcata.2007.09.006_bib2) 2004; 17 Yee (10.1016/j.molcata.2007.09.006_bib37) 1999; 186 Finocchio (10.1016/j.molcata.2007.09.006_bib23) 1997; 93 Feijen-Jeurissen (10.1016/j.molcata.2007.09.006_bib15) 1999; 54 Yee (10.1016/j.molcata.2007.09.006_bib38) 2000; 191 Li (10.1016/j.molcata.2007.09.006_bib40) 1992; 12 Reddy (10.1016/j.molcata.2007.09.006_bib20) 2003; 107 Scire (10.1016/j.molcata.2007.09.006_bib13) 2003; 40 van den Brink (10.1016/j.molcata.2007.09.006_bib26) 1998; 180 Cutrufello (10.1016/j.molcata.2007.09.006_bib32) 2002; 19 Balducci (10.1016/j.molcata.2007.09.006_bib22) 1997; 101 Miao (10.1016/j.molcata.2007.09.006_bib30) 1999; 28 Centi (10.1016/j.molcata.2007.09.006_bib1) 2002; 75 López-Fonseca (10.1016/j.molcata.2007.09.006_bib25) 2003; 2 Windawi (10.1016/j.molcata.2007.09.006_bib3) 1993; 37 Trovarelli (10.1016/j.molcata.2007.09.006_bib7) 2002 Finocchio (10.1016/j.molcata.2007.09.006_bib41) 1995; 151 |
References_xml | – volume: 54 start-page: 13 year: 1999 ident: bib28 publication-title: Catal. Today contributor: fullname: Rossin – volume: 17 start-page: 105 year: 2004 ident: bib2 publication-title: Catalysis contributor: fullname: Taylor – volume: 77 start-page: 407 year: 2003 ident: bib21 publication-title: Catal. Today contributor: fullname: Trovarelli – volume: 115 start-page: 6131 year: 1993 ident: bib5 publication-title: J. Am. Chem. Soc. contributor: fullname: Grunewald – volume: 131 start-page: 149 year: 1998 ident: bib34 publication-title: J. Mol. Catal. A contributor: fullname: Grassian – volume: 113 start-page: 651 year: 2001 ident: bib31 publication-title: Proc. Indian Acad. Chem. Sci. contributor: fullname: Ranjan Sahu – volume: 54 start-page: 65 year: 1999 ident: bib15 publication-title: Catal. Today contributor: fullname: Hindermann – volume: 51 start-page: 83 year: 2004 ident: bib6 publication-title: Appl. Catal. B contributor: fullname: Arias – volume: 40 start-page: 43 year: 2003 ident: bib13 publication-title: Appl. Catal. B contributor: fullname: Pistone – volume: 180 start-page: 153 year: 1998 ident: bib26 publication-title: J. Catal. contributor: fullname: Hindermann – volume: 101 start-page: 1750 year: 1997 ident: bib22 publication-title: J. Phys. Chem. B contributor: fullname: Graziani – volume: 62 start-page: 367 year: 2000 ident: bib18 publication-title: Catal. Today contributor: fullname: González-Velasco – volume: 269 start-page: 147 year: 2004 ident: bib19 publication-title: Appl. Catal. A contributor: fullname: González-Velasco – volume: 74 start-page: 105 year: 2001 ident: bib33 publication-title: Catal. Lett. contributor: fullname: Ryu – volume: 19 start-page: 225 year: 2002 ident: bib32 publication-title: Top. Catal. contributor: fullname: Solinas – volume: 75 start-page: 1955 year: 1993 ident: bib12 publication-title: Stud. Surf. Sci. Catal. contributor: fullname: Onishi – volume: 165 start-page: 12 year: 1997 ident: bib16 publication-title: J. Catal. contributor: fullname: Greene – volume: 189 start-page: 263 year: 1999 ident: bib24 publication-title: Appl. Catal. A contributor: fullname: Hannus – volume: 30 start-page: 273 year: 2000 ident: bib35 publication-title: Surf. Interface Anal. contributor: fullname: Blanchard – volume: 12 start-page: 297 year: 1992 ident: bib40 publication-title: Catal. Lett. contributor: fullname: Guo – volume: 37 start-page: 186 year: 1993 ident: bib3 publication-title: Platinum Met. Rev. contributor: fullname: Wyatt – volume: 193 start-page: 273 year: 2003 ident: bib36 publication-title: J. Mol. Catal. A contributor: fullname: Choung – volume: 229 start-page: 154 year: 2005 ident: bib8 publication-title: J. Catal. contributor: fullname: Nieuwenhuys – volume: 22 start-page: 167 year: 1999 ident: bib9 publication-title: Appl. Catal. B contributor: fullname: Blanchard – volume: 104 start-page: 11253 year: 2000 ident: bib39 publication-title: J. Phys. Chem. B contributor: fullname: Yao – volume: 28 start-page: 123 year: 1999 ident: bib30 publication-title: Surf. Interface Anal. contributor: fullname: Cai – volume: 26 start-page: 71 year: 1995 ident: bib27 publication-title: Catal. Today contributor: fullname: Cheng – volume: 107 start-page: 11475 year: 2003 ident: bib20 publication-title: J. Phys. Chem. B contributor: fullname: Volta – volume: 109 start-page: 113 year: 2004 ident: bib4 publication-title: J. Hazard. Mater. contributor: fullname: Baeyens – volume: 51 start-page: 9 year: 2004 ident: bib14 publication-title: Appl. Catal. B contributor: fullname: Moulijn – volume: 153 start-page: 304 year: 1995 ident: bib11 publication-title: J. Catal. contributor: fullname: Flytzani-Stephanopoulos – volume: 186 start-page: 279 year: 1999 ident: bib37 publication-title: J. Catal. contributor: fullname: Idriss – volume: 191 start-page: 30 year: 2000 ident: bib38 publication-title: J. Catal. contributor: fullname: Idriss – volume: 151 start-page: 204 year: 1995 ident: bib41 publication-title: J. Catal. contributor: fullname: Willey – volume: 12 start-page: 263 year: 1997 ident: bib29 publication-title: Appl. Catal. B contributor: fullname: Ohuchi – year: 2002 ident: bib7 article-title: Catalysis by Ceria and Related Materials contributor: fullname: Trovarelli – volume: 75 start-page: 3 year: 2002 ident: bib1 publication-title: Catal. Today contributor: fullname: Russo – volume: 240 start-page: 295 year: 2003 ident: bib10 publication-title: Appl. Catal. A contributor: fullname: Deganello – volume: 2 start-page: 51 year: 2003 end-page: 75 ident: bib25 publication-title: Recent Res. Dev. Catal. contributor: fullname: González-Velasco – volume: 93 start-page: 75 year: 1997 ident: bib23 publication-title: J. Chem. Soc., Faraday Trans. contributor: fullname: Lorenzelli – volume: 51 start-page: 203 year: 1999 ident: bib17 publication-title: Catal. Today contributor: fullname: Amiridis – volume: 77 start-page: 407 year: 2003 ident: 10.1016/j.molcata.2007.09.006_bib21 publication-title: Catal. Today doi: 10.1016/S0920-5861(02)00383-8 contributor: fullname: Boaro – volume: 93 start-page: 75 year: 1997 ident: 10.1016/j.molcata.2007.09.006_bib23 publication-title: J. Chem. Soc., Faraday Trans. doi: 10.1039/a605341f contributor: fullname: Finocchio – volume: 109 start-page: 113 year: 2004 ident: 10.1016/j.molcata.2007.09.006_bib4 publication-title: J. Hazard. Mater. doi: 10.1016/j.jhazmat.2004.03.019 contributor: fullname: Everaert – volume: 229 start-page: 154 year: 2005 ident: 10.1016/j.molcata.2007.09.006_bib8 publication-title: J. Catal. doi: 10.1016/j.jcat.2004.10.003 contributor: fullname: Gluhoi – volume: 107 start-page: 11475 year: 2003 ident: 10.1016/j.molcata.2007.09.006_bib20 publication-title: J. Phys. Chem. B doi: 10.1021/jp0358376 contributor: fullname: Reddy – volume: 191 start-page: 30 year: 2000 ident: 10.1016/j.molcata.2007.09.006_bib38 publication-title: J. Catal. doi: 10.1006/jcat.1999.2765 contributor: fullname: Yee – volume: 54 start-page: 13 year: 1999 ident: 10.1016/j.molcata.2007.09.006_bib28 publication-title: Catal. Today doi: 10.1016/S0920-5861(99)00163-7 contributor: fullname: Feaver – volume: 2 start-page: 51 year: 2003 ident: 10.1016/j.molcata.2007.09.006_bib25 publication-title: Recent Res. Dev. Catal. contributor: fullname: López-Fonseca – volume: 12 start-page: 297 year: 1992 ident: 10.1016/j.molcata.2007.09.006_bib40 publication-title: Catal. Lett. doi: 10.1007/BF00767212 contributor: fullname: Li – volume: 28 start-page: 123 year: 1999 ident: 10.1016/j.molcata.2007.09.006_bib30 publication-title: Surf. Interface Anal. doi: 10.1002/(SICI)1096-9918(199908)28:1<123::AID-SIA632>3.0.CO;2-6 contributor: fullname: Miao – volume: 19 start-page: 225 year: 2002 ident: 10.1016/j.molcata.2007.09.006_bib32 publication-title: Top. Catal. doi: 10.1023/A:1015376409863 contributor: fullname: Cutrufello – volume: 17 start-page: 105 year: 2004 ident: 10.1016/j.molcata.2007.09.006_bib2 publication-title: Catalysis doi: 10.1039/9781847553294-00105 contributor: fullname: Heneghan – volume: 51 start-page: 83 year: 2004 ident: 10.1016/j.molcata.2007.09.006_bib6 publication-title: Appl. Catal. B doi: 10.1016/j.apcatb.2004.01.024 contributor: fullname: Álvarez-Galván – year: 2002 ident: 10.1016/j.molcata.2007.09.006_bib7 contributor: fullname: Trovarelli – volume: 12 start-page: 263 year: 1997 ident: 10.1016/j.molcata.2007.09.006_bib29 publication-title: Appl. Catal. B doi: 10.1016/S0926-3373(96)00078-1 contributor: fullname: Tajima – volume: 104 start-page: 11253 year: 2000 ident: 10.1016/j.molcata.2007.09.006_bib39 publication-title: J. Phys. Chem. B doi: 10.1021/jp002509m contributor: fullname: Ouyang – volume: 240 start-page: 295 year: 2003 ident: 10.1016/j.molcata.2007.09.006_bib10 publication-title: Appl. Catal. A doi: 10.1016/S0926-860X(02)00460-X contributor: fullname: Liotta – volume: 180 start-page: 153 year: 1998 ident: 10.1016/j.molcata.2007.09.006_bib26 publication-title: J. Catal. doi: 10.1006/jcat.1998.2274 contributor: fullname: van den Brink – volume: 189 start-page: 263 year: 1999 ident: 10.1016/j.molcata.2007.09.006_bib24 publication-title: Appl. Catal. A doi: 10.1016/S0926-860X(99)00283-5 contributor: fullname: Hannus – volume: 186 start-page: 279 year: 1999 ident: 10.1016/j.molcata.2007.09.006_bib37 publication-title: J. Catal. doi: 10.1006/jcat.1999.2563 contributor: fullname: Yee – volume: 165 start-page: 12 year: 1997 ident: 10.1016/j.molcata.2007.09.006_bib16 publication-title: J. Catal. doi: 10.1006/jcat.1997.1443 contributor: fullname: Chintawar – volume: 40 start-page: 43 year: 2003 ident: 10.1016/j.molcata.2007.09.006_bib13 publication-title: Appl. Catal. B doi: 10.1016/S0926-3373(02)00127-3 contributor: fullname: Scire – volume: 54 start-page: 65 year: 1999 ident: 10.1016/j.molcata.2007.09.006_bib15 publication-title: Catal. Today doi: 10.1016/S0920-5861(99)00169-8 contributor: fullname: Feijen-Jeurissen – volume: 193 start-page: 273 year: 2003 ident: 10.1016/j.molcata.2007.09.006_bib36 publication-title: J. Mol. Catal. A doi: 10.1016/S1381-1169(02)00474-0 contributor: fullname: Kang – volume: 37 start-page: 186 year: 1993 ident: 10.1016/j.molcata.2007.09.006_bib3 publication-title: Platinum Met. Rev. contributor: fullname: Windawi – volume: 75 start-page: 1955 year: 1993 ident: 10.1016/j.molcata.2007.09.006_bib12 publication-title: Stud. Surf. Sci. Catal. doi: 10.1016/S0167-2991(08)64199-3 contributor: fullname: Li – volume: 22 start-page: 167 year: 1999 ident: 10.1016/j.molcata.2007.09.006_bib9 publication-title: Appl. Catal. B doi: 10.1016/S0926-3373(99)00054-5 contributor: fullname: González-Velasco – volume: 115 start-page: 6131 year: 1993 ident: 10.1016/j.molcata.2007.09.006_bib5 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00067a031 contributor: fullname: Petrosius – volume: 153 start-page: 304 year: 1995 ident: 10.1016/j.molcata.2007.09.006_bib11 publication-title: J. Catal. doi: 10.1006/jcat.1995.1132 contributor: fullname: Liu – volume: 269 start-page: 147 year: 2004 ident: 10.1016/j.molcata.2007.09.006_bib19 publication-title: Appl. Catal. A doi: 10.1016/j.apcata.2004.04.014 contributor: fullname: Gutiérrez-Ortiz – volume: 101 start-page: 1750 year: 1997 ident: 10.1016/j.molcata.2007.09.006_bib22 publication-title: J. Phys. Chem. B doi: 10.1021/jp962530g contributor: fullname: Balducci – volume: 51 start-page: 9 year: 2004 ident: 10.1016/j.molcata.2007.09.006_bib14 publication-title: Appl. Catal. B doi: 10.1016/j.apcatb.2004.01.005 contributor: fullname: Setiabudi – volume: 151 start-page: 204 year: 1995 ident: 10.1016/j.molcata.2007.09.006_bib41 publication-title: J. Catal. doi: 10.1006/jcat.1995.1022 contributor: fullname: Finocchio – volume: 62 start-page: 367 year: 2000 ident: 10.1016/j.molcata.2007.09.006_bib18 publication-title: Catal. Today doi: 10.1016/S0920-5861(00)00438-7 contributor: fullname: López-Fonseca – volume: 26 start-page: 71 year: 1995 ident: 10.1016/j.molcata.2007.09.006_bib27 publication-title: Catal. Today doi: 10.1016/0920-5861(95)00095-W contributor: fullname: Liu – volume: 74 start-page: 105 year: 2001 ident: 10.1016/j.molcata.2007.09.006_bib33 publication-title: Catal. Lett. doi: 10.1023/A:1016643232442 contributor: fullname: Sohn – volume: 113 start-page: 651 year: 2001 ident: 10.1016/j.molcata.2007.09.006_bib31 publication-title: Proc. Indian Acad. Chem. Sci. doi: 10.1007/BF02708797 contributor: fullname: Ranga Rao – volume: 131 start-page: 149 year: 1998 ident: 10.1016/j.molcata.2007.09.006_bib34 publication-title: J. Mol. Catal. A doi: 10.1016/S1381-1169(97)00262-8 contributor: fullname: Driessen – volume: 51 start-page: 203 year: 1999 ident: 10.1016/j.molcata.2007.09.006_bib17 publication-title: Catal. Today doi: 10.1016/S0920-5861(99)00045-0 contributor: fullname: Krishnamoorthy – volume: 30 start-page: 273 year: 2000 ident: 10.1016/j.molcata.2007.09.006_bib35 publication-title: Surf. Interface Anal. doi: 10.1002/1096-9918(200008)30:1<273::AID-SIA715>3.0.CO;2-G contributor: fullname: Daturi – volume: 75 start-page: 3 year: 2002 ident: 10.1016/j.molcata.2007.09.006_bib1 publication-title: Catal. Today doi: 10.1016/S0920-5861(02)00037-8 contributor: fullname: Centi – volume: 130 start-page: 411 year: 1991 ident: 10.1016/j.molcata.2007.09.006_bib42 publication-title: J. Catal. doi: 10.1016/0021-9517(91)90124-M contributor: fullname: Choudhary |
SSID | ssj0004341 |
Score | 2.2395265 |
Snippet | The oxidation mechanism of the oxidation of 1,2-dichloroethane on Ce/Zr mixed oxides was investigated by means of a combined flow and infrared spectroscopy... |
SourceID | crossref pascalfrancis elsevier |
SourceType | Aggregation Database Index Database Publisher |
StartPage | 181 |
SubjectTerms | 1,2-Dichloroethane Catalysis Catalytic combustion Ceria–zirconia mixed oxides Chemistry Exact sciences and technology General and physical chemistry IR-spectroscopy Oxidation mechanism Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
Title | On the mechanism of the catalytic destruction of 1,2-dichloroethane over Ce/Zr mixed oxide catalysts |
URI | https://dx.doi.org/10.1016/j.molcata.2007.09.006 |
Volume | 278 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3Nb9MwFH8a3QGmCcEArfuofOCImzi2k_hYVZs6EOMAkyYuUZxni0xrU9Eetsv-9j03Cd0OCImrLb9YPz-9r7wPgI_GequdUdxUKuVKIslB8kO4QOl0XGHpMVQjf71MZ1fq87W-3oFpXwsT0io72d_K9I207laiDs1oWdfRd0HKRoS_PFngpNATdJfUkVID2J1cfJldbssjpWr9rlzwcGBbyBPdjOfNbQiUdM0MQ_PK9G8qan9Zrgg43068eKKGzt_A685-ZJP2im9hxy0O4OW0H9t2AHtPOgy-A_y2YGTisbkLFb71as4av1nYhG3uiQhD96eHbNgUnxKOdfWL_PjGhbi6YyHLk01d9PM3m9d3DllzV2NPYrVevYer87Mf0xnvBivwSkqz5lqiybz0VWxdaSuZ52SX6KrEXLk0k8bHwmVkRyJq643OEzIjjEsl7SVYikx-gMGiWbhDYCJxqNGkpfFGydLa1BJNjCWRtyQ8hjDusSyWbf-Mok8suyk68MMszKyITUHgDyHvES-eMUJBMv5fR0fPXmj7QbparmN19P-0j-HVJqorEi7UCQzoYdwpmSNrO4IX4wcx6pjuETtJ4I8 |
link.rule.ids | 315,786,790,4521,24144,27955,27956,45618,45712 |
linkProvider | Elsevier |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT9wwELYQHJYKIUqpoKXgQ4_1Jo7tJD6iVdHSLvTQXQlxieKMLbJiN6vuHuDCb-84DxYOCImrnUys8Wjmm8k8CPmujTPKasl0IWMmBaAeRD-EcRBWhQXkDnw18uVVPJzIX9fqeoMMuloYn1bZ6v5Gp9faul0JWm4Gi7IM_nI0Ntz_5Um8JPmeoFseDfi8rv7jOs9DCtl4XSln_vF1GU8w7c-qOx8maVsZ-taV8WsGameRL5Ftrpl38cwIne-R3RY90rPmgB_Jhp3vk96gG9q2Tz486y_4icCfOUWAR2fW1_eWyxmtXL1QB20ekAgF-9RB1m_yHxGDsrhFL76yPqpuqc_xpAMb3Pyjs_LeAq3uS-hILFfLAzI5_zkeDFk7VoEVQugVUwJ04oQrQmNzU4g0RVSiihxSaeNEaBdymyCKBFDGaZVGCCK0jQXuRZDzRHwmm_Nqbg8J5ZEFBTrOtdNS5MbEBmlCKJC8QdVxRPodL7NF0z0j69LKplnLfD8JM8lCnSHzj0jacTx7IQYZavi3Xj15cUPrD-LRUhXKL--nfUp6w_HlKBtdXP3-Srbr-C6PGJfHZBMvyX5DYLIyJ7Xg_Qc5zuFk |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=On+the+mechanism+of+the+catalytic+destruction+of+1%2C2-dichloroethane+over+Ce%2FZr+mixed+oxide+catalysts&rft.jtitle=Journal+of+molecular+catalysis.+A%2C+Chemical&rft.au=DE+RIVAS%2C+Beatriz&rft.au=LOPEZ-FONSECA%2C+Rub%C3%A9n&rft.au=GONZALEZ-VELASCO%2C+Juan+R&rft.au=GUTIERREZ-ORTIZ%2C+Jos%C3%A9+I&rft.date=2007-12-14&rft.pub=Elsevier&rft.issn=1381-1169&rft.eissn=1873-314X&rft.volume=278&rft.issue=1-2&rft.spage=181&rft.epage=188&rft_id=info:doi/10.1016%2Fj.molcata.2007.09.006&rft.externalDBID=n%2Fa&rft.externalDocID=19438504 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1381-1169&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1381-1169&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1381-1169&client=summon |