Electrochemical Study and Mechanical Properties of Ti-Zr Alloy for Biomedical Applications
In response to concerns of potential cytotoxicity and adverse tissue reactions caused by vanadium and aluminum in the currently used biomaterial Ti-6Al-4V, the Ti–20Zr alloy was evaluated in this study because it has been suggested as a candidate for human body implant material. The Ti-20Zr alloy wa...
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Published in | Crystals (Basel) Vol. 14; no. 6; p. 493 |
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Abstract | In response to concerns of potential cytotoxicity and adverse tissue reactions caused by vanadium and aluminum in the currently used biomaterial Ti-6Al-4V, the Ti–20Zr alloy was evaluated in this study because it has been suggested as a candidate for human body implant material. The Ti-20Zr alloy was obtained by vacuum-melting, followed by heat treatment at 1000 °C for 1 h, and then air-cooled. Optical and scanning electron microscopy revealed that the sample had an α and β lamellar microstructure. Analysis showed that the mechanical properties, in terms of hardness measurements performed at low loads, were significantly different between the two phases. Thus, it was found out that the α phase is softer by about 30% compared to the β phase. The Electrochemical Impedance Spectroscopy technique (EIS) was employed to study the electrochemical behavior in simulated body fluid (SBF). The electrochemical behavior demonstrated that Ti-20Zr alloy exhibits excellent corrosion resistance due to the stable oxide layer formed on its surface. SEM and EDS investigations showed that the surface topography, after electrochemical studies, is characterized by a porous film with increased oxygen content, which might be suitable for the osteoinductive growth of bone. |
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AbstractList | In response to concerns of potential cytotoxicity and adverse tissue reactions caused by vanadium and aluminum in the currently used biomaterial Ti-6Al-4V, the Ti–20Zr alloy was evaluated in this study because it has been suggested as a candidate for human body implant material. The Ti-20Zr alloy was obtained by vacuum-melting, followed by heat treatment at 1000 °C for 1 h, and then air-cooled. Optical and scanning electron microscopy revealed that the sample had an α and β lamellar microstructure. Analysis showed that the mechanical properties, in terms of hardness measurements performed at low loads, were significantly different between the two phases. Thus, it was found out that the α phase is softer by about 30% compared to the β phase. The Electrochemical Impedance Spectroscopy technique (EIS) was employed to study the electrochemical behavior in simulated body fluid (SBF). The electrochemical behavior demonstrated that Ti-20Zr alloy exhibits excellent corrosion resistance due to the stable oxide layer formed on its surface. SEM and EDS investigations showed that the surface topography, after electrochemical studies, is characterized by a porous film with increased oxygen content, which might be suitable for the osteoinductive growth of bone. |
Audience | Academic |
Author | Uțu, Ion-Dragoș Verdu-Vazquez, Amparo Hulka, Iosif Mirza-Rosca, Julia C. Brito-Garcia, Santiago |
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Cites_doi | 10.1021/acsbiomaterials.7b00882 10.1002/1521-4176(200201)53:1<51::AID-MACO51>3.0.CO;2-6 10.1177/0885328218811052 10.1016/j.matlet.2022.132091 10.1007/s10856-021-06522-w 10.1177/0022034518792567 10.1016/j.precisioneng.2024.01.019 10.3390/met8080633 10.1007/978-3-642-56486-4 10.2478/v10178-011-0005-5 10.1007/s12540-013-6031-x 10.1016/0167-2738(86)90031-7 10.1016/j.jallcom.2020.155792 10.3390/ma5081348 10.1016/j.mseb.2013.07.006 10.37358/MP.19.2.5209 10.2320/matertrans.MRA2008403 10.1016/j.msec.2013.09.032 10.1016/j.jtemb.2024.127464 10.2497/jjspm.65.746 10.3390/met10020166 10.1017/S1431927622004433 10.1016/j.tox.2014.10.016 10.1016/j.jtemb.2016.12.001 10.1002/1521-4176(200006)51:6<413::AID-MACO413>3.0.CO;2-3 10.1093/rb/rbx027 10.1108/ACMM-10-2019-2201 10.1038/s41598-020-64734-6 10.1016/j.matchemphys.2022.126343 10.1016/j.ijom.2016.01.004 10.1016/j.matlet.2020.129041 10.1016/j.jmbbm.2020.104048 10.1179/1743284711Y.0000000052 |
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SubjectTerms | Alloys Biocompatibility Biological products biomaterial Biomedical materials Body fluids Cooling Corrosion and anti-corrosives Corrosion resistance Corrosion resistant alloys Dental implants Dentistry EIS Electrochemical analysis Electrochemical impedance spectroscopy Electrochemical reactions Electrodes Heat treatment Homogenization implant Mechanical properties microhardness microstructure Oxygen content Scanning electron microscopy Specialty metals industry Surgical implants Ti-Zr Titanium Titanium base alloys Zirconium Zirconium alloys |
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