Chemometric analysis of triglycerides hydrolysis in an enzyme membrane reactor
The work concerns hydrolysis of oil in a reactor with an ultrafiltration enzyme membrane. A phenomenological model of the reactor performance and its mathematical representation have earlier been elaborated according to a network thermodynamics approach by Schnakenberg. We try to explain when and wh...
Saved in:
Published in | Journal of molecular catalysis. B, Enzymatic Vol. 61; no. 3-4; pp. 180 - 183 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
01.12.2009
Elsevier |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | The work concerns hydrolysis of oil in a reactor with an ultrafiltration enzyme membrane. A phenomenological model of the reactor performance and its mathematical representation have earlier been elaborated according to a network thermodynamics approach by Schnakenberg.
We try to explain when and why the process in the membrane reactor exhibits a typical consecutive kinetics, i.e., mono- and diglycerides are produced together with fatty acids and glycerol or only the latter two products are formed.
The detailed discussion on the reactor performance at different levels of selected parameters is based on chemometric simulation procedure. The parameters were: the load density of lipase immobilised in the membrane, the rate constant of uncompetitive inhibition of the lipase catalyst, and the rate of convection streams of the circulating oil and aqueous phases.
Planning of the simulation experiments has been done by the full factorial design technique while the cluster analysis has been used to discuss the resulted features of the reactor performances. This was possible after selection of the linkage distances between the particular clusters of simulated experiments, represented by “cumulative” points defined as the functions of all the product time courses in the simulated processes versus the normalised time. |
---|---|
AbstractList | The work concerns hydrolysis of oil in a reactor with an ultrafiltration enzyme membrane. A phenomenological model of the reactor performance and its mathematical representation have earlier been elaborated according to a network thermodynamics approach by Schnakenberg.
We try to explain when and why the process in the membrane reactor exhibits a typical consecutive kinetics, i.e., mono- and diglycerides are produced together with fatty acids and glycerol or only the latter two products are formed.
The detailed discussion on the reactor performance at different levels of selected parameters is based on chemometric simulation procedure. The parameters were: the load density of lipase immobilised in the membrane, the rate constant of uncompetitive inhibition of the lipase catalyst, and the rate of convection streams of the circulating oil and aqueous phases.
Planning of the simulation experiments has been done by the full factorial design technique while the cluster analysis has been used to discuss the resulted features of the reactor performances. This was possible after selection of the linkage distances between the particular clusters of simulated experiments, represented by “cumulative” points defined as the functions of all the product time courses in the simulated processes versus the normalised time. |
Author | Adamczak, Piotr Oberta, Andrzej Ceynowa, Józef |
Author_xml | – sequence: 1 givenname: Piotr surname: Adamczak fullname: Adamczak, Piotr email: padam@chem.uni.torun.pl – sequence: 2 givenname: Andrzej surname: Oberta fullname: Oberta, Andrzej – sequence: 3 givenname: Józef surname: Ceynowa fullname: Ceynowa, Józef |
BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22149183$$DView record in Pascal Francis |
BookMark | eNqFkEtLxDAQx4Os4O7qRxB68diaafpITiKLL1j0oueQx9TN0jZLUoT66c2y4tXTDDP__zx-K7IY_YiEXAMtgEJzuy8G3xs16aKkVBS0KSjQM7IE3rKcQc0XKWcccoC2vSCrGPeU0hKAL8nrZoeDH3AKzmRqVP0cXcx8l6XCZz8bDM5izHazDf7Uc2PSZTh-zwNmAw46qBGzgMpMPlyS8071Ea9-45p8PD68b57z7dvTy-Z-mxvGxJRXpVWV1dxaVuuSadFpVrfclpxx5EoL1WirreEcDe9AUA0CsWJ1RWsUKNia1Ke5JvgYA3byENygwiyByiMUuZe_UOQRiqSNTFCS7-bkO6hoVN-l242Lf-ayhEoAZ0l3d9JheuLLYZDROBwNWhfQTNJ698-mHzX7fnc |
CitedBy_id | crossref_primary_10_1016_j_carbpol_2016_07_065 |
Cites_doi | 10.1002/abio.370170207 10.1016/S1383-5866(00)00173-8 10.1016/S0167-7799(00)01472-4 10.1002/jctb.280640406 10.1002/bit.260320414 10.1016/j.memsci.2007.09.064 |
ContentType | Journal Article |
Copyright | 2009 Elsevier B.V. 2015 INIST-CNRS |
Copyright_xml | – notice: 2009 Elsevier B.V. – notice: 2015 INIST-CNRS |
DBID | IQODW AAYXX CITATION |
DOI | 10.1016/j.molcatb.2009.06.010 |
DatabaseName | Pascal-Francis CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering Chemistry |
EISSN | 1873-3158 |
EndPage | 183 |
ExternalDocumentID | 10_1016_j_molcatb_2009_06_010 22149183 S1381117709001672 |
GroupedDBID | --- --K --M .~1 0R~ 1B1 1RT 1~. 1~5 29L 4.4 457 4G. 53G 5GY 5VS 7-5 71M 8P~ AABNK AACTN AAEDT AAEDW AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AAXUO ABFNM ABGSF ABMAC ABNUV ABUDA ABXDB ABYKQ ACDAQ ACGFS ACNCT ACRLP ADBBV ADEWK ADEZE ADMUD ADUVX AEBSH AEHWI AEKER AFKWA AFTJW AFXIZ AGHFR AGRDE AGUBO AGYEJ AHPOS AI. AIEXJ AIKHN AITUG AJBFU AJOXV AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BKOJK BLXMC CS3 DOVZS EBS EFJIC EFLBG EJD ENUVR EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FNPLU FYGXN G-Q GBLVA HVGLF HZ~ IHE J1W KOM M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SDF SDG SDP SES SEW SPC SSG SSU SSZ T5K TN5 VH1 ZMT ABPIF ABPTK IQODW AAXKI AAYXX AKRWK CITATION |
ID | FETCH-LOGICAL-c339t-42da4db8dd35b23b9fb3578d2838e8ab9a6bdbdc88ec8f190b19ee435405e9e93 |
IEDL.DBID | AIKHN |
ISSN | 1381-1177 |
IngestDate | Thu Sep 12 16:38:30 EDT 2024 Sun Oct 22 16:08:03 EDT 2023 Fri Feb 23 02:42:22 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 3-4 |
Keywords | Network thermodynamics Enzyme membrane reactor Chemometrics Glycerides hydrolysis Hydrolysis Membrane reactor Thermodynamics Bioreactor Enzyme Triglyceride Glyceride |
Language | English |
License | CC BY 4.0 |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c339t-42da4db8dd35b23b9fb3578d2838e8ab9a6bdbdc88ec8f190b19ee435405e9e93 |
PageCount | 4 |
ParticipantIDs | crossref_primary_10_1016_j_molcatb_2009_06_010 pascalfrancis_primary_22149183 elsevier_sciencedirect_doi_10_1016_j_molcatb_2009_06_010 |
PublicationCentury | 2000 |
PublicationDate | 2009-12-01 |
PublicationDateYYYYMMDD | 2009-12-01 |
PublicationDate_xml | – month: 12 year: 2009 text: 2009-12-01 day: 01 |
PublicationDecade | 2000 |
PublicationPlace | Amsterdam |
PublicationPlace_xml | – name: Amsterdam |
PublicationTitle | Journal of molecular catalysis. B, Enzymatic |
PublicationYear | 2009 |
Publisher | Elsevier B.V Elsevier |
Publisher_xml | – name: Elsevier B.V – name: Elsevier |
References | Pronk, Kerkhof, van Helden, van’t Reit (bib5) 1988; 32 Drioli, Giorno (bib1) 2000; 18 Hu, Wang, Luo, Dai (bib4) 2008; 308 Mazerski (bib10) 2003 A.W. Oberta, Modeling of reaction and diffusion systems. ‘Nobis’—integrated tool for planning and analysis of experiments, M.Sc. Thesis, Toruń, 2007. Ceynowa, Koter (bib2) 2003; 5 Giorno, Molinari, Drioli, Bianchi, Cesti (bib6) 1995; 64 Ceynowa, Adamczak (bib7) 2001; 22–23 Siwkowski, Ceynowa (bib11) 1995; 40 Ceynowa, Adamczak, Staniszewski (bib3) 1997; 17 Gemperline (bib8) 2006 Pronk (10.1016/j.molcatb.2009.06.010_bib5) 1988; 32 Drioli (10.1016/j.molcatb.2009.06.010_bib1) 2000; 18 Mazerski (10.1016/j.molcatb.2009.06.010_bib10) 2003 Hu (10.1016/j.molcatb.2009.06.010_bib4) 2008; 308 Ceynowa (10.1016/j.molcatb.2009.06.010_bib7) 2001; 22–23 Siwkowski (10.1016/j.molcatb.2009.06.010_bib11) 1995; 40 Ceynowa (10.1016/j.molcatb.2009.06.010_bib2) 2003; 5 Ceynowa (10.1016/j.molcatb.2009.06.010_bib3) 1997; 17 Giorno (10.1016/j.molcatb.2009.06.010_bib6) 1995; 64 Gemperline (10.1016/j.molcatb.2009.06.010_bib8) 2006 10.1016/j.molcatb.2009.06.010_bib9 |
References_xml | – year: 2003 ident: bib10 publication-title: Proceedings of Chemometria. Metody i Zastosowania contributor: fullname: Mazerski – volume: 5 start-page: 18 year: 2003 end-page: 26 ident: bib2 publication-title: Polish J. Chem. Technol. contributor: fullname: Koter – volume: 32 start-page: 512 year: 1988 end-page: 518 ident: bib5 publication-title: Biotechnol. Bioeng. contributor: fullname: van’t Reit – volume: 308 start-page: 242 year: 2008 end-page: 249 ident: bib4 publication-title: J. Membr. Sci. contributor: fullname: Dai – volume: 18 start-page: 339 year: 2000 ident: bib1 publication-title: Trends Biotechnol. contributor: fullname: Giorno – volume: 22–23 start-page: 443 year: 2001 end-page: 449 ident: bib7 publication-title: Sep. Purif. Technol. contributor: fullname: Adamczak – volume: 64 start-page: 345 year: 1995 end-page: 352 ident: bib6 publication-title: J. Chem. Technol. Biotechnol. contributor: fullname: Cesti – volume: 17 start-page: 161 year: 1997 end-page: 176 ident: bib3 publication-title: Biotechnol. Acta contributor: fullname: Staniszewski – year: 2006 ident: bib8 article-title: Practical Guide to Chemometrics contributor: fullname: Gemperline – volume: 40 start-page: 747 year: 1995 ident: bib11 publication-title: Chem. Anal. (Warsaw) contributor: fullname: Ceynowa – volume: 17 start-page: 161 year: 1997 ident: 10.1016/j.molcatb.2009.06.010_bib3 publication-title: Biotechnol. Acta doi: 10.1002/abio.370170207 contributor: fullname: Ceynowa – volume: 22–23 start-page: 443 year: 2001 ident: 10.1016/j.molcatb.2009.06.010_bib7 publication-title: Sep. Purif. Technol. doi: 10.1016/S1383-5866(00)00173-8 contributor: fullname: Ceynowa – volume: 18 start-page: 339 year: 2000 ident: 10.1016/j.molcatb.2009.06.010_bib1 publication-title: Trends Biotechnol. doi: 10.1016/S0167-7799(00)01472-4 contributor: fullname: Drioli – volume: 64 start-page: 345 year: 1995 ident: 10.1016/j.molcatb.2009.06.010_bib6 publication-title: J. Chem. Technol. Biotechnol. doi: 10.1002/jctb.280640406 contributor: fullname: Giorno – year: 2003 ident: 10.1016/j.molcatb.2009.06.010_bib10 contributor: fullname: Mazerski – volume: 5 start-page: 18 year: 2003 ident: 10.1016/j.molcatb.2009.06.010_bib2 publication-title: Polish J. Chem. Technol. contributor: fullname: Ceynowa – year: 2006 ident: 10.1016/j.molcatb.2009.06.010_bib8 contributor: fullname: Gemperline – volume: 40 start-page: 747 year: 1995 ident: 10.1016/j.molcatb.2009.06.010_bib11 publication-title: Chem. Anal. (Warsaw) contributor: fullname: Siwkowski – volume: 32 start-page: 512 year: 1988 ident: 10.1016/j.molcatb.2009.06.010_bib5 publication-title: Biotechnol. Bioeng. doi: 10.1002/bit.260320414 contributor: fullname: Pronk – ident: 10.1016/j.molcatb.2009.06.010_bib9 – volume: 308 start-page: 242 year: 2008 ident: 10.1016/j.molcatb.2009.06.010_bib4 publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2007.09.064 contributor: fullname: Hu |
SSID | ssj0002118 |
Score | 1.9408273 |
Snippet | The work concerns hydrolysis of oil in a reactor with an ultrafiltration enzyme membrane. A phenomenological model of the reactor performance and its... |
SourceID | crossref pascalfrancis elsevier |
SourceType | Aggregation Database Index Database Publisher |
StartPage | 180 |
SubjectTerms | Bioconversions. Hemisynthesis Biological and medical sciences Biotechnology Chemometrics Enzyme membrane reactor Fundamental and applied biological sciences. Psychology Glycerides hydrolysis Methods. Procedures. Technologies Network thermodynamics |
Title | Chemometric analysis of triglycerides hydrolysis in an enzyme membrane reactor |
URI | https://dx.doi.org/10.1016/j.molcatb.2009.06.010 |
Volume | 61 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT-MwEB5BOQBCK56CZbfygWvaPNxgH1EF6i6iF0DiFvkxhiKSVFAO5cBv33Hj8JBWQuLqRxKNo2--Gc8D4EhwNKi0jZwvckca2kWKtGx0LMyxjDOBWnmH_sU4H13zvzeDmyUYtrkwPqwyYH-D6Qu0DiP9IM3-dDLpXyakbPyVYywXsfSEwyukjjjvwMrJn_PR-A2QycZZZMTR-shveE_k6d_3yvrBqJkOlSvzXuxzaf-vojam6okE55qOFx_U0Nkm_Aj8kZ00n7gFS1htw-qwbdu2DesfKgzuwNjP1KVvm2WYCgVIWO0YDdw-zA0ts_jE7ub2sW7mJhWtY1i9zEtkJZZkTVfIiFp67_4uXJ-dXg1HUWihEJksk7OIp1Zxq4W12UCnmZZO-_I2lkiFQKG0VLm22hoh0AhH5EAnEpF7Z9AAJcpsDzpVXeE-sDQ1Suc-5BRjnrhccseNSQgTiIUp7g6g10qtmDaVMoo2hOy-CGL2XS9l4UPpkvgARCvb4tORF4TmX23tfjqLtxemKVl8hFI_v__sQ1hLQ4-IOPkFndnjM_4m4jHTXVjuvSbd8Hv9AxY82ag |
link.rule.ids | 315,786,790,4521,24144,27955,27956,45618,45712 |
linkProvider | Elsevier |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3JTsMwELUqOABCiFXs-MA1bRY32EdUgcrSXgCJW-RlDK2apCrlUA58O-PGYZGQkLjak0Xj6M2z82aGkFPOQINUJrCuyB1GaBtIjLLBGddnIkw4KOkO9Hv9tPvArh_bjw3SqXNhnKzSY3-F6XO09iMt783WeDBo3UUYbNwvx1DMtfSIw4uODThdV_P9S-eBO5x5PhxaB878K42nNWzm5UjLqfJ1K9Nm6DJpfw9Qq2P5gm6zVb-Lb0Hocp2sefZIz6sX3CANKDbJUqdu2rZJVr7VF9wifTdT5q5plqbSlx-hpaU48DSaaTQz8EKfZ2ZSVnODAu0oFG-zHGgOOe6lC6BILN3Z_jZ5uLy473QD30Ah0EkipgGLjWRGcWOStooTJaxyxW0MUgoOXCohU2WU0ZyD5hapgYoEAHNHQW0QIJIdslCUBewSGsdaqtQJTiFkkU0Fs0zrCBEBOZhkdo80a69l46pORlYLyIaZd7PreSkyJ6SLwj3Ca99mPxY8Qyz_69LjH2vx-cA4xv0eYtT-_-99Qpa6973b7Paqf3NAlmPfLSKMDsnCdPIKR0hBpup4_ol9AAUf2n0 |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Chemometric+analysis+of+triglycerides+hydrolysis+in+an+enzyme+membrane+reactor&rft.jtitle=Journal+of+molecular+catalysis.+B%2C+Enzymatic&rft.au=Adamczak%2C+Piotr&rft.au=Oberta%2C+Andrzej&rft.au=Ceynowa%2C+J%C3%B3zef&rft.date=2009-12-01&rft.issn=1381-1177&rft.volume=61&rft.issue=3-4&rft.spage=180&rft.epage=183&rft_id=info:doi/10.1016%2Fj.molcatb.2009.06.010&rft.externalDBID=n%2Fa&rft.externalDocID=10_1016_j_molcatb_2009_06_010 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1381-1177&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1381-1177&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1381-1177&client=summon |