Synthesis and characterization of cationic quaternary ammonium geminis (16-s-16) and their role in ninhydrin-[Cu(II)-His]+ reaction

Cationic quaternary ammonium gemini surfactants were synthesized by mixing N,N-dimethylcetylamine and α,ω-dibromoalkane. The synthesized products were characterized by C, H, N elemental and 1 H NMR analyses. The critical micelle concentration (CMC) of these surfactants with and without additives was...

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Published inChemical engineering communications Vol. 208; no. 11; pp. 1607 - 1617
Main Authors Kumar, Dileep, Rub, Malik Abdul
Format Journal Article
LanguageEnglish
Published Philadelphia Taylor & Francis 02.11.2021
Taylor & Francis Ltd
Subjects
Additives
catalysis
Cations
Cu(II)-His
interfacial properties
kinetics
Micelles
Ninhydrin
NMR
Nuclear magnetic resonance
quaternary ammonium geminis
surfactant micelles
Surfactants
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Abstract Cationic quaternary ammonium gemini surfactants were synthesized by mixing N,N-dimethylcetylamine and α,ω-dibromoalkane. The synthesized products were characterized by C, H, N elemental and 1 H NMR analyses. The critical micelle concentration (CMC) of these surfactants with and without additives was calculated by means of the conductivity technique. The role of the synthesized quaternary ammonium geminis in the reaction was investigated by a UV-vis spectroscopy. The rate constant (k ψ ) was determined at different gemini concentrations and plotted graphically as k ψ vs. [16-s-16]. Additionally, the influence of other reaction parameters (viz., reactants, pH, and temperature) was investigated. The binding constants were also determined (K A for [Cu(II)-His] + and K B for ninhydrin). The resulting k ψ -[16-s-16] plot can be understood in terms of a pseudo-phase model of micelles.
AbstractList Cationic quaternary ammonium gemini surfactants were synthesized by mixing N,N-dimethylcetylamine and α,ω-dibromoalkane. The synthesized products were characterized by C, H, N elemental and 1 H NMR analyses. The critical micelle concentration (CMC) of these surfactants with and without additives was calculated by means of the conductivity technique. The role of the synthesized quaternary ammonium geminis in the reaction was investigated by a UV-vis spectroscopy. The rate constant (k ψ ) was determined at different gemini concentrations and plotted graphically as k ψ vs. [16-s-16]. Additionally, the influence of other reaction parameters (viz., reactants, pH, and temperature) was investigated. The binding constants were also determined (K A for [Cu(II)-His] + and K B for ninhydrin). The resulting k ψ -[16-s-16] plot can be understood in terms of a pseudo-phase model of micelles.
Cationic quaternary ammonium gemini surfactants were synthesized by mixing N,N-dimethylcetylamine and α,ω-dibromoalkane. The synthesized products were characterized by C, H, N elemental and 1H NMR analyses. The critical micelle concentration (CMC) of these surfactants with and without additives was calculated by means of the conductivity technique. The role of the synthesized quaternary ammonium geminis in the reaction was investigated by a UV–vis spectroscopy. The rate constant (kψ) was determined at different gemini concentrations and plotted graphically as kψ vs. [16–s–16]. Additionally, the influence of other reaction parameters (viz., reactants, pH, and temperature) was investigated. The binding constants were also determined (KA for [Cu(II)–His]+ and KB for ninhydrin). The resulting kψ–[16–s–16] plot can be understood in terms of a pseudo-phase model of micelles.
Author Rub, Malik Abdul
Kumar, Dileep
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Cites_doi 10.1007/s13202-014-0139-5
10.1007/BF00139332
10.1021/la020250o
10.1002/(SICI)1097-4601(1999)31:10<729::AID-JCK6>3.0.CO;2-G
10.1002/poc.3730
10.1002/poc.3967
10.1016/j.molliq.2019.111322
10.1080/00986445.2018.1533465
10.1080/03602457908065104
10.1016/j.molliq.2017.05.027
10.1002/1521-3773(20000602)39:11<1906::AID-ANIE1906>3.0.CO;2-Q
10.1016/j.molliq.2018.08.147
10.1080/00986445.2019.1581616
10.1021/j100131a055
10.1080/00986445.2012.686938
10.1016/j.molliq.2018.04.053
10.1080/00986445.2012.752733
10.1016/j.molliq.2018.08.002
10.1002/poc.1171
10.1021/acs.jced.9b00146
10.1080/00986445.2013.867260
10.1016/j.molliq.2018.11.035
10.1021/la00023a014
10.1002/poc.3997
10.1039/f29817700601
10.1201/9781420015843
10.1002/jps.21506
10.1039/C9RA03557E
10.3139/113.110635
10.1021/jp9535598
10.1080/01932690903110269
10.1021/ja00994a023
10.1006/jcis.2001.8104
10.5650/jos.ess19213
10.1016/0040-4020(73)80046-8
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Snippet Cationic quaternary ammonium gemini surfactants were synthesized by mixing N,N-dimethylcetylamine and α,ω-dibromoalkane. The synthesized products were...
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SubjectTerms Additives
catalysis
Cations
Cu(II)-His
interfacial properties
kinetics
Micelles
Ninhydrin
NMR
Nuclear magnetic resonance
quaternary ammonium geminis
surfactant micelles
Surfactants
Title Synthesis and characterization of cationic quaternary ammonium geminis (16-s-16) and their role in ninhydrin-[Cu(II)-His]+ reaction
URI https://www.tandfonline.com/doi/abs/10.1080/00986445.2020.1805437
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