Crystal structures and luminescent properties of a cadmium(II) metal-organic framework based on tri(4-pyridylphenyl)amine

• Published in: Journal of coordination chemistry Vol. 71; no. 24; pp. 4023 - 4030
• Main Authors: Li, Jun-Feng, Xu, Xiu-Dian, Zhou, Ze-Yu, Chen, Li-Zhuang, Wang, Fang-Ming
• Format: Journal Article
• Language: English
• Published: Abingdon Taylor & Francis 17.12.2018; Taylor & Francis Ltd
• Subjects: (Tri(4-pyridylphenyl)amine) ligand; Cadmium; Crystal structure; Crystals; Luminescent; Metal-organic frameworks; Optical properties; Porosity; Single crystals; WLED; X ray analysis

A luminescent cadmium(II) metal-organic framework, [Cd(tppa) 2 (bpdc) 2 ] n (1) (tppa = tri(4-pyridylphenyl)amine, bpdc =4,4′-biphenyldicarboxylic acid), has been solvothermally synthesized by using Cd(NO 3 ) 2 ·4H 2 O and a mixture of tppa and bpdc. Single crystal X-ray analysis reveals that 1 crys...