Hybrid photoanode films based on sparse ZnO rod array-TiO2 nanoparticles in dye-sensitized solar cells

ZnO-TiO2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO2 nanoparticles. A special surface-coating technique was developed to deposit a thin TiO2 layer on the surface of ZnO rods. Microstructure, optical and photo...

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Published inScience China. Physics, mechanics & astronomy Vol. 55; no. 7; pp. 1183 - 1188
Main Authors Wang, CaiLu, Gao, XiangDong, Li, XiaoMin, Jiang, ZhengWu, Yang, ZhengHong, Gu, ZhengYing, He, Peng
Format Journal Article
LanguageEnglish
Published Heidelberg SP Science China Press 01.07.2012
Springer Nature B.V
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Abstract ZnO-TiO2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO2 nanoparticles. A special surface-coating technique was developed to deposit a thin TiO2 layer on the surface of ZnO rods. Microstructure, optical and photoelectrochemical performance of the hybrid photoanodes were investi- gated. The denser ZnO array exhibited bad filling behavior of nanoparticles in the interspace of ZnO rods, strong scattering and low conversion efficiency (0.27%). The sparser array showed a much better integrated microstructure, improved transmittance and high conversion efficiency (2.68%). The surface modification of ZnO rods by the TiO2 thin layer was found useful in im- proving the interfacial microstructure between the ZnO rod and the TiO2 bulk film, and the total conversion efficiency of 3.01% was achieved, higher than that of the pure TiO2 nanoparticle cell (2.93%). The increased scattering effects on the inci- dent light, the enhanced electron transportation at TiO2/dye/electrolyte interface, and the inhabited recombination were respon- sible for this improvement.
AbstractList ZnO-TiO 2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO 2 nanoparticles. A special surface-coating technique was developed to deposit a thin TiO 2 layer on the surface of ZnO rods. Microstructure, optical and photoelectrochemical performance of the hybrid photoanodes were investigated. The denser ZnO array exhibited bad filling behavior of nanoparticles in the interspace of ZnO rods, strong scattering and low conversion efficiency (0.27%). The sparser array showed a much better integrated microstructure, improved transmittance and high conversion efficiency (2.68%). The surface modification of ZnO rods by the TiO 2 thin layer was found useful in improving the interfacial microstructure between the ZnO rod and the TiO 2 bulk film, and the total conversion efficiency of 3.01% was achieved, higher than that of the pure TiO 2 nanoparticle cell (2.93%). The increased scattering effects on the incident light, the enhanced electron transportation at TiO 2 /dye/electrolyte interface, and the inhabited recombination were responsible for this improvement.
ZnO-TiO2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO2 nanoparticles. A special surface-coating technique was developed to deposit a thin TiO2 layer on the surface of ZnO rods. Microstructure, optical and photoelectrochemical performance of the hybrid photoanodes were investigated. The denser ZnO array exhibited bad filling behavior of nanoparticles in the interspace of ZnO rods, strong scattering and low conversion efficiency (0.27%). The sparser array showed a much better integrated microstructure, improved transmittance and high conversion efficiency (2.68%). The surface modification of ZnO rods by the TiO2 thin layer was found useful in improving the interfacial microstructure between the ZnO rod and the TiO2 bulk film, and the total conversion efficiency of 3.01% was achieved, higher than that of the pure TiO2 nanoparticle cell (2.93%). The increased scattering effects on the incident light, the enhanced electron transportation at TiO2/dye/electrolyte interface, and the inhabited recombination were responsible for this improvement.
ZnO-TiO2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO2 nanoparticles. A special surface-coating technique was developed to deposit a thin TiO2 layer on the surface of ZnO rods. Microstructure, optical and photoelectrochemical performance of the hybrid photoanodes were investi- gated. The denser ZnO array exhibited bad filling behavior of nanoparticles in the interspace of ZnO rods, strong scattering and low conversion efficiency (0.27%). The sparser array showed a much better integrated microstructure, improved transmittance and high conversion efficiency (2.68%). The surface modification of ZnO rods by the TiO2 thin layer was found useful in im- proving the interfacial microstructure between the ZnO rod and the TiO2 bulk film, and the total conversion efficiency of 3.01% was achieved, higher than that of the pure TiO2 nanoparticle cell (2.93%). The increased scattering effects on the inci- dent light, the enhanced electron transportation at TiO2/dye/electrolyte interface, and the inhabited recombination were respon- sible for this improvement.
Author WANG CaiLu GAO XiangDong LI XiaoMin JIANG ZhengWu YANG ZhengHong GU ZhengYing HE Peng
AuthorAffiliation State Key Lab of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China; Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 200092, China
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CitedBy_id crossref_primary_10_1080_15533174_2014_988806
crossref_primary_10_1080_15533174_2013_862680
crossref_primary_10_1007_s12598_014_0327_y
crossref_primary_10_1007_s12598_014_0329_9
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dye-sensitized solar cells
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ZnO-TiO2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO2 nanoparticles. A special surface-coating technique was developed to deposit a thin TiO2 layer on the surface of ZnO rods. Microstructure, optical and photoelectrochemical performance of the hybrid photoanodes were investi- gated. The denser ZnO array exhibited bad filling behavior of nanoparticles in the interspace of ZnO rods, strong scattering and low conversion efficiency (0.27%). The sparser array showed a much better integrated microstructure, improved transmittance and high conversion efficiency (2.68%). The surface modification of ZnO rods by the TiO2 thin layer was found useful in im- proving the interfacial microstructure between the ZnO rod and the TiO2 bulk film, and the total conversion efficiency of 3.01% was achieved, higher than that of the pure TiO2 nanoparticle cell (2.93%). The increased scattering effects on the inci- dent light, the enhanced electron transportation at TiO2/dye/electrolyte interface, and the inhabited recombination were respon- sible for this improvement.
hybrid photoanode, ZnO, TiO2, dye-sensitized solar cells
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PublicationTitle Science China. Physics, mechanics & astronomy
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Snippet ZnO-TiO2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO2 nanoparticles....
ZnO-TiO 2 hybrid photoanodes were fabricated via the doctor-blade method by integrating vertically-grown sparse ZnO arrays with hydrothermal TiO 2...
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StartPage 1183
SubjectTerms Arrays
Astronomy
Classical and Continuum Physics
Dye-sensitized solar cells
Dyes
Efficiency
Electrolytic cells
Incident light
Microstructure
Nanoparticles
Observations and Techniques
Photoanodes
Physics
Physics and Astronomy
Rods
Scattering
Solar cells
TiO2纳米粒子
Titanium dioxide
Zinc oxide
染料敏化太阳能电池
氧化锌
混合光
稀疏阵列
纳米TiO2
纳米二氧化钛
阳极膜
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Title Hybrid photoanode films based on sparse ZnO rod array-TiO2 nanoparticles in dye-sensitized solar cells
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