Degradation of diazinon from aqueous solutions by electro-Fenton process: effect of operating parameters, intermediate identification, degradation pathway, and optimization using response surface methodology (RSM)

In this experimental study, the statistical response surface methodology (RSM) based Box-Behnken design (BBD) was selected for evaluation of the effect of different parameters (solution pH,H 2 O 2 concentration, current density, and time) and their interactions on the degradation of the diazinon by...

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Published inSeparation science and technology Vol. 56; no. 13; pp. 2287 - 2299
Main Authors heidari, Maryam, Vosoughi, Mehdi, Sadeghi, Hadi, Dargahi, Abdollah, Mokhtari, S. Ahmad
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis 02.09.2021
Taylor & Francis Ltd
Subjects
Adequacy
advanced oxidation
Aqueous solutions
Correlation coefficient
Correlation coefficients
Current density
Degradation
Diazinon
Electro-Fenton process
Fungicides
Hydrogen peroxide
Insecticides
Mathematical models
Optimization
Parameter identification
Parameters
Pesticides
Process parameters
Regression analysis
Response surface methodology
Statistical analysis
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Abstract In this experimental study, the statistical response surface methodology (RSM) based Box-Behnken design (BBD) was selected for evaluation of the effect of different parameters (solution pH,H 2 O 2 concentration, current density, and time) and their interactions on the degradation of the diazinon by electro Fenton process. The results showed that the quadratic model is suitable for the obtained data (P-value = 0.0001) and in optimal process performance conditions was set equal to 100%. Regression analysis with a high correlation coefficient (R 2  = 0.9980) and the model value of 765.56 indicated the adequacy of the model. Based on the results, the electro-Fenton process is an efficient technique for removing diazinon from aqueous media.
AbstractList In this experimental study, the statistical response surface methodology (RSM) based Box-Behnken design (BBD) was selected for evaluation of the effect of different parameters (solution pH,H 2 O 2 concentration, current density, and time) and their interactions on the degradation of the diazinon by electro Fenton process. The results showed that the quadratic model is suitable for the obtained data (P-value = 0.0001) and in optimal process performance conditions was set equal to 100%. Regression analysis with a high correlation coefficient (R 2  = 0.9980) and the model value of 765.56 indicated the adequacy of the model. Based on the results, the electro-Fenton process is an efficient technique for removing diazinon from aqueous media.
In this experimental study, the statistical response surface methodology (RSM) based Box-Behnken design (BBD) was selected for evaluation of the effect of different parameters (solution pH,H2O2 concentration, current density, and time) and their interactions on the degradation of the diazinon by electro Fenton process. The results showed that the quadratic model is suitable for the obtained data (P-value = 0.0001) and in optimal process performance conditions was set equal to 100%. Regression analysis with a high correlation coefficient (R2 = 0.9980) and the model value of 765.56 indicated the adequacy of the model. Based on the results, the electro-Fenton process is an efficient technique for removing diazinon from aqueous media.
Author heidari, Maryam
Dargahi, Abdollah
Mokhtari, S. Ahmad
Vosoughi, Mehdi
Sadeghi, Hadi
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  email: s.a.mokhtari@gmail.com
  organization: School of Public Health, Ardabil University of Medical Sciences
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Snippet In this experimental study, the statistical response surface methodology (RSM) based Box-Behnken design (BBD) was selected for evaluation of the effect of...
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SubjectTerms Adequacy
advanced oxidation
Aqueous solutions
Correlation coefficient
Correlation coefficients
Current density
Degradation
Diazinon
Electro-Fenton process
Fungicides
Hydrogen peroxide
Insecticides
Mathematical models
Optimization
Parameter identification
Parameters
Pesticides
Process parameters
Regression analysis
Response surface methodology
Statistical analysis
Title Degradation of diazinon from aqueous solutions by electro-Fenton process: effect of operating parameters, intermediate identification, degradation pathway, and optimization using response surface methodology (RSM)
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