Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution
In this study, functionalized MIL-101(Cr) with amine group (ED-MIL-101(Cr)) was Synthesized. Using grafted MOF, adsorption experiments of Cu(II) and Cd(II) ions in single and binary solutions were performed. The adsorption results were fitted well by the Langmuir and extended Freundlich models for s...
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Published in | Separation science and technology Vol. 55; no. 18; pp. 3362 - 3374 |
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Main Authors | , |
Format | Journal Article |
Language | English |
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Taylor & Francis
11.12.2020
Taylor & Francis Ltd |
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Abstract | In this study, functionalized MIL-101(Cr) with amine group (ED-MIL-101(Cr)) was Synthesized. Using grafted MOF, adsorption experiments of Cu(II) and Cd(II) ions in single and binary solutions were performed. The adsorption results were fitted well by the Langmuir and extended Freundlich models for single ion and binary ion solutions, respectively. Data revealed that ED-MIL-101(Cr) possess maximum adsorption capacities (mg/g) of 69.9 and 63.15 for Cu(II) and Cd(II), respectively,with affinity order Cu(II) ˃ Cd(II) in binary ion solution. The kinetic data was well described by the pseudo-second-order model. The amino-functionalized MIL-101(Cr) can be a promising candidate for metal ion removal from the aqueous environment. |
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AbstractList | In this study, functionalized MIL-101(Cr) with amine group (ED-MIL-101(Cr)) was Synthesized. Using grafted MOF, adsorption experiments of Cu(II) and Cd(II) ions in single and binary solutions were performed. The adsorption results were fitted well by the Langmuir and extended Freundlich models for single ion and binary ion solutions, respectively. Data revealed that ED-MIL-101(Cr) possess maximum adsorption capacities (mg/g) of 69.9 and 63.15 for Cu(II) and Cd(II), respectively,with affinity order Cu(II) ˃ Cd(II) in binary ion solution. The kinetic data was well described by the pseudo-second-order model. The amino-functionalized MIL-101(Cr) can be a promising candidate for metal ion removal from the aqueous environment. |
Author | Elaiwi, Fadhil Abid Sirkecioglu, Ahmet |
Author_xml | – sequence: 1 givenname: Fadhil Abid surname: Elaiwi fullname: Elaiwi, Fadhil Abid email: elaiwi16@itu.edu.tr organization: Istanbul Technical University – sequence: 2 givenname: Ahmet surname: Sirkecioglu fullname: Sirkecioglu, Ahmet organization: Istanbul Technical University |
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SubjectTerms | Adsorption Amine functionalized MIL-101(Cr) Amines Aqueous environments Cadmium Chromium Copper Heavy metals Metal ions Metal-organic frameworks |
Title | Amine-functionalized metal organic frameworks MIL-101(Cr) adsorbent for copper and cadmium ions in single and binary solution |
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