Sulfuric Acid-Doping on Thermally Aged Polyaniline

The effects of aging temperature on the doping reaction of thermally aged polyaniline have been studied. The behavior of the reaction was analyzed with respect to the concentration of sulfuric acid solution, the temperature of the solution and the dipping time. Samples prepared by casting were heate...

Full description

Saved in:
Bibliographic Details
Published inKOBUNSHI RONBUNSHU Vol. 53; no. 8; pp. 509 - 511
Main Authors TSUBAKIHARA, Hiroshi, FUJIMORI, Takashi, NIHONMATSU, Kaoru
Format Journal Article
LanguageJapanese
Published Tokyo The Society of Polymer Science, Japan 01.01.1996
Tsukiji daisan nagaoka
Subjects
H2SO4 Doping
Polyaniline
Thermal Aging
Online AccessGet full text

Cover

Abstract The effects of aging temperature on the doping reaction of thermally aged polyaniline have been studied. The behavior of the reaction was analyzed with respect to the concentration of sulfuric acid solution, the temperature of the solution and the dipping time. Samples prepared by casting were heated at 90-170°C and then dipped into aqueous solutions of H2SO4. The degree of protonation was characterized by the peak height of 1150 cm-1 absorption band formed in doping reactions. The results obtained indicate that the protonation has two steps. At first, some kinds of hindrances protecting imines should be removed at a certain proton concentration and/or dipping times. In the second step, protonated imines are formed in a thermally activated reaction.
AbstractList The effects of aging temperature on the doping reaction of thermally aged polyaniline have been studied. The behavior of the reaction was analyzed with respect to the concentration of sulfuric acid solution, the temperature of the solution and the dipping time. Samples prepared by casting were heated at 90-170°C and then dipped into aqueous solutions of H2SO4. The degree of protonation was characterized by the peak height of 1150 cm-1 absorption band formed in doping reactions. The results obtained indicate that the protonation has two steps. At first, some kinds of hindrances protecting imines should be removed at a certain proton concentration and/or dipping times. In the second step, protonated imines are formed in a thermally activated reaction.
Author NIHONMATSU, Kaoru
TSUBAKIHARA, Hiroshi
FUJIMORI, Takashi
Author_xml – sequence: 1
  fullname: TSUBAKIHARA, Hiroshi
  organization: Department of Electronic Engineering and Computer Science, Faculty of Engineering, Kinki University
– sequence: 2
  fullname: FUJIMORI, Takashi
  organization: Department of Electronic Engineering and Computer Science, Faculty of Engineering, Kinki University
– sequence: 3
  fullname: NIHONMATSU, Kaoru
  organization: Department of Electronic Engineering and Computer Science, Faculty of Engineering, Kinki University
BackLink http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3227771$$DView record in Pascal Francis
BookMark eNo9j01PAjEQhhuDiYjc_AF78Ohip91u2yNB_EhINBHPm263hWrpkhYO_HsXl-xlZpL3mSd5b9EotMEgdA94BkSyp982tmHG6IxheYXGIATkrBRshMaYijInIMobNE3J1RgziUHicozI19HbY3Q6m2vX5M_t3oVN1oZsvTVxp7w_ZfONabLP1p9UcN4Fc4eurfLJTC97gr5fluvFW776eH1fzFe5plQcck5qLpsaoDSSlYVSBBgrwBrTKIqtwlZLEN1ZCEYVhgIaxgWxnGEMNZV0gh57r45tStHYah_dTsVTBbg6V67-K1eMVl3lDn_o8b1KWnkbVdAuDT-UEM45dNiyx37SQW3MkKt4cNqb3gmSF2evuAwsh1xvVaxMoH9yo3AU
CODEN KBRBA3
ContentType Journal Article
Copyright The Society of Polymer Science, Japan
1996 INIST-CNRS
Copyright_xml – notice: The Society of Polymer Science, Japan
– notice: 1996 INIST-CNRS
DBID IQODW
AAYXX
CITATION
DOI 10.1295/koron.53.509
DatabaseName Pascal-Francis
CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
EISSN 1881-5685
EndPage 511
ExternalDocumentID 10_1295_koron_53_509
3227771
article_koron1974_53_8_53_8_509_article_char_en
GroupedDBID 5GY
ACGFS
ACIWK
AENEX
ALMA_UNASSIGNED_HOLDINGS
CS3
DU5
JSF
KQ8
RJT
IQODW
AAYXX
CITATION
ID FETCH-LOGICAL-c338t-72b79db116e9564aa215541feeda30fa0fc918a304853a0141d5782f75001b393
ISSN 0386-2186
IngestDate Fri Aug 23 02:37:05 EDT 2024
Sun Oct 29 17:06:21 EDT 2023
Thu Aug 17 20:29:20 EDT 2023
IsDoiOpenAccess true
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 8
Language Japanese
License CC BY 4.0
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c338t-72b79db116e9564aa215541feeda30fa0fc918a304853a0141d5782f75001b393
OpenAccessLink https://www.jstage.jst.go.jp/article/koron1974/53/8/53_8_509/_article/-char/en
PageCount 3
ParticipantIDs crossref_primary_10_1295_koron_53_509
pascalfrancis_primary_3227771
jstage_primary_article_koron1974_53_8_53_8_509_article_char_en
PublicationCentury 1900
PublicationDate 1996-01-01
PublicationDateYYYYMMDD 1996-01-01
PublicationDate_xml – month: 01
  year: 1996
  text: 1996-01-01
  day: 01
PublicationDecade 1990
PublicationPlace Tokyo
PublicationPlace_xml – name: Tokyo
PublicationTitle KOBUNSHI RONBUNSHU
PublicationTitleAlternate KOBUNSHI RONBUNSHU
PublicationYear 1996
Publisher The Society of Polymer Science, Japan
Tsukiji daisan nagaoka
Publisher_xml – name: The Society of Polymer Science, Japan
– name: Tsukiji daisan nagaoka
References 3) 椿原啓, 岡村洋, 吉村斎, 林光澤, 岡田和之, 坂本昭彦, 高分子論文集, 51, 759 (1994).
6) 椿原啓, 橋本秀之, 岡村洋, 林光澤, 電子情報通信学会論文誌.
5) H. Kuzmany, N.S. Saricifti, H. Neugebauer, and A. Neckel, Phys. Rev. Lett., 60, 212 (1988).
2) 椿原啓, 岡村洋, 岡田和之, 坂本昭彦, 高分子論文集, 51, 565 (1994).
4) J. Tang, X. Jing, B. Wang, and F. Wang, Synth. Met., 24, 231 (1988).
1) 椿原啓, 樋口一, 岡田和之, 坂本昭彦, 高分子論文集, 51, 145 (1994).
References_xml
SSID ssib005901906
ssib000972329
ssj0059176
ssib014653950
ssib053392992
Score 1.4641145
Snippet The effects of aging temperature on the doping reaction of thermally aged polyaniline have been studied. The behavior of the reaction was analyzed with respect...
SourceID crossref
pascalfrancis
jstage
SourceType Aggregation Database
Index Database
Publisher
StartPage 509
SubjectTerms H2SO4 Doping
Polyaniline
Thermal Aging
Title Sulfuric Acid-Doping on Thermally Aged Polyaniline
URI https://www.jstage.jst.go.jp/article/koron1974/53/8/53_8_509/_article/-char/en
Volume 53
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
ispartofPNX KOBUNSHI RONBUNSHU, 1996/08/25, Vol.53(8), pp.509-511
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lj9MwELbQwgGEEE9RYFEO9FSlxHGcOBekUEDtVu3CbivtLbLzgG6jZFWaQ_n1zMRp6oU9LFwsy7GTyDMef7ZnPhPyLmdchVQldsI9BQsUoWwJwNgO8tDPpPIT2Xi7z-b-eOmdXPCLg7ttE12yVcPk141xJf8jVSgDuWKU7D9ItnspFEAe5AspSBjSW8n4vC5yZAUaRMkqtT_p2CcQJ8ge7G1R7AbRdwCUX6tiJ8tVsT9Cb7HotOqPRn3hqRpdtgabqmxytS5F6Lmo1rvK2CtYnC8_RtPJODqLmilrBVPsj1WnAsuTyez0bNKogFxL49F8Mj6dzyJorz04qk192G7QHsrddkMbZiV8Gy-y0hOItppCUJv7-u6dvVnVHMCt-gjDRnInNKZbrm3tX5bcDZH0Yo00DkPOhl0jkzD7j4mscy_EhQ20j5vWMWcxxxDPuy7YIjSC028GAsVb1wyEiKG4BgE-Rfq58HDwC-AY8GTYMZRxWO3q4_C2V9rYCvj6e_Pfr6Gee5cA_JHR4eGV_AkjMddXqBi4ZvGYPGoXJFaktesJuXMpn5IHBk3lM-Lu9cwy9MyqSqvTMwv1zDL07DlZfvm8GI3t9q4NO2FMbO3AVUGYKkr9DFbMnpQuAk2aA4SSzMmlkychFZD1AN9J9A5O8SKEHACnQxUL2QtyVFZl9pJYEhCySkRKUyfzRIoUkEiySJlSUlEme6S_74v4SlOqxDdJrEc-6I7qarUDTdeisBLGmqJNnLB7jgGLYB965PhaB3fvgUksCAL66pY_8prcP4yEN-Rou6mzY4CiW_W2UabffOGAJA
link.rule.ids 315,783,787,27936,27937
linkProvider Colorado Alliance of Research Libraries
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Sulfuric+Acid-Doping+on+Thermally+Aged+Polyaniline&rft.jtitle=Ko%CC%84bunshi+ronbunshu%CC%84+%28Tokyo%29&rft.au=TSUBAKIHARA%2C+Hiroshi&rft.au=FUJIMORI%2C+Takashi&rft.au=NIHONMATSU%2C+Kaoru&rft.date=1996-01-01&rft.issn=0386-2186&rft.eissn=1881-5685&rft.volume=53&rft.issue=8&rft.spage=509&rft.epage=511&rft_id=info:doi/10.1295%2Fkoron.53.509&rft.externalDBID=n%2Fa&rft.externalDocID=10_1295_koron_53_509
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0386-2186&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0386-2186&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0386-2186&client=summon