Specifics of localization of carbon black at the interface between polymeric phases
The thermodynamic and kinetic factors that determine the localization of carbon black particles at interfaces in polymer blends were established. Substantial differences in particle localization conditions at the interfaces of two high-molecular-mass or low-molecular-mass liquids were revealed; thes...
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| Published in | Polymer Science. Series A Vol. 49; no. 3; pp. 328 - 336 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Oxford
Springer Nature B.V
01.03.2007
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| Abstract | The thermodynamic and kinetic factors that determine the localization of carbon black particles at interfaces in polymer blends were established. Substantial differences in particle localization conditions at the interfaces of two high-molecular-mass or low-molecular-mass liquids were revealed; these differences are manifested in the determining effect of the sequence of mixing of the filler with the polymeric components of the blend on the localization. The effect is explained in terms of nonequilibrium positions of carbon black particles at the interface. This nonequilibrium distribution is primarily due to a high energy of desorption of macromolecules from the solid surface.[PUBLICATION ABSTRACT] |
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| AbstractList | The thermodynamic and kinetic factors that determine the localization of carbon black particles at interfaces in polymer blends were established. Substantial differences in particle localization conditions at the interfaces of two high-molecular-mass or low-molecular-mass liquids were revealed; these differences are manifested in the determining effect of the sequence of mixing of the filler with the polymeric components of the blend on the localization. The effect is explained in terms of nonequilibrium positions of carbon black particles at the interface. This nonequilibrium distribution is primarily due to a high energy of desorption of macromolecules from the solid surface.[PUBLICATION ABSTRACT] |
| Author | Zharinova, E. A. Bikmullin, R. S. Zaikin, A. E. |
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| Cites_doi | 10.5254/1.3544796 10.5254/1.3547460 10.5254/1.3538419 10.1021/ma00085a049 10.1007/BF00312918 10.5254/1.3547173 10.1007/BF00652179 10.1021/ma00109a030 10.5254/1.3547326 10.5254/1.3535837 10.1007/BF00310802 |
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| References_xml | – volume: 44 start-page: 814 year: 1971 ident: 3014_CR27 publication-title: Rubber Chem. Technol. doi: 10.5254/1.3544796 contributor: fullname: J. E. Callan – volume: 29 start-page: 84 issue: 5 year: 1986 ident: 3014_CR11 publication-title: Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. contributor: fullname: V. G. Pavlii – volume: 48 start-page: 410 year: 1975 ident: 3014_CR19 publication-title: Rubber Chem. Technol. doi: 10.5254/1.3547460 contributor: fullname: E. M. Dannenberg – volume: 70 start-page: 60 year: 1997 ident: 3014_CR8 publication-title: Rubber Chem. Technol. doi: 10.5254/1.3538419 contributor: fullname: B. G. Soares – volume: 33 start-page: 1864 year: 1991 ident: 3014_CR24 publication-title: Vysokomol. Soedin., Ser. A contributor: fullname: A. E. Zaikin – volume: 29 start-page: 447 year: 1987 ident: 3014_CR13 publication-title: Vysokomol. Soedin., Ser. A contributor: fullname: V. G. Pavlii – volume: 39 start-page: 104 issue: 505 year: 1967 ident: 3014_CR20 publication-title: J. Paint Technol. contributor: fullname: C. M. Hansen – volume: 27 start-page: 1972 year: 1994 ident: 3014_CR5 publication-title: Macromolecules doi: 10.1021/ma00085a049 contributor: fullname: F. Gubbels – volume-title: Adhesion and Adhesives Science and Technology year: 1990 ident: 3014_CR23 contributor: fullname: A. J. Kinloch – ident: 3014_CR4 – volume: 35 start-page: 223 year: 1995 ident: 3014_CR7 publication-title: Polym. Bull. (Berlin) doi: 10.1007/BF00312918 contributor: fullname: B. G. Soares – volume: 64 start-page: 2107 year: 1991 ident: 3014_CR22 publication-title: Zh. Prikl. Khim. (Leningrad) contributor: fullname: S. N. Stepin – volume-title: Adsorption from Solution at the Solid/Liquid Interface year: 1983 ident: 3014_CR25 contributor: fullname: G. Flir – volume: 41 start-page: 344 year: 1968 ident: 3014_CR1 publication-title: Pubber Chem. Technol. doi: 10.5254/1.3547173 contributor: fullname: P. A. Marsh – volume: 270 start-page: 134 year: 1992 ident: 3014_CR10 publication-title: Colloid Polym. Sci. doi: 10.1007/BF00652179 contributor: fullname: M. Sumita – volume: 28 start-page: 1559 year: 1995 ident: 3014_CR6 publication-title: Macromolecules doi: 10.1021/ma00109a030 contributor: fullname: F. Gubbels – volume: 43 start-page: 973 year: 1970 ident: 3014_CR26 publication-title: Rubber Chem. Technol. doi: 10.5254/1.3547326 contributor: fullname: A. K. Sircar – volume: 4 start-page: 55 issue: 3 year: 1998 ident: 3014_CR14 publication-title: Mekh. Kompoz. Mater. Konstr. contributor: fullname: A. E. Zaikin – volume: 39 start-page: 505 issue: 511 year: 1967 ident: 3014_CR21 publication-title: J. Paint. Technol. contributor: fullname: C. M. Hansen – volume-title: The Physical Chemistry of Surfaces year: 1970 ident: 3014_CR16 contributor: fullname: A. W. Adamson – volume-title: Polymer Blends year: 1978 ident: 3014_CR17 contributor: fullname: S. Wu – volume: 25 start-page: 1483 year: 1983 ident: 3014_CR3 publication-title: Vysokomol. Soedin., Ser. A contributor: fullname: Yu. S. Lipatov – volume: 54 start-page: 820 year: 1981 ident: 3014_CR2 publication-title: Rubber Chem. Technol. doi: 10.5254/1.3535837 contributor: fullname: A. K. Sircar – volume: 25 start-page: 265 year: 1991 ident: 3014_CR9 publication-title: Polym. Bull. (Berlin) doi: 10.1007/BF00310802 contributor: fullname: M. Sumita – volume: 40 start-page: 499 year: 1998 ident: 3014_CR15 publication-title: Polymer Science, Ser. A contributor: fullname: A. E. Zaikin – volume: 41 start-page: 15 year: 1999 ident: 3014_CR12 publication-title: Polymer Science, Ser. B contributor: fullname: A. E. Zaikin – volume-title: Reinforcement of Elastomers year: 1965 ident: 3014_CR18 contributor: fullname: G. Kraus |
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| Title | Specifics of localization of carbon black at the interface between polymeric phases |
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