A critical review on nickel sulfide-based electrode materials for supercapacitors
Supercapacitors (SCs) are currently numbered among the most outstanding energy storage and supply devices due to their high power density, durable cycle life, and wide operating temperature range. However, the wide application of SCs is still subject to the low energy density, which drives researche...
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| Published in | Critical reviews in solid state and materials sciences Vol. 48; no. 4; pp. 502 - 518 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Boca Raton
Taylor & Francis
04.07.2023
Taylor & Francis Ltd |
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| Online Access | Get full text |
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| Abstract | Supercapacitors (SCs) are currently numbered among the most outstanding energy storage and supply devices due to their high power density, durable cycle life, and wide operating temperature range. However, the wide application of SCs is still subject to the low energy density, which drives researchers to extensively look for high-performance electrode materials. In recent years, nickel sulfide-based materials have been widely studied as promising electrode materials for SCs due to their superior theoretical specific capacity, high redox activity, and rapid electric conduction, but the inferior active material utilization efficiency and poor reaction kinetics limit their practical demand in SCs. In this review, we briefly introduced the energy storage mechanism of nickel sulfide electrode materials used in supercapacitors and then launched an overview of improving performance. A particular emphasis is on the modification strategies to accelerate the electron conduction and mass transfer process through carbon recombination, metal heteroatom doping, interfacial electric field construction, exposure of edge active sites and large specific surface area, and building of ion diffusion channels. Finally, we discuss the research orientation of nickel sulfide-based electrode materials. |
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| AbstractList | Supercapacitors (SCs) are currently numbered among the most outstanding energy storage and supply devices due to their high power density, durable cycle life, and wide operating temperature range. However, the wide application of SCs is still subject to the low energy density, which drives researchers to extensively look for high-performance electrode materials. In recent years, nickel sulfide-based materials have been widely studied as promising electrode materials for SCs due to their superior theoretical specific capacity, high redox activity, and rapid electric conduction, but the inferior active material utilization efficiency and poor reaction kinetics limit their practical demand in SCs. In this review, we briefly introduced the energy storage mechanism of nickel sulfide electrode materials used in supercapacitors and then launched an overview of improving performance. A particular emphasis is on the modification strategies to accelerate the electron conduction and mass transfer process through carbon recombination, metal heteroatom doping, interfacial electric field construction, exposure of edge active sites and large specific surface area, and building of ion diffusion channels. Finally, we discuss the research orientation of nickel sulfide-based electrode materials. |
| Author | He, Guang-Yuan Meng, Chao He, Xiong-Fei Wang, Yu-Ting Chen, Xue-Min Li, Fa-Tang Zhou, Yue |
| Author_xml | – sequence: 1 givenname: Yu-Ting surname: Wang fullname: Wang, Yu-Ting organization: Hebei Provincial Key Laboratory of Photoelectric Control on Surface and Interface, College of Science, Hebei University of Science and Technology – sequence: 2 givenname: Xiong-Fei surname: He fullname: He, Xiong-Fei organization: Hebei Provincial Key Laboratory of Photoelectric Control on Surface and Interface, College of Science, Hebei University of Science and Technology – sequence: 3 givenname: Guang-Yuan surname: He fullname: He, Guang-Yuan organization: Hebei Provincial Key Laboratory of Photoelectric Control on Surface and Interface, College of Science, Hebei University of Science and Technology – sequence: 4 givenname: Chao surname: Meng fullname: Meng, Chao organization: Key Laboratory for Robot and Intelligent Technology of Shandong Province, Shandong University of Science and Technology – sequence: 5 givenname: Xue-Min surname: Chen fullname: Chen, Xue-Min organization: Hebei Provincial Key Laboratory of Photoelectric Control on Surface and Interface, College of Science, Hebei University of Science and Technology – sequence: 6 givenname: Fa-Tang surname: Li fullname: Li, Fa-Tang organization: Hebei Provincial Key Laboratory of Photoelectric Control on Surface and Interface, College of Science, Hebei University of Science and Technology – sequence: 7 givenname: Yue surname: Zhou fullname: Zhou, Yue organization: Key Laboratory for Robot and Intelligent Technology of Shandong Province, Shandong University of Science and Technology |
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| SubjectTerms | Electric fields electrochemical performance Electrode materials Electrodes electron transport Energy storage Ion diffusion Mass transfer Nickel Nickel sulfide Operating temperature Reaction kinetics Specific capacity Sulfides supercapacitor Supercapacitors |
| Title | A critical review on nickel sulfide-based electrode materials for supercapacitors |
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