Investigations on supported bimetallic PdPt nanostructures
PdPt bimetallic clusters have been produced by a laser vaporisation source and studied after deposition on a support. We have been able to obtain clusters with a well-defined composition, identical to that of the target rod as deduced from energy dispersive X-ray analysis measurements. An evaporati...
Saved in:
Published in | Surface science Vol. 352; pp. 583 - 587 |
---|---|
Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
15.05.1996
Elsevier |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | PdPt bimetallic clusters have been produced by a laser vaporisation source and studied after deposition on a support. We have been able to obtain clusters with a well-defined composition, identical to that of the target rod as deduced from energy dispersive X-ray analysis measurements. An evaporation of Pd atoms upon the impact of the electron beam has been observed, suggesting that the surfaces of the clusters are Pd-enriched. The segregation behaviour using Monte Carlo simulations has been studied for the Pd
15Pt
85 and Pd
50Pt
50 cubo-octahedral clusters composed of 586 and 2406 atoms. The results indicate a large Pd segregation in all the systems, in qualitative agreement with the experimental observations, with preferential occupation of corner and edge sites. |
---|---|
AbstractList | PdPt bimetallic clusters have been produced by a laser vaporisation source and studied after deposition on a support. We have been able to obtain clusters with a well-defined composition, identical to that of the target rod as deduced from energy dispersive X-ray analysis measurements. An evaporation of Pd atoms upon the impact of the electron beam has been observed, suggesting that the surfaces of the clusters are Pd-enriched. The segregation behaviour using Monte Carlo simulations has been studied for the Pd
15Pt
85 and Pd
50Pt
50 cubo-octahedral clusters composed of 586 and 2406 atoms. The results indicate a large Pd segregation in all the systems, in qualitative agreement with the experimental observations, with preferential occupation of corner and edge sites. |
Author | Pellarin, M. Cadrot, A.M. Aires, F.J.Cadete Santos Khanra, B.C. Rousset, J.L. Renouprez, A.J. |
Author_xml | – sequence: 1 givenname: J.L. surname: Rousset fullname: Rousset, J.L. organization: Institut de Recherches sur la Catalyse/CNRS, 2 Av. Albert Einstein, 69626 Villeurbanne Cedex, France – sequence: 2 givenname: B.C. surname: Khanra fullname: Khanra, B.C. organization: Institut de Recherches sur la Catalyse/CNRS, 2 Av. Albert Einstein, 69626 Villeurbanne Cedex, France – sequence: 3 givenname: A.M. surname: Cadrot fullname: Cadrot, A.M. organization: Institut de Recherches sur la Catalyse/CNRS, 2 Av. Albert Einstein, 69626 Villeurbanne Cedex, France – sequence: 4 givenname: F.J.Cadete Santos surname: Aires fullname: Aires, F.J.Cadete Santos organization: Institut de Recherches sur la Catalyse/CNRS, 2 Av. Albert Einstein, 69626 Villeurbanne Cedex, France – sequence: 5 givenname: A.J. surname: Renouprez fullname: Renouprez, A.J. organization: Institut de Recherches sur la Catalyse/CNRS, 2 Av. Albert Einstein, 69626 Villeurbanne Cedex, France – sequence: 6 givenname: M. surname: Pellarin fullname: Pellarin, M. organization: Laboratoire de Spectrométrie Ionique et Moléculaire, Université Claude Bernard LyonI, 43 Bd du 11 Nov. 1918, 69622 Villeurbanne Cedex, France |
BackLink | https://hal.science/hal-00006521$$DView record in HAL |
BookMark | eNp9kEFLAzEUhINUsK3-Aw97tIfVZDfJJh6EUqotFOxBzyGbfauRbVKStOC_d9dKj77LwGNmYL4JGjnvAKFbgu8JJvwB41LmHBfiTrIZJgUucnGBxkRUMi8qJkZofLZcoUmMX7g_KtkYPa7dEWKyHzpZ72LmXRYP-70PCZqstjtIuuusybbNNmVOOx9TOJh0CBCv0WWruwg3fzpF78_Lt8Uq37y-rBfzTW7KUqScGM2N5LolmgnRUKo5ZbgklBMheMlwpY2hmNa4grrFrBK6kk0NNcgCN4Upp2h26v3UndoHu9PhW3lt1Wq-UcNvGMNZQY6k99KT1wQfY4D2HCBYDazUAEINIJRk6peVEn3s6RSDfsfRQlDRWHAGGhvAJNV4-3_BD8WWcWc |
CitedBy_id | crossref_primary_10_1142_S0217979200001588 crossref_primary_10_1103_PhysRevB_67_155409 crossref_primary_10_1142_S0217979203022817 crossref_primary_10_1016_j_susc_2014_06_026 crossref_primary_10_1103_PhysRevB_58_2150 crossref_primary_10_1016_j_apcatb_2003_07_001 crossref_primary_10_1103_PhysRevB_63_165406 crossref_primary_10_1103_RevModPhys_71_1695 crossref_primary_10_1016_j_chemphys_2006_09_015 crossref_primary_10_1016_S0009_2614_02_00056_8 crossref_primary_10_1006_jcat_1997_1729 crossref_primary_10_1016_S0169_4332_01_00457_3 crossref_primary_10_3390_catal10111291 crossref_primary_10_1016_j_apcatb_2014_12_001 crossref_primary_10_1016_S0921_4526_01_00340_4 crossref_primary_10_1021_nl302405k crossref_primary_10_1103_PhysRevB_76_045429 crossref_primary_10_1142_S0217979299000059 crossref_primary_10_1627_jpi_46_315 crossref_primary_10_1039_c2ce25235j crossref_primary_10_1039_B702732J crossref_primary_10_1016_j_nimb_2004_10_022 crossref_primary_10_1016_S0009_2614_99_00346_2 crossref_primary_10_1016_S0921_4526_00_00450_6 crossref_primary_10_1016_j_jelechem_2008_05_003 crossref_primary_10_1016_j_jcat_2011_03_011 crossref_primary_10_1021_jp973395q |
Cites_doi | 10.1063/1.468847 10.1016/0378-5963(83)90083-1 10.1007/BF02642747 10.1016/0021-9517(77)90026-4 10.1246/cl.1989.1769 10.1103/PhysRevB.32.5051 10.1016/0039-6028(78)90274-1 10.1080/01418618908205062 |
ContentType | Journal Article |
Copyright | 1996 Distributed under a Creative Commons Attribution 4.0 International License |
Copyright_xml | – notice: 1996 – notice: Distributed under a Creative Commons Attribution 4.0 International License |
DBID | AAYXX CITATION 1XC |
DOI | 10.1016/0039-6028(95)01202-8 |
DatabaseName | CrossRef Hyper Article en Ligne (HAL) |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry Physics |
EISSN | 1879-2758 |
EndPage | 587 |
ExternalDocumentID | oai_HAL_hal_00006521v1 10_1016_0039_6028_95_01202_8 0039602895012028 |
GroupedDBID | --K --M -~X .~1 0R~ 123 1B1 1RT 1~. 1~5 29Q 4.4 457 4G. 5VS 7-5 71M 8P~ 8WZ 9JN A6W AABNK AABXZ AACTN AAEDT AAEDW AAEPC AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO AAYJJ ABFNM ABMAC ABNEU ABXDB ABXRA ABYKQ ACDAQ ACFVG ACGFS ACIWK ACNNM ACRLP ADBBV ADECG ADEZE ADIYS ADMUD AEBSH AEKER AENEX AEZYN AFFNX AFKWA AFRZQ AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AIEXJ AIKHN AITUG AIVDX AJBFU AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BBWZM BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HMV HVGLF HZ~ H~9 IHE J1W KOM M38 M41 MAGPM MO0 N9A NDZJH O-L O9- OAUVE OGIMB OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SCB SDF SDG SDP SES SEW SPC SPCBC SPD SPG SSK SSM SSQ SSZ T5K TN5 TWZ VOH WUQ XPP ZMT ~02 ~G- AAXKI AAYXX AKRWK CITATION 1XC |
ID | FETCH-LOGICAL-c338t-1ca6c96af1a588d44a6450314618863507acc404b07ebf0578a79dbebe920d2c3 |
IEDL.DBID | AIKHN |
ISSN | 0039-6028 |
IngestDate | Fri Sep 06 12:45:43 EDT 2024 Thu Sep 12 16:37:26 EDT 2024 Fri Feb 23 02:32:41 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Keywords | Clusters Surface segragation Laser methods Semi-empirical models and model calculations |
Language | English |
License | Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0 |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c338t-1ca6c96af1a588d44a6450314618863507acc404b07ebf0578a79dbebe920d2c3 |
ORCID | 0000-0003-4617-0227 |
PageCount | 5 |
ParticipantIDs | hal_primary_oai_HAL_hal_00006521v1 crossref_primary_10_1016_0039_6028_95_01202_8 elsevier_sciencedirect_doi_10_1016_0039_6028_95_01202_8 |
PublicationCentury | 1900 |
PublicationDate | 1996-05-15 |
PublicationDateYYYYMMDD | 1996-05-15 |
PublicationDate_xml | – month: 05 year: 1996 text: 1996-05-15 day: 15 |
PublicationDecade | 1990 |
PublicationTitle | Surface science |
PublicationYear | 1996 |
Publisher | Elsevier B.V Elsevier |
Publisher_xml | – name: Elsevier B.V – name: Elsevier |
References | Miura, Feng, Saymeth, Gonzalez (BIB3) 1985 Rousset, Cadrot, Aires, Renouprez, Melinon, Perez, Pellarin, Vialle, Broyer (BIB5) 1995; 102 Massardier, Bertolini, Renouprez (BIB1) 1988 Toshima, Kushihashi, Yonezawa, Hirai (BIB2) 1989 Rosato, Guillope, Legrand (BIB8) 1989; 59 Darby, Myles, Myles (BIB11) 1972; 3 Yang, Woo (BIB4) 1993 Tsai, Pound, Abraham (BIB9) 1977; 50 Tomanek, Aligia, Balseiro (BIB7) 1985; 32 Donnely, King (BIB6) 1978; 74 Van Langeveld, Ponec (BIB10) 1983; 16 Massardier (10.1016/0039-6028(95)01202-8_BIB1) 1988 Rousset (10.1016/0039-6028(95)01202-8_BIB5) 1995; 102 Tsai (10.1016/0039-6028(95)01202-8_BIB9) 1977; 50 Donnely (10.1016/0039-6028(95)01202-8_BIB6) 1978; 74 Darby (10.1016/0039-6028(95)01202-8_BIB11) 1972; 3 Van Langeveld (10.1016/0039-6028(95)01202-8_BIB10) 1983; 16 Rosato (10.1016/0039-6028(95)01202-8_BIB8) 1989; 59 Miura (10.1016/0039-6028(95)01202-8_BIB3) 1985 Tomanek (10.1016/0039-6028(95)01202-8_BIB7) 1985; 32 Toshima (10.1016/0039-6028(95)01202-8_BIB2) 1989 Yang (10.1016/0039-6028(95)01202-8_BIB4) 1993 |
References_xml | – volume: 59 start-page: 321 year: 1989 ident: BIB8 publication-title: Phillos. Mag. A contributor: fullname: Legrand – volume: 32 start-page: 5051 year: 1985 ident: BIB7 publication-title: Phys. Rev. B contributor: fullname: Balseiro – volume: 102 start-page: 8574 year: 1995 ident: BIB5 publication-title: J. Chem. Phys. contributor: fullname: Broyer – volume: 74 start-page: 89 year: 1978 ident: BIB6 publication-title: Surf. Sci. contributor: fullname: King – start-page: 294 year: 1985 ident: BIB3 publication-title: Catalysts Characterization Science contributor: fullname: Gonzalez – volume: 16 start-page: 405 year: 1983 ident: BIB10 publication-title: Appl. Surf. Sci. contributor: fullname: Ponec – start-page: 1769 year: 1989 ident: BIB2 publication-title: Chem. Lett. contributor: fullname: Hirai – volume: 50 start-page: 200 year: 1977 ident: BIB9 publication-title: J. Catal. contributor: fullname: Abraham – volume: 3 start-page: 653 year: 1972 ident: BIB11 publication-title: Met. Trans. contributor: fullname: Myles – start-page: 1222 year: 1988 ident: BIB1 publication-title: Proc. of the 9th Int. Congr. on Catalysis contributor: fullname: Renouprez – start-page: B671 year: 1993 ident: BIB4 publication-title: Proc. of the 10th Int. Congr. on Catalysis contributor: fullname: Woo – start-page: 1222 year: 1988 ident: 10.1016/0039-6028(95)01202-8_BIB1 contributor: fullname: Massardier – volume: 102 start-page: 8574 year: 1995 ident: 10.1016/0039-6028(95)01202-8_BIB5 publication-title: J. Chem. Phys. doi: 10.1063/1.468847 contributor: fullname: Rousset – volume: 16 start-page: 405 year: 1983 ident: 10.1016/0039-6028(95)01202-8_BIB10 publication-title: Appl. Surf. Sci. doi: 10.1016/0378-5963(83)90083-1 contributor: fullname: Van Langeveld – volume: 3 start-page: 653 year: 1972 ident: 10.1016/0039-6028(95)01202-8_BIB11 publication-title: Met. Trans. doi: 10.1007/BF02642747 contributor: fullname: Darby – start-page: 294 year: 1985 ident: 10.1016/0039-6028(95)01202-8_BIB3 contributor: fullname: Miura – volume: 50 start-page: 200 year: 1977 ident: 10.1016/0039-6028(95)01202-8_BIB9 publication-title: J. Catal. doi: 10.1016/0021-9517(77)90026-4 contributor: fullname: Tsai – start-page: B671 year: 1993 ident: 10.1016/0039-6028(95)01202-8_BIB4 contributor: fullname: Yang – start-page: 1769 year: 1989 ident: 10.1016/0039-6028(95)01202-8_BIB2 publication-title: Chem. Lett. doi: 10.1246/cl.1989.1769 contributor: fullname: Toshima – volume: 32 start-page: 5051 year: 1985 ident: 10.1016/0039-6028(95)01202-8_BIB7 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.32.5051 contributor: fullname: Tomanek – volume: 74 start-page: 89 year: 1978 ident: 10.1016/0039-6028(95)01202-8_BIB6 publication-title: Surf. Sci. doi: 10.1016/0039-6028(78)90274-1 contributor: fullname: Donnely – volume: 59 start-page: 321 year: 1989 ident: 10.1016/0039-6028(95)01202-8_BIB8 publication-title: Phillos. Mag. A doi: 10.1080/01418618908205062 contributor: fullname: Rosato |
SSID | ssj0000495 |
Score | 1.6572766 |
Snippet | PdPt bimetallic clusters have been produced by a laser vaporisation source and studied after deposition on a support. We have been able to obtain clusters... |
SourceID | hal crossref elsevier |
SourceType | Open Access Repository Aggregation Database Publisher |
StartPage | 583 |
SubjectTerms | Catalysis Chemical Sciences Clusters Laser methods Semi-empirical models and model calculations Surface segragation |
Title | Investigations on supported bimetallic PdPt nanostructures |
URI | https://dx.doi.org/10.1016/0039-6028(95)01202-8 https://hal.science/hal-00006521 |
Volume | 352 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LSwMxEB5si-hFtCrWF4t40EPsPpLdxFsplvVVerDQW8juZnFBt4W2Hv3tTvZR60EEr4FMli_hm2-WeQBcosezU8pTIhTzCMUIgig31YSh3kdC1Og1TL3z89APx_RhwiZrtTAmrbLi_pLTC7auVroVmt1ZlpkpZKi-MV5gpv7T5Q1ooTeitAmt3v1jOPzmYyrKOQaeIGZDXUDn-N3V2pVg14UZwn9zUI3X-ldr4XoGu7BTaUarV37WHmzovA1b_XpUWxs2izzOeL4Pt2t9M_A9WdPcmi9nRfPyxIqyd41a-y2LrVEyWli5yqdl_9glBt0HMB7cvfRDUo1HIDHGlQvixMqPha9SRzHOE0qVT5npRu87nKOOsAMVx9SmkR3oKEVdxlUgkghvTbh24sbeITTzaa6PwPK0L7Ry3QjVEkUUuZ2iUtTcV2jWDZwOkBoTOSu7YMg6PcxgKA2GUjBZYCh5B4IaOPnjNiUS9R87LxDn1SGm-XXYe5JmrXCtqDY-nON_mz-B7TLtmhGHnUITMdZnqCoW0Tk0bj6d8-rxfAHsP8Nt |
link.rule.ids | 230,315,786,790,891,4521,24144,27957,27958,45620,45714 |
linkProvider | Elsevier |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LS8NAEB5si-hFtCrWZxAPeliapLvJrrdSLKl90EMLvS2bZIMFTQtt_f3O5lHrQQSvCzsbvl2--SbMA-ABPZ6dUJ4QoViLUIwgiHITTRjqfSREjV7D1DsPR14wpa8zNtuphTFplQX355yesXWx0izQbC7nczOFDNU3xgvM1H-6vAI1ynyHVqHW7vWD0TcfU5HPMWgJYjaUBXSO19yuPQr2lJkh_DcHVXkrf7Vmrqd7DEeFZrTa-WedwJ5O63DQKUe11WE_y-OMVqfwvNM3A9-TtUit1WaZNS-PrXD-oVFrv88jaxyP11aq0kXeP3aDQfcZTLsvk05AivEIJMK4ck2cSHmR8FTiKMZ5TKnyKDPd6D2Hc9QRtq-iiNo0tH0dJqjLuPJFHOKtCdeO3ah1DtV0keoLsFraE1q5bohqiaJP53aCSlFzT6FZ13caQEpM5DLvgiHL9DCDoTQYSsFkhqHkDfBL4OSP25RI1H_svEect4eY5tdBeyDNWuZaUW18Opf_Nn8HB8FkOJCD3qh_BYd5CjYjDruGKuKtb1BhrMPb4gl9AabXxV8 |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Investigations+on+supported+bimetallic+PdPt+nanostructures&rft.jtitle=Surface+science&rft.au=Rousset%2C+J.L.&rft.au=Khanra%2C+B.C.&rft.au=Cadrot%2C+A.M.&rft.au=Cadete+Santos+Aires%2C+F.J.&rft.date=1996-05-15&rft.pub=Elsevier&rft.issn=0039-6028&rft.eissn=1879-2758&rft.volume=352-354&rft.spage=583&rft.epage=587&rft_id=info:doi/10.1016%2F0039-6028%2895%2901202-8&rft.externalDBID=HAS_PDF_LINK&rft.externalDocID=oai_HAL_hal_00006521v1 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0039-6028&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0039-6028&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0039-6028&client=summon |