Twisted Schiff-base macrocycle showing excited-state intramolecular proton-transfer (ESIPT): assembly and sensing properties

A Schiff-base macrocyclic host (MH) showing ESIPT and AIEE is reported for the first time; the fluorescent macrocycle exhibited good pH tolerance and could serve as a probe for Cu 2+ and Fe 3+ ion sensing and removal. In addition, a series of size-tunable nanoparticles was fabricated by the self-ass...

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Published inChemical communications (Cambridge, England) Vol. 56; no. 15; pp. 234 - 237
Main Authors Yu, Qing, Zhang, Xiaodong, Wu, Shou-Ting, Chen, Huaiyu, Zhang, Qi-Long, Xu, Hong, Huang, Ya-Li, Zhu, Bi-Xue, Ni, Xin-Long
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 20.02.2020
Subjects
Coordination compounds
Copper
Crystallography
Ferric ions
Fluorescence
Imines
Nanoparticles
Self-assembly
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Abstract A Schiff-base macrocyclic host (MH) showing ESIPT and AIEE is reported for the first time; the fluorescent macrocycle exhibited good pH tolerance and could serve as a probe for Cu 2+ and Fe 3+ ion sensing and removal. In addition, a series of size-tunable nanoparticles was fabricated by the self-assembly of free MH and its coordination complex with Fe 3+ in THF/water solution. A Schiff-base macrocyclic host showing ESIPT-based AIEE and nanoparticle assembly.
AbstractList A Schiff-base macrocyclic host (MH) showing ESIPT and AIEE is reported for the first time; the fluorescent macrocycle exhibited good pH tolerance and could serve as a probe for Cu 2+ and Fe 3+ ion sensing and removal. In addition, a series of size-tunable nanoparticles was fabricated by the self-assembly of free MH and its coordination complex with Fe 3+ in THF/water solution. A Schiff-base macrocyclic host showing ESIPT-based AIEE and nanoparticle assembly.
A Schiff-base macrocyclic host (MH) showing ESIPT and AIEE is reported for the first time; the fluorescent macrocycle exhibited good pH tolerance and could serve as a probe for Cu 2+ and Fe 3+ ion sensing and removal. In addition, a series of size-tunable nanoparticles was fabricated by the self-assembly of free MH and its coordination complex with Fe 3+ in THF/water solution.
A Schiff-base macrocyclic host (MH) showing ESIPT and AIEE is reported for the first time; the fluorescent macrocycle exhibited good pH tolerance and could serve as a probe for Cu2+ and Fe3+ ion sensing and removal. In addition, a series of size-tunable nanoparticles was fabricated by the self-assembly of free MH and its coordination complex with Fe3+ in THF/water solution.
Author Zhang, Qi-Long
Huang, Ya-Li
Yu, Qing
Zhang, Xiaodong
Wu, Shou-Ting
Zhu, Bi-Xue
Xu, Hong
Chen, Huaiyu
Ni, Xin-Long
AuthorAffiliation School of Basic Medical Science/School of Public Health
Guizhou Medical University
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province
Guizhou University
AuthorAffiliation_xml – name: Guizhou University
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Snippet A Schiff-base macrocyclic host (MH) showing ESIPT and AIEE is reported for the first time; the fluorescent macrocycle exhibited good pH tolerance and could...
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SubjectTerms Coordination compounds
Copper
Crystallography
Ferric ions
Fluorescence
Imines
Nanoparticles
Self-assembly
Title Twisted Schiff-base macrocycle showing excited-state intramolecular proton-transfer (ESIPT): assembly and sensing properties
URI https://www.ncbi.nlm.nih.gov/pubmed/31989126
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