Low molar mass polybutadiene made crosslinkable by the introduction of styrenic moieties via urethane linkage: synthesis, kinetic and crosslinking studies
The introduction of styrenic moieties was chosen for the radical crosslinking of polybutadiene bearing hydroxy functions. The modifications were carried out with 3-isopropenyl-α,α-dimethylbenzyl isocyanate (TMI) with or without catalyst (DBTL). A 2nd order kinetic fits our experimental results up to...
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| Published in | European polymer journal Vol. 38; no. 10; pp. 1979 - 1986 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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01.10.2002
Elsevier |
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| Abstract | The introduction of styrenic moieties was chosen for the radical crosslinking of polybutadiene bearing hydroxy functions. The modifications were carried out with 3-isopropenyl-α,α-dimethylbenzyl isocyanate (TMI) with or without catalyst (DBTL). A 2nd order kinetic fits our experimental results up to high conversion. Arrhenius parameters were calculated. Thermally catalyzed crosslinking was studied. The reaction was followed by measuring swelling (
Q) in toluene as well as mechanical parameters (storage modulus
E
′ at the rubbery plateau and tan
δ). The influence of temperature, the nature and concentration of initiators, the number of styrenic groups per chain (
n=1.2, 2, 2.4) were investigated. In the range of our experimental conditions, a “reaction master curve” was established to predict the evolution of
E
′ and
Q as a function of time, for any temperature, initiator concentration and value of
n. |
|---|---|
| AbstractList | The introduction of styrenic moieties was chosen for the radical crosslinking of polybutadiene bearing hydroxy functions. The modifications were carried out with 3-isopropenyl-α,α-dimethylbenzyl isocyanate (TMI) with or without catalyst (DBTL). A 2nd order kinetic fits our experimental results up to high conversion. Arrhenius parameters were calculated. Thermally catalyzed crosslinking was studied. The reaction was followed by measuring swelling (
Q) in toluene as well as mechanical parameters (storage modulus
E
′ at the rubbery plateau and tan
δ). The influence of temperature, the nature and concentration of initiators, the number of styrenic groups per chain (
n=1.2, 2, 2.4) were investigated. In the range of our experimental conditions, a “reaction master curve” was established to predict the evolution of
E
′ and
Q as a function of time, for any temperature, initiator concentration and value of
n. |
| Author | Bunel, Claude Schapman, Fanny Couvercelle, Jean-Pierre |
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| Cites_doi | 10.1016/S0032-3861(01)00271-3 10.1002/pola.1995.080331505 10.1039/jr9470000713 10.1016/S0032-3861(97)00354-6 10.1007/BF00296165 10.1021/ja01555a015 10.1016/S0032-3861(99)00133-0 10.1039/jr9490000027 10.1021/ja01488a036 10.1021/ja01539a012 10.1021/ja01500a027 10.1039/JR9490000024 10.1002/macp.1987.021880814 10.1002/pola.1995.080331503 10.1002/pola.1995.080331502 10.1002/pola.1995.080331504 10.1039/JR9490000019 10.1039/jr9490000009 10.1016/S0032-3861(97)10244-0 10.1016/S0032-3861(97)00355-8 10.1007/BF00296164 |
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| Keywords | Mechanical properties Styrenic Crosslinking Polybutadiene Kinetic Organic isocyanate Butadiene copolymer Bifunctional compound Styrene derivative copolymer Experimental study Carbamoylation Crosslinked copolymer Chemical modification Free radical polymerization Dynamic mechanical properties Butadiene polymer Preparation Styrene derivatives Prepolymer Kinetics Chemical reactivity Butadiene(hydroxy) polymer Activation energy |
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| References | Baker, Gaunt (BIB14) 1949 Vilar, Menezes, Akcelrud (BIB7) 1994; 33 Baker, Holsworth, Davies, Gaunt (BIB15) 1949 Saunders, Frisch (BIB17) 1962 Schapman, Couvercelle, Bunel (BIB6) 2001; 42 Baker, Holsworth (BIB12) 1947 Grigor'eva, Baturin, Entelis (BIB23) 1972; 14 Huang, Sundberg (BIB24) 1995; 33 Schapman, Couvercelle, Bunel (BIB2) 1998; 39 Sato (BIB10) 1960; 82 Huang, Sundberg (BIB26) 1995; 33 Schapman, Couvercelle, Bunel (BIB5) 2000; 41 Schapman, Couvercelle, Bunel (BIB4) 1998; 39 Baker, Gaunt (BIB16) 1949 Allard-Breton B. Thesis INSA Lyon, 1994 Baker, Gaunt (BIB13) 1949 Sato (BIB11) 1962; 27 Hydroxyl terminated polybd resins, Technical data, Elf-Atochem Inc., 1990. Entelis, Nesterov, Zabrodin (BIB22) 1970; 11 Farkas, Flynn (BIB20) 1960; 82 Vilar, Menezes, Akcelrud (BIB8) 1994; 33 Deschères, Pham (BIB21) 1987; 188 Huang, Sundberg (BIB25) 1995; 33 Ephraim, Woodward, Mesrobian (BIB18) 1958; 80 Huang, Sundberg (BIB27) 1995; 33 Schapman, Couvercelle, Bunel (BIB3) 1998; 39 Burkus, Eckert (BIB19) 1958; 80 Schapman (10.1016/S0014-3057(02)00088-5_BIB2) 1998; 39 10.1016/S0014-3057(02)00088-5_BIB9 Schapman (10.1016/S0014-3057(02)00088-5_BIB4) 1998; 39 Huang (10.1016/S0014-3057(02)00088-5_BIB25) 1995; 33 Baker (10.1016/S0014-3057(02)00088-5_BIB14) 1949 Schapman (10.1016/S0014-3057(02)00088-5_BIB6) 2001; 42 Baker (10.1016/S0014-3057(02)00088-5_BIB13) 1949 Farkas (10.1016/S0014-3057(02)00088-5_BIB20) 1960; 82 Schapman (10.1016/S0014-3057(02)00088-5_BIB5) 2000; 41 Baker (10.1016/S0014-3057(02)00088-5_BIB16) 1949 Saunders (10.1016/S0014-3057(02)00088-5_BIB17) 1962 10.1016/S0014-3057(02)00088-5_BIB1 Entelis (10.1016/S0014-3057(02)00088-5_BIB22) 1970; 11 Vilar (10.1016/S0014-3057(02)00088-5_BIB7) 1994; 33 Sato (10.1016/S0014-3057(02)00088-5_BIB11) 1962; 27 Baker (10.1016/S0014-3057(02)00088-5_BIB15) 1949 Huang (10.1016/S0014-3057(02)00088-5_BIB24) 1995; 33 Schapman (10.1016/S0014-3057(02)00088-5_BIB3) 1998; 39 Huang (10.1016/S0014-3057(02)00088-5_BIB26) 1995; 33 Huang (10.1016/S0014-3057(02)00088-5_BIB27) 1995; 33 Burkus (10.1016/S0014-3057(02)00088-5_BIB19) 1958; 80 Deschères (10.1016/S0014-3057(02)00088-5_BIB21) 1987; 188 Ephraim (10.1016/S0014-3057(02)00088-5_BIB18) 1958; 80 Grigor'eva (10.1016/S0014-3057(02)00088-5_BIB23) 1972; 14 Vilar (10.1016/S0014-3057(02)00088-5_BIB8) 1994; 33 Sato (10.1016/S0014-3057(02)00088-5_BIB10) 1960; 82 Baker (10.1016/S0014-3057(02)00088-5_BIB12) 1947 |
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| SubjectTerms | Applied sciences Chemical modifications Chemical reactions and properties Crosslinking Exact sciences and technology Kinetic Mechanical properties Organic polymers Physicochemistry of polymers Polybutadiene Styrenic |
| Title | Low molar mass polybutadiene made crosslinkable by the introduction of styrenic moieties via urethane linkage: synthesis, kinetic and crosslinking studies |
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