Crown ether-like discrete clusters for sodium binding and gas adsorption

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 52; no. 25; pp. 88 - 881
• Main Authors: Deng, Lan, Ma, Deng-Hui, Xie, Zhen-Lang, Lin, Rong-Yan, Zhou, Zhao-Hui
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 27.06.2023
• Subjects: Adsorption; Binding; Cations; Chemical bonds; Clusters; Crown ethers; Electrons; Hydrogen bonding; Lattice energy; Molecular orbitals; Organometallic compounds; Sodium

Hexanuclear polyoxomolybdenum-based discrete supermolecules Na x [Mo V 6 O 6 (μ 2 -O) 9 (Htrz) 6− x (trz) x ]· n H 2 O ( x = 0, n = 15, 1 ; x = 1, n = 12, 2 ; x = 2, n = 10, 3 ; x = 2, n = 49, 4 ; Htrz = 1 H -1,2,3-triazole) have been prepared and fully characterized with different amounts of sodium...