New Epoxy sugar based glucose derivatives as eco friendly corrosion inhibitors for the carbon steel in 1.0 M HCl: Experimental and theoretical investigations
In this study, we chose to synthesize new sugar based glucose derivatives as ecological corrosion inhibitors for carbon steel in acidic medium. The products obtained in the form of syrupy liquids, and the purity of obtained compounds was characterized by NMR spectroscopy analysis. The corrosion inhi...
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| Published in | Journal of alloys and compounds Vol. 833; p. 154949 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Lausanne
Elsevier B.V
25.08.2020
Elsevier BV |
| Subjects | |
| Online Access | Get full text |
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| Abstract | In this study, we chose to synthesize new sugar based glucose derivatives as ecological corrosion inhibitors for carbon steel in acidic medium. The products obtained in the form of syrupy liquids, and the purity of obtained compounds was characterized by NMR spectroscopy analysis. The corrosion inhibition activities for both compounds were evaluated by electrochemical and rheological methods. Thus, the results of the experimental tests have been confirmed by theoretical studies (DFT, MC and MD simulations). The surface study of carbon steel has been characterized by the scanning electron spectroscopy (SEM). The gravimetric solutions were identified using UV-Vis spectroscopy and Inductively Coupled Plasma-Optical Spectroscopy (ICP-OES).
•Newly both glucose derivatives was synthesized and evaluated as corrosion inhibitor for steel in acidic medium.•Adsorption of G-C12 and G-C6, obeyed the Langmuir adsorption isotherm model their adsorption was supported by SEM and UV-vis spectroscopic analyses.•The experimental results were correlated with DFT and MC stimulation results. |
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| AbstractList | In this study, we chose to synthesize new sugar based glucose derivatives as ecological corrosion inhibitors for carbon steel in acidic medium. The products obtained in the form of syrupy liquids, and the purity of obtained compounds was characterized by NMR spectroscopy analysis. The corrosion inhibition activities for both compounds were evaluated by electrochemical and rheological methods. Thus, the results of the experimental tests have been confirmed by theoretical studies (DFT, MC and MD simulations). The surface study of carbon steel has been characterized by the scanning electron spectroscopy (SEM). The gravimetric solutions were identified using UV-Vis spectroscopy and Inductively Coupled Plasma-Optical Spectroscopy (ICP-OES). In this study, we chose to synthesize new sugar based glucose derivatives as ecological corrosion inhibitors for carbon steel in acidic medium. The products obtained in the form of syrupy liquids, and the purity of obtained compounds was characterized by NMR spectroscopy analysis. The corrosion inhibition activities for both compounds were evaluated by electrochemical and rheological methods. Thus, the results of the experimental tests have been confirmed by theoretical studies (DFT, MC and MD simulations). The surface study of carbon steel has been characterized by the scanning electron spectroscopy (SEM). The gravimetric solutions were identified using UV-Vis spectroscopy and Inductively Coupled Plasma-Optical Spectroscopy (ICP-OES). •Newly both glucose derivatives was synthesized and evaluated as corrosion inhibitor for steel in acidic medium.•Adsorption of G-C12 and G-C6, obeyed the Langmuir adsorption isotherm model their adsorption was supported by SEM and UV-vis spectroscopic analyses.•The experimental results were correlated with DFT and MC stimulation results. |
| ArticleNumber | 154949 |
| Author | Rbaa, M. Warad, I. Zarrouk, A. Berisha, A. Dohare, P. Touhami, M. Ebn Lakhrissi, L. Dagdag, O. Lakhrissi, B. Galai, M. |
| Author_xml | – sequence: 1 givenname: M. surname: Rbaa fullname: Rbaa, M. email: mohamed.rbaa10@gmail.com organization: Laboratory Agro-Resources, Polymers and Process Engineering, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PO Box 133, 14000, Kenitra, Morocco – sequence: 2 givenname: P. surname: Dohare fullname: Dohare, P. organization: Department of Chemistry, Indian Institute of Technology (BHU), Varanasi, 221005, India – sequence: 3 givenname: A. surname: Berisha fullname: Berisha, A. organization: Department of Chemistry, Faculty of Natural and Mathematics Science, University of Prishtina, 10000, Prishtina, Kosovo – sequence: 4 givenname: O. surname: Dagdag fullname: Dagdag, O. organization: Laboratory Agro-Resources, Polymers and Process Engineering, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PO Box 133, 14000, Kenitra, Morocco – sequence: 5 givenname: L. surname: Lakhrissi fullname: Lakhrissi, L. organization: Laboratory Agro-Resources, Polymers and Process Engineering, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PO Box 133, 14000, Kenitra, Morocco – sequence: 6 givenname: M. surname: Galai fullname: Galai, M. organization: Laboratory of Materials Engineering and Environment: Modeling and Application, Faculty of Science, Ibn Tofail University BP. 133-14000, Kenitra, Morocco – sequence: 7 givenname: B. surname: Lakhrissi fullname: Lakhrissi, B. organization: Laboratory Agro-Resources, Polymers and Process Engineering, Department of Chemistry, Faculty of Sciences, Ibn Tofail University, PO Box 133, 14000, Kenitra, Morocco – sequence: 8 givenname: M. Ebn surname: Touhami fullname: Touhami, M. Ebn organization: Laboratory of Materials Engineering and Environment: Modeling and Application, Faculty of Science, Ibn Tofail University BP. 133-14000, Kenitra, Morocco – sequence: 9 givenname: I. surname: Warad fullname: Warad, I. organization: Department of Chemistry and Earth Sciences, PO Box 2713, Qatar University, Doha, Qatar – sequence: 10 givenname: A. surname: Zarrouk fullname: Zarrouk, A. email: azarrouk@gmail.com organization: Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University, Av. Ibn Battuta. B.P 1014, Rabat, Morocco |
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| Snippet | In this study, we chose to synthesize new sugar based glucose derivatives as ecological corrosion inhibitors for carbon steel in acidic medium. The products... |
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| SubjectTerms | Carbon steel Carbon steels Corrosion Corrosion inhibitors Corrosion products Derivatives Eco friendly corrosion inhibitors Electrochemical techniques Glucose Gravimetry Inductively coupled plasma MD simulations NMR spectroscopy Rheological methods Rheological properties SEM Spectrum analysis Synthesis |
| Title | New Epoxy sugar based glucose derivatives as eco friendly corrosion inhibitors for the carbon steel in 1.0 M HCl: Experimental and theoretical investigations |
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