Stability of a block-copolymer lamella in a strong electric field

Using self-consistent field theory, we examine the stability of a lamellar layer of diblock copolymer subject to strong orthogonal electric fields. Two competing instabilities are identified; one is a peristaltic mode that leads to perpendicular lamellae, and the other is an undulatory mode that res...

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Published inPhysical review letters Vol. 95; no. 25; p. 258302
Main Author Matsen, M W
Format Journal Article
LanguageEnglish
Published United States 16.12.2005
Subjects
Computer Simulation
Dose-Response Relationship, Radiation
Electromagnetic Fields
Kinetics
Models, Chemical
Models, Molecular
Molecular Conformation - radiation effects
Polymers - chemistry
Polymers - radiation effects
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Abstract Using self-consistent field theory, we examine the stability of a lamellar layer of diblock copolymer subject to strong orthogonal electric fields. Two competing instabilities are identified; one is a peristaltic mode that leads to perpendicular lamellae, and the other is an undulatory mode that results in the formation of an undesirable grain boundary. The former kinetic pathway is favored when the central domain is relatively thin and composed of the low-dielectric material.
AbstractList Using self-consistent field theory, we examine the stability of a lamellar layer of diblock copolymer subject to strong orthogonal electric fields. Two competing instabilities are identified; one is a peristaltic mode that leads to perpendicular lamellae, and the other is an undulatory mode that results in the formation of an undesirable grain boundary. The former kinetic pathway is favored when the central domain is relatively thin and composed of the low-dielectric material.
Author Matsen, M W
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Snippet Using self-consistent field theory, we examine the stability of a lamellar layer of diblock copolymer subject to strong orthogonal electric fields. Two...
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StartPage 258302
SubjectTerms Computer Simulation
Dose-Response Relationship, Radiation
Electromagnetic Fields
Kinetics
Models, Chemical
Models, Molecular
Molecular Conformation - radiation effects
Polymers - chemistry
Polymers - radiation effects
Title Stability of a block-copolymer lamella in a strong electric field
URI https://www.ncbi.nlm.nih.gov/pubmed/16384517
Volume 95
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