Corrosion behavior and elements interdiffusion between a Ni coating and GH3535 alloy with and without a CrN barrier in molten fluoride salts
CrN barrier was deposited between a Ni-electroplating and GH3535 alloy with the goal of prohibiting elements interdiffusion and increasing corrosion resistance in molten FLiNaK (LiF-NaF-KF: 46.5-11.5-42.0 mol%) salt. Results indicate that the Ni-coating apparently improves corrosion resistance of GH...
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| Published in | Journal of nuclear materials Vol. 514; pp. 348 - 357 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
01.02.2019
Elsevier BV |
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| Online Access | Get full text |
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| Abstract | CrN barrier was deposited between a Ni-electroplating and GH3535 alloy with the goal of prohibiting elements interdiffusion and increasing corrosion resistance in molten FLiNaK (LiF-NaF-KF: 46.5-11.5-42.0 mol%) salt. Results indicate that the Ni-coating apparently improves corrosion resistance of GH3535 in molten fluoride salts, but Cr and Fe diffuse constantly from the alloy to the Ni-coating. They are finally dissolved into the molten salt, causing corrosion of the GH3535 alloy. With a CrN diffusion barrier, however, elements interdiffusion has been completely suppressed and the corrosion resistance is further improved by more than eight times comparing to the CrN-free Ni-coated alloy.
•Ni-coating greatly improves corrosion resistance of alloy in molten fluoride salts.•CrN barrier can inhibit elements interdiffusion and enhance corrosion resistance.•CrN layer remains intact and adheres well to the alloy and coating after corrosion. |
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| AbstractList | CrN barrier was deposited between a Ni-electroplating and GH3535 alloy with the goal of prohibiting elements interdiffusion and increasing corrosion resistance in molten FLiNaK (LiF-NaF-KF: 46.5-11.5-42.0 mol%) salt. Results indicate that the Ni-coating apparently improves corrosion resistance of GH3535 in molten fluoride salts, but Cr and Fe diffuse constantly from the alloy to the Ni-coating. They are finally dissolved into the molten salt, causing corrosion of the GH3535 alloy. With a CrN diffusion barrier, however, elements interdiffusion has been completely suppressed and the corrosion resistance is further improved by more than eight times comparing to the CrN-free Ni-coated alloy. CrN barrier was deposited between a Ni-electroplating and GH3535 alloy with the goal of prohibiting elements interdiffusion and increasing corrosion resistance in molten FLiNaK (LiF-NaF-KF: 46.5-11.5-42.0 mol%) salt. Results indicate that the Ni-coating apparently improves corrosion resistance of GH3535 in molten fluoride salts, but Cr and Fe diffuse constantly from the alloy to the Ni-coating. They are finally dissolved into the molten salt, causing corrosion of the GH3535 alloy. With a CrN diffusion barrier, however, elements interdiffusion has been completely suppressed and the corrosion resistance is further improved by more than eight times comparing to the CrN-free Ni-coated alloy. •Ni-coating greatly improves corrosion resistance of alloy in molten fluoride salts.•CrN barrier can inhibit elements interdiffusion and enhance corrosion resistance.•CrN layer remains intact and adheres well to the alloy and coating after corrosion. |
| Author | Chen, Wei Wang, Chengxu Chen, Demin Yang, Ke Chen, Minghui |
| Author_xml | – sequence: 1 givenname: Chengxu surname: Wang fullname: Wang, Chengxu organization: Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China – sequence: 2 givenname: Wei surname: Chen fullname: Chen, Wei email: chenwei@imr.ac.cn organization: Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China – sequence: 3 givenname: Minghui orcidid: 0000-0001-6350-2401 surname: Chen fullname: Chen, Minghui email: mhchen@mail.neu.edu.cn organization: Corrosion and Protection Division, Shenyang National Laboratory for Materials Science, Northeastern University, Shenyang, 110819, China – sequence: 4 givenname: Demin surname: Chen fullname: Chen, Demin organization: Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China – sequence: 5 givenname: Ke surname: Yang fullname: Yang, Ke organization: Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China |
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| Snippet | CrN barrier was deposited between a Ni-electroplating and GH3535 alloy with the goal of prohibiting elements interdiffusion and increasing corrosion resistance... |
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| SubjectTerms | Chromium nitride Coatings Corrosion Corrosion resistance Corrosion resistant alloys Diffusion barriers Electroplating Fluorides High temperature corrosion Interdiffusion Iron Lithium fluoride Molten salts Nickel base alloys Nickel coatings Protective coatings Salts Superalloys |
| Title | Corrosion behavior and elements interdiffusion between a Ni coating and GH3535 alloy with and without a CrN barrier in molten fluoride salts |
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