Synthesis and proton-conductive behaviour of two MOFs with covalently bonded imidazoles in the channels
Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr 6 (OH) 16 (H 3 L 1 ) 4 ]C...
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| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 53; no. 2; pp. 8716 - 8721 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
21.05.2024
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1477-9226 1477-9234 1477-9234 |
| DOI | 10.1039/d3dt04338j |
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| Abstract | Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr
6
(OH)
16
(H
3
L
1
)
4
]Cl
8
·20H
2
O}
n
[
Zr-MOF
; H
3
L
1
= 2-(1
H
-imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H
2
L
2
)
2
}
n
[
Gd-MOF
; H
3
L
2
= 5-(1
H
-imidazol-4-yl)methylaminoisophthalic acid] and fully studied their porous nature, stability and water-assisted proton conduction. The resulting
Zr-MOF
exhibits a high proton conductivity of 1.82 × 10
−2
S cm
−1
at 98% RH and 80 °C, while
Gd-MOF
has a proton conductivity of 3.01 × 10
−3
S cm
−1
at 98% RH and 60 °C.
Based on two imidazole substituted phthalic acid ligands, two new metal-organic frameworks have been synthesized. Both complexes exhibit impressive proton conductivities under 98% RH. |
|---|---|
| AbstractList | Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr6(OH)16(H3L1)4]Cl8·20H2O}n [Zr-MOF; H3L1 = 2-(1H-imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H2L2)2}n [Gd-MOF; H3L2 = 5-(1H-imidazol-4-yl)methylaminoisophthalic acid] and fully studied their porous nature, stability and water-assisted proton conduction. The resulting Zr-MOF exhibits a high proton conductivity of 1.82 × 10−2 S cm−1 at 98% RH and 80 °C, while Gd-MOF has a proton conductivity of 3.01 × 10−3 S cm−1 at 98% RH and 60 °C. Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr 6 (OH) 16 (H 3 L 1 ) 4 ]Cl 8 ·20H 2 O} n [ Zr-MOF ; H 3 L 1 = 2-(1 H -imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H 2 L 2 ) 2 } n [ Gd-MOF ; H 3 L 2 = 5-(1 H -imidazol-4-yl)methylaminoisophthalic acid] and fully studied their porous nature, stability and water-assisted proton conduction. The resulting Zr-MOF exhibits a high proton conductivity of 1.82 × 10 −2 S cm −1 at 98% RH and 80 °C, while Gd-MOF has a proton conductivity of 3.01 × 10 −3 S cm −1 at 98% RH and 60 °C. Based on two imidazole substituted phthalic acid ligands, two new metal-organic frameworks have been synthesized. Both complexes exhibit impressive proton conductivities under 98% RH. Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr (OH) (H L ) ]Cl ·20H O} [Zr-MOF; H L = 2-(1 -imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H L ) } [Gd-MOF; H L = 5-(1 -imidazol-4-yl)methylaminoisophthalic acid] and fully studied their porous nature, stability and water-assisted proton conduction. The resulting Zr-MOF exhibits a high proton conductivity of 1.82 × 10 S cm at 98% RH and 80 °C, while Gd-MOF has a proton conductivity of 3.01 × 10 S cm at 98% RH and 60 °C. Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr 6 (OH) 16 (H 3 L 1 ) 4 ]Cl 8 ·20H 2 O} n [Zr-MOF; H 3 L 1 = 2-(1 H -imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H 2 L 2 ) 2 } n [Gd-MOF; H 3 L 2 = 5-(1 H -imidazol-4-yl)methylaminoisophthalic acid] and fully studied their porous nature, stability and water-assisted proton conduction. The resulting Zr-MOF exhibits a high proton conductivity of 1.82 × 10 −2 S cm −1 at 98% RH and 80 °C, while Gd-MOF has a proton conductivity of 3.01 × 10 −3 S cm −1 at 98% RH and 60 °C. Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr6(OH)16(H3L1)4]Cl8·20H2O}n [Zr-MOF; H3L1 = 2-(1H-imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H2L2)2}n [Gd-MOF; H3L2 = 5-(1H-imidazol-4-yl)methylaminoisophthalic acid] and fully studied their porous nature, stability and water-assisted proton conduction. The resulting Zr-MOF exhibits a high proton conductivity of 1.82 × 10-2 S cm-1 at 98% RH and 80 °C, while Gd-MOF has a proton conductivity of 3.01 × 10-3 S cm-1 at 98% RH and 60 °C.Immobilization of imidazole molecules as proton carriers into MOFs to facilitate proton conduction is a general strategy for developing high proton conductive materials. Herein, we designed two imidazole substituted phthalic acid ligands and constructed two novel MOFs, {[Zr6(OH)16(H3L1)4]Cl8·20H2O}n [Zr-MOF; H3L1 = 2-(1H-imidazol-4-yl) methylaminoterephthalic acid] and {Gd(HCOO)(H2L2)2}n [Gd-MOF; H3L2 = 5-(1H-imidazol-4-yl)methylaminoisophthalic acid] and fully studied their porous nature, stability and water-assisted proton conduction. The resulting Zr-MOF exhibits a high proton conductivity of 1.82 × 10-2 S cm-1 at 98% RH and 80 °C, while Gd-MOF has a proton conductivity of 3.01 × 10-3 S cm-1 at 98% RH and 60 °C. |
| Author | Ma, Yue Zhang, Chen-Xi Chen, Kun-Peng Ren, Hong-Xia Wang, Qing-Lun |
| AuthorAffiliation | College of Chemical Engineering and Materials Science Nankai University Tianjin University of Science and Technology College of Chemistry Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38711354$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1021_acs_inorgchem_4c01579 crossref_primary_10_1016_j_jallcom_2024_177546 crossref_primary_10_1002_admi_202400928 |
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| SubjectTerms | Gadolinium Imidazole Metal-organic frameworks Proton conduction Zirconium |
| Title | Synthesis and proton-conductive behaviour of two MOFs with covalently bonded imidazoles in the channels |
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