A solvent-controlled photoresponsive ionic hydrogen-bonded organic framework for encryption applications

Two novel ionic hydrogen-bonded organic frameworks ( iHOF-17 and iHOF-18 ) were obtained by integrating organosulfonic acids with amidine salts. Among them, iHOF-18 exhibits fast, reversible, and high-contrast UV-induced photochromic properties, and this property is solvent-controlled. This work pro...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 6; no. 25; pp. 3437 - 344
Main Authors Huang, Ming-Feng, Cao, Li-Hui, Zhou, Bin
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 21.03.2024
Subjects
Online AccessGet full text

Cover

Loading…
Abstract Two novel ionic hydrogen-bonded organic frameworks ( iHOF-17 and iHOF-18 ) were obtained by integrating organosulfonic acids with amidine salts. Among them, iHOF-18 exhibits fast, reversible, and high-contrast UV-induced photochromic properties, and this property is solvent-controlled. This work provides valuable insights for designing advanced anti-counterfeiting techniques and encryption applications. An ionic hydrogen-bonded organic framework exhibits fast and reversible photochromic properties. Benefiting from the stimuli-responsive property, information encryptions and decryptions integrated with photoresponsivity are successfully designed.
AbstractList Two novel ionic hydrogen-bonded organic frameworks ( iHOF-17 and iHOF-18 ) were obtained by integrating organosulfonic acids with amidine salts. Among them, iHOF-18 exhibits fast, reversible, and high-contrast UV-induced photochromic properties, and this property is solvent-controlled. This work provides valuable insights for designing advanced anti-counterfeiting techniques and encryption applications. An ionic hydrogen-bonded organic framework exhibits fast and reversible photochromic properties. Benefiting from the stimuli-responsive property, information encryptions and decryptions integrated with photoresponsivity are successfully designed.
Two novel ionic hydrogen-bonded organic frameworks (iHOF-17 and iHOF-18) were obtained by integrating organosulfonic acids with amidine salts. Among them, iHOF-18 exhibits fast, reversible, and high-contrast UV-induced photochromic properties, and this property is solvent-controlled. This work provides valuable insights for designing advanced anti-counterfeiting techniques and encryption applications.
Two novel ionic hydrogen-bonded organic frameworks (iHOF-17 and iHOF-18) were obtained by integrating organosulfonic acids with amidine salts. Among them, iHOF-18 exhibits fast, reversible, and high-contrast UV-induced photochromic properties, and this property is solvent-controlled. This work provides valuable insights for designing advanced anti-counterfeiting techniques and encryption applications.Two novel ionic hydrogen-bonded organic frameworks (iHOF-17 and iHOF-18) were obtained by integrating organosulfonic acids with amidine salts. Among them, iHOF-18 exhibits fast, reversible, and high-contrast UV-induced photochromic properties, and this property is solvent-controlled. This work provides valuable insights for designing advanced anti-counterfeiting techniques and encryption applications.
Author Zhou, Bin
Huang, Ming-Feng
Cao, Li-Hui
AuthorAffiliation Shaanxi Key Laboratory of Chemical Additives for Industry
Shaanxi University of Science and Technology
College of Chemistry and Chemical Engineering
AuthorAffiliation_xml – sequence: 0
  name: Shaanxi University of Science and Technology
– sequence: 0
  name: College of Chemistry and Chemical Engineering
– sequence: 0
  name: Shaanxi Key Laboratory of Chemical Additives for Industry
Author_xml – sequence: 1
  givenname: Ming-Feng
  surname: Huang
  fullname: Huang, Ming-Feng
– sequence: 2
  givenname: Li-Hui
  surname: Cao
  fullname: Cao, Li-Hui
– sequence: 3
  givenname: Bin
  surname: Zhou
  fullname: Zhou, Bin
BackLink https://www.ncbi.nlm.nih.gov/pubmed/38444288$$D View this record in MEDLINE/PubMed
BookMark eNpt0UtLxDAQB_Agiu-Ld6XgRYRq0iRNelzWJwheFLyVNJm61W6mJl1lv73dXR8g5pIh_GZI8t8h6x49EHLA6BmjvDh3wlpKFWWTNbLNeC5SKfTT-qKWRaq4kFtkJ8YXOiwm9SbZ4loIkWm9TSajJGL7Dr5PLfo-YNuCS7oJ9hggduhj8w5Jg76xyWTuAj6DTyv0blAYns3ivA5mCh8YXpMaQwLehnnXDy2J6bq2sWZRxz2yUZs2wv7Xvksery4fxjfp3f317Xh0l1rOVZ-KHPIcOC20pLLKpYKacwcmcxVYYKpQma3yrHYAUmvpWG6Am6KweV1pIwq-S05Wc7uAbzOIfTltooW2NR5wFsus4DrTgi_p8R_6grPgh9sNSmWKZUyJQR19qVk1BVd2oZmaMC-__3AAdAVswBgD1KVt-uWj-2CatmS0XMRUXojxeBnTzdBy-qfle-q_-HCFQ7Q_7jdz_gnUc54H
CitedBy_id crossref_primary_10_1039_D4QM00927D
crossref_primary_10_1360_SSC_2024_0138
crossref_primary_10_1039_D4CC03594A
crossref_primary_10_1021_acsami_4c15701
crossref_primary_10_1002_adom_202402321
crossref_primary_10_1039_D4CC03957B
crossref_primary_10_1039_D5CC00892A
Cites_doi 10.1002/anie.202308418
10.1039/C9SC00757A
10.1002/advs.202104790
10.1039/C9TC01312A
10.1039/D3QI00444A
10.1039/C8CC00224J
10.1039/C8CC06662K
10.1039/C6RA18073F
10.1016/j.carbon.2021.05.023
10.1016/j.cclet.2022.107864
10.1002/anie.201800119
10.1021/prechem.3c00094
10.1021/acsami.1c23328
10.1002/chem.202300028
10.1021/acs.chemmater.2c03817
10.1021/acs.inorgchem.2c02687
10.1002/advs.202206290
10.1021/jacs.2c13108
10.1021/jacs.9b05280
10.1021/acs.inorgchem.6b01186
10.1002/adma.201405483
10.1039/C6SC04579K
10.1021/jacs.0c06473
10.1002/adfm.202305796
10.1016/j.cej.2023.143781
10.1039/C7CC00961E
10.1002/adfm.202103321
10.1039/D0CC02411B
10.1002/anie.201910530
10.1039/D0TC02297G
10.1021/acs.inorgchem.2c01019
10.1038/ncomms7884
10.1039/D1CC03438C
ContentType Journal Article
Copyright Copyright Royal Society of Chemistry 2024
Copyright_xml – notice: Copyright Royal Society of Chemistry 2024
DBID AAYXX
CITATION
NPM
7SR
7U5
8BQ
8FD
JG9
L7M
7X8
DOI 10.1039/d4cc00701h
DatabaseName CrossRef
PubMed
Engineered Materials Abstracts
Solid State and Superconductivity Abstracts
METADEX
Technology Research Database
Materials Research Database
Advanced Technologies Database with Aerospace
MEDLINE - Academic
DatabaseTitle CrossRef
PubMed
Materials Research Database
Engineered Materials Abstracts
Solid State and Superconductivity Abstracts
Technology Research Database
Advanced Technologies Database with Aerospace
METADEX
MEDLINE - Academic
DatabaseTitleList
PubMed
MEDLINE - Academic
CrossRef
Materials Research Database
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1364-548X
EndPage 344
ExternalDocumentID 38444288
10_1039_D4CC00701H
d4cc00701h
Genre Journal Article
GroupedDBID ---
-DZ
-JG
-~X
0-7
0R~
29B
4.4
53G
5GY
6J9
705
70~
7~J
AAEMU
AAHBH
AAIWI
AAJAE
AAMEH
AANOJ
AAWGC
AAXHV
AAXPP
ABASK
ABDVN
ABEMK
ABJNI
ABPDG
ABRYZ
ABXOH
ACBEA
ACGFO
ACGFS
ACIWK
ACLDK
ACNCT
ADMRA
ADSRN
AEFDR
AENEX
AENGV
AESAV
AETIL
AFLYV
AFOGI
AFRDS
AFVBQ
AGEGJ
AGKEF
AGRSR
AGSTE
AHGCF
ALMA_UNASSIGNED_HOLDINGS
ANUXI
APEMP
ASKNT
AUDPV
AZFZN
BLAPV
BSQNT
C6K
CS3
DU5
EBS
ECGLT
EE0
EF-
F5P
GGIMP
GNO
H13
HZ~
H~N
IDZ
IH2
J3I
M4U
N9A
O9-
P2P
R7B
R7C
R7D
RAOCF
RCNCU
RPMJG
RRA
RRC
RSCEA
SJN
SKA
SKF
SKH
SLH
TN5
TWZ
UPT
VH6
VQA
WH7
X7L
AAYXX
AFRZK
AKMSF
ALUYA
CITATION
R56
NPM
7SR
7U5
8BQ
8FD
JG9
L7M
7X8
ID FETCH-LOGICAL-c337t-46e66e3098505b657ef33dea2dbece17972cb62fdee5885d16ae3a99c6fb8a493
ISSN 1359-7345
1364-548X
IngestDate Fri Jul 11 00:09:11 EDT 2025
Mon Jun 30 04:46:51 EDT 2025
Wed Feb 19 02:05:57 EST 2025
Tue Jul 01 04:23:16 EDT 2025
Thu Apr 24 23:02:27 EDT 2025
Tue Dec 17 20:58:47 EST 2024
IsPeerReviewed true
IsScholarly true
Issue 25
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c337t-46e66e3098505b657ef33dea2dbece17972cb62fdee5885d16ae3a99c6fb8a493
Notes For ESI and crystallographic data in CIF or other electronic format see DOI
https://doi.org/10.1039/d4cc00701h
Electronic supplementary information (ESI) available: The crystal structures, PXRD patterns, TGA curves, XPS, EPR, UV-vis absorption and photoluminescent spectroscopy. CCDC
2330876
and
2330877
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ORCID 0000-0002-3676-0242
PMID 38444288
PQID 2972712174
PQPubID 2047502
PageCount 4
ParticipantIDs rsc_primary_d4cc00701h
proquest_miscellaneous_2938284349
crossref_citationtrail_10_1039_D4CC00701H
crossref_primary_10_1039_D4CC00701H
proquest_journals_2972712174
pubmed_primary_38444288
ProviderPackageCode CITATION
AAYXX
PublicationCentury 2000
PublicationDate 2024-03-21
PublicationDateYYYYMMDD 2024-03-21
PublicationDate_xml – month: 03
  year: 2024
  text: 2024-03-21
  day: 21
PublicationDecade 2020
PublicationPlace England
PublicationPlace_xml – name: England
– name: Cambridge
PublicationTitle Chemical communications (Cambridge, England)
PublicationTitleAlternate Chem Commun (Camb)
PublicationYear 2024
Publisher Royal Society of Chemistry
Publisher_xml – name: Royal Society of Chemistry
References Xu (D4CC00701H/cit29/1) 2021; 31
Zhou (D4CC00701H/cit14/1) 2020; 8
Hai (D4CC00701H/cit2/1) 2018; 57
Li (D4CC00701H/cit3/1) 2023; 10
McFadden (D4CC00701H/cit9/1) 2019; 141
Wu (D4CC00701H/cit15/1) 2023; 469
Sui (D4CC00701H/cit10/1) 2017; 8
Li (D4CC00701H/cit21/1) 2022; 9
Sun (D4CC00701H/cit16/1) 2019; 7
Huang (D4CC00701H/cit20/1) 2019; 58
Chen (D4CC00701H/cit32/1) 2022; 14
Yang (D4CC00701H/cit28/1) 2023; 10
Feng (D4CC00701H/cit4/1) 2023; 33
Chen (D4CC00701H/cit26/1) 2023; 29
Wang (D4CC00701H/cit24/1) 2020; 142
Li (D4CC00701H/cit7/1) 2022; 61
Gao (D4CC00701H/cit23/1) 2022; 61
Li (D4CC00701H/cit12/1) 2019; 10
Wu (D4CC00701H/cit11/1) 2018; 54
Müller (D4CC00701H/cit17/1) 2017; 53
Chen (D4CC00701H/cit22/1) 2023; 1
Bai (D4CC00701H/cit25/1) 2023; 35
Tuktarov (D4CC00701H/cit19/1) 2016; 6
Hou (D4CC00701H/cit6/1) 2015; 6
Guo (D4CC00701H/cit1/1) 2023; 145
Lin (D4CC00701H/cit30/1) 2023; 34
Chen (D4CC00701H/cit33/1) 2023; 62
Takeuchi (D4CC00701H/cit18/1) 2020; 56
Gupta (D4CC00701H/cit13/1) 2016; 55
Bae (D4CC00701H/cit5/1) 2015; 27
Xu (D4CC00701H/cit31/1) 2018; 54
Liu (D4CC00701H/cit8/1) 2021; 181
Wang (D4CC00701H/cit27/1) 2021; 57
References_xml – volume: 62
  start-page: e202308418
  year: 2023
  ident: D4CC00701H/cit33/1
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.202308418
– volume: 10
  start-page: 4896
  year: 2019
  ident: D4CC00701H/cit12/1
  publication-title: Chem. Sci.
  doi: 10.1039/C9SC00757A
– volume: 9
  start-page: 2104790
  year: 2022
  ident: D4CC00701H/cit21/1
  publication-title: Adv. Sci.
  doi: 10.1002/advs.202104790
– volume: 7
  start-page: 7053
  year: 2019
  ident: D4CC00701H/cit16/1
  publication-title: J. Mater. Chem. C
  doi: 10.1039/C9TC01312A
– volume: 10
  start-page: 2951
  year: 2023
  ident: D4CC00701H/cit28/1
  publication-title: Inorg. Chem. Front.
  doi: 10.1039/D3QI00444A
– volume: 54
  start-page: 2619
  year: 2018
  ident: D4CC00701H/cit11/1
  publication-title: Chem. Commun.
  doi: 10.1039/C8CC00224J
– volume: 54
  start-page: 12942
  year: 2018
  ident: D4CC00701H/cit31/1
  publication-title: Chem. Commun.
  doi: 10.1039/C8CC06662K
– volume: 6
  start-page: 71151
  year: 2016
  ident: D4CC00701H/cit19/1
  publication-title: RSC Adv.
  doi: 10.1039/C6RA18073F
– volume: 181
  start-page: 9
  year: 2021
  ident: D4CC00701H/cit8/1
  publication-title: Carbon
  doi: 10.1016/j.carbon.2021.05.023
– volume: 34
  start-page: 107864
  year: 2023
  ident: D4CC00701H/cit30/1
  publication-title: Chin. Chem. Lett.
  doi: 10.1016/j.cclet.2022.107864
– volume: 57
  start-page: 6786
  year: 2018
  ident: D4CC00701H/cit2/1
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201800119
– volume: 1
  start-page: 608
  year: 2023
  ident: D4CC00701H/cit22/1
  publication-title: Precis. Chem.
  doi: 10.1021/prechem.3c00094
– volume: 14
  start-page: 11619
  year: 2022
  ident: D4CC00701H/cit32/1
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.1c23328
– volume: 29
  start-page: e202300028
  year: 2023
  ident: D4CC00701H/cit26/1
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.202300028
– volume: 35
  start-page: 3172
  year: 2023
  ident: D4CC00701H/cit25/1
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.2c03817
– volume: 61
  start-page: 15812
  year: 2022
  ident: D4CC00701H/cit23/1
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.2c02687
– volume: 10
  start-page: 2206290
  year: 2023
  ident: D4CC00701H/cit3/1
  publication-title: Adv. Sci.
  doi: 10.1002/advs.202206290
– volume: 145
  start-page: 4246
  year: 2023
  ident: D4CC00701H/cit1/1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.2c13108
– volume: 141
  start-page: 11388
  year: 2019
  ident: D4CC00701H/cit9/1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.9b05280
– volume: 55
  start-page: 6817
  year: 2016
  ident: D4CC00701H/cit13/1
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.6b01186
– volume: 27
  start-page: 2083
  year: 2015
  ident: D4CC00701H/cit5/1
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201405483
– volume: 8
  start-page: 2758
  year: 2017
  ident: D4CC00701H/cit10/1
  publication-title: Chem. Sci.
  doi: 10.1039/C6SC04579K
– volume: 142
  start-page: 14399
  year: 2020
  ident: D4CC00701H/cit24/1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.0c06473
– volume: 33
  start-page: 2305796
  year: 2023
  ident: D4CC00701H/cit4/1
  publication-title: Adv. Funct. Mater.
  doi: 10.1002/adfm.202305796
– volume: 469
  start-page: 143781
  year: 2023
  ident: D4CC00701H/cit15/1
  publication-title: Chem. Eng. J.
  doi: 10.1016/j.cej.2023.143781
– volume: 53
  start-page: 8070
  year: 2017
  ident: D4CC00701H/cit17/1
  publication-title: Chem. Commun.
  doi: 10.1039/C7CC00961E
– volume: 31
  start-page: 2103321
  year: 2021
  ident: D4CC00701H/cit29/1
  publication-title: Adv. Funct. Mater.
  doi: 10.1002/adfm.202103321
– volume: 56
  start-page: 6492
  year: 2020
  ident: D4CC00701H/cit18/1
  publication-title: Chem. Commun.
  doi: 10.1039/D0CC02411B
– volume: 58
  start-page: 17814
  year: 2019
  ident: D4CC00701H/cit20/1
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201910530
– volume: 8
  start-page: 13197
  year: 2020
  ident: D4CC00701H/cit14/1
  publication-title: J. Mater. Chem. C
  doi: 10.1039/D0TC02297G
– volume: 61
  start-page: 10792
  year: 2022
  ident: D4CC00701H/cit7/1
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.2c01019
– volume: 6
  start-page: 6884
  year: 2015
  ident: D4CC00701H/cit6/1
  publication-title: Nat. Commun.
  doi: 10.1038/ncomms7884
– volume: 57
  start-page: 10051
  year: 2021
  ident: D4CC00701H/cit27/1
  publication-title: Chem. Commun.
  doi: 10.1039/D1CC03438C
SSID ssj0000158
Score 2.4906843
Snippet Two novel ionic hydrogen-bonded organic frameworks ( iHOF-17 and iHOF-18 ) were obtained by integrating organosulfonic acids with amidine salts. Among them,...
Two novel ionic hydrogen-bonded organic frameworks (iHOF-17 and iHOF-18) were obtained by integrating organosulfonic acids with amidine salts. Among them,...
SourceID proquest
pubmed
crossref
rsc
SourceType Aggregation Database
Index Database
Enrichment Source
Publisher
StartPage 3437
SubjectTerms Hydrogen bonding
Solvents
Title A solvent-controlled photoresponsive ionic hydrogen-bonded organic framework for encryption applications
URI https://www.ncbi.nlm.nih.gov/pubmed/38444288
https://www.proquest.com/docview/2972712174
https://www.proquest.com/docview/2938284349
Volume 6
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3db9MwELege4AXxNdYYCAjeEGVR5tzHPuxKkMBMZ46qW9R4jh00pRMpUEafz0X2_lgHRLwElW260S-n8935_sg5C1K9FpkpWR4uHNUUABYHkaG5fNIizIvitw6j599Fck5_7yO1sMNvo0u2eUn-uetcSX_Q1VsQ7q2UbL_QNl-UmzA30hffCKF8flXNF5Mcf7WYZF5j_NLFB-vNjXq0d719YeZXtgaN5vrYlvjRCyvW5u3r-akp2XnnOVyf1d6e-2YyPhmeyzB9hkG9Di0xNpu-_gvy2BddZCRpSFpvG36DI9Lhgv5bbgAqZ19gCXNxWDKrhuLPp8b3JsmkNYzYC7e2XNTiBSLweWLPDG-TXCGatJ6zILFCGlhNOKnwF1KGH82g8sVucf2Z9BmTS241m36ovlmONx6l8Oh8y45CFGnCCfkYHG6-vRllG3MlnPtv7rLZgvq_fDv3-WXPaUERZRtVzrGiiirh-SB1y3owgHlEbljqsfk3rIr6feEbBZ0HzD0BmCoBQy9ARjqAUN7wFAEDB0AQ8eAeUrOP56ulgnzpTaYBoh3jAsjhIGZkigR5yKKTQlQmCwscI8bZNpxqHMRloUxkZRRMReZgUypdj_LjCs4JJOqrswRoRArlBs1xDKX3MyFCjOFqyfLIsSzTBUBedctYKp9Hvq2HMplav0hQKUf-HJpFzsJyJt-7JXLvnLrqOOODqnfnd_TED85nrcKd0Be99243u2FWFaZumnHgETxDLgKyDNHv_41IDlH1VwG5BAJ2jcPQHj-p44X5P6wGY7JZLdtzEuUXHf5K4-4X51dnUE
linkProvider Royal Society of Chemistry
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=A+solvent-controlled+photoresponsive+ionic+hydrogen-bonded+organic+framework+for+encryption+applications&rft.jtitle=Chemical+communications+%28Cambridge%2C+England%29&rft.au=Huang%2C+Ming-Feng&rft.au=Cao%2C+Li-Hui&rft.au=Zhou%2C+Bin&rft.date=2024-03-21&rft.issn=1359-7345&rft.eissn=1364-548X&rft.volume=6&rft.issue=25&rft.spage=3437&rft.epage=344&rft_id=info:doi/10.1039%2Fd4cc00701h&rft.externalDocID=d4cc00701h
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1359-7345&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1359-7345&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1359-7345&client=summon